Wairakite
A valid IMA mineral species - grandfathered
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About Wairakite
"Craters of the Moon" in Taupo
Wairakei geothermal area, Wairakei, Taupo District, Waikato Region, New Zealand
Wairakei geothermal area, Wairakei, Taupo District, Waikato Region, New Zealand
Formula:
Ca(Al2Si4O12) · 2H2O
Colour:
Colorless to white
Lustre:
Vitreous, Dull
Hardness:
5½ - 6
Specific Gravity:
2.26
Crystal System:
Monoclinic
Member of:
Name:
Named after its discovery locality, Wairakei, North Island, New Zealand.
Unique Identifiers
Mindat ID:
4230
Long-form identifier:
mindat:1:1:4230:3
GUID
(UUID V4):
(UUID V4):
4884c72d-b402-4b35-b32a-f8f2b4ad603d
IMA Classification of Wairakite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca(Si4Al2)O12 · 2H2O
Classification of Wairakite
9.GB.05
9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
B : Chains of single connected 4-membered rings
9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
B : Chains of single connected 4-membered rings
Dana 7th ed.:
77.1.1.3
77.1.1.3
77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
16.9.20
16 : Silicates Containing Aluminum and other Metals
9 : Aluminosilicates of Ca
16 : Silicates Containing Aluminum and other Metals
9 : Aluminosilicates of Ca
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Wrk | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Wrk | Siivolam & Schmid (2007) | Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download |
Wrk | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
Wrk | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Wrk | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30 |
Physical Properties of Wairakite
Vitreous, Dull
Transparency:
Transparent, Translucent
Colour:
Colorless to white
Streak:
White
Hardness:
5½ - 6 on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
Distinct on the {100}
Distinct on the {100}
Parting:
Two sets of possible partings intersecting at 90 degrees
Fracture:
Conchoidal
Density:
2.26 g/cm3 (Measured) 2.272 g/cm3 (Calculated)
Optical Data of Wairakite
Type:
Biaxial (+/-)
RI values:
nα = 1.498(1) nγ = 1.502(1)
2V:
Measured: 70° to 105°
Max Birefringence:
δ = 0.004
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
very weak
Chemistry of Wairakite
Mindat Formula:
Ca(Al2Si4O12) · 2H2O
Common Impurities:
Fe,Mg,Sr,Na,K,Cs
Crystallography of Wairakite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Cell Parameters:
a = 13.692(3) Å, b = 13.643(3) Å, c = 13.560(3) Å
β = 90.5(1)°
β = 90.5(1)°
Ratio:
a:b:c = 1.004 : 1 : 0.994
Unit Cell V:
2,532.91 ų (Calculated from Unit Cell)
Z:
8
Twinning:
Lamellar on {110}, common
Comment:
Space-group setting I2/a.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0000740 | Wairakite | Takeuchi Y, Mazzi F, Haga N, Galli E (1979) The crystal structure of wairakite American Mineralogist 64 993-1001 | 1979 | 0 | 293 | ||
0006990 | Wairakite | Seryotkin Y V, Joswig W, Bakakin V V, Belitsky I A, Fursenko B A (2003) High-temperature crystal structure of wairakite European Journal of Mineralogy 15 475-484 | 2003 | 0 | 293 | ||
0006991 | Wairakite | Seryotkin Y V, Joswig W, Bakakin V V, Belitsky I A, Fursenko B A (2003) High-temperature crystal structure of wairakite European Journal of Mineralogy 15 475-484 | 2003 | 0 | 443 | ||
0006992 | Wairakite | Seryotkin Y V, Joswig W, Bakakin V V, Belitsky I A, Fursenko B A (2003) High-temperature crystal structure of wairakite European Journal of Mineralogy 15 475-484 | 2003 | 0 | 483 | ||
0006993 | Wairakite | Seryotkin Y V, Joswig W, Bakakin V V, Belitsky I A, Fursenko B A (2003) High-temperature crystal structure of wairakite European Journal of Mineralogy 15 475-484 | 2003 | 0 | 673 | ||
0006994 | Wairakite | Seryotkin Y V, Joswig W, Bakakin V V, Belitsky I A, Fursenko B A (2003) High-temperature crystal structure of wairakite European Journal of Mineralogy 15 475-484 | 2003 | 0 | 873 | ||
0014533 | Wairakite | Henderson C M B, Bell A M T, Kohn S C, Page C S (1998) Leucite-pollucite structure-type variability and the structure of a synthetic end-member calcium wairakite (CaAl2Si4O12*2(H2O)) Mineralogical Magazine 62 165-178 | 1998 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.39 Å | (10) |
5.57 Å | (8) |
3.42 Å | (6) |
2.909 Å | (5) |
6.85 Å | (4) |
4.84 Å | (4) |
2.680 Å | (4) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 3b: Earth’s earliest hydrosphere | >4.45 |
14 : Hot springs, geysers, and other subaerial geothermal minerals | |
16 : Low-𝑇 aqueous alteration of Hadean subaerial lithologies (see also #23) | |
17 : Marine authigenic Hadean minerals (see also #24) |
Type Occurrence of Wairakite
Place of Conservation of Type Material:
Geological Survey of New Zealand, Lower Hutt, New Zealand, P13871;
National Museum of Natural History, Washington, D.C., USA, 137192.
National Museum of Natural History, Washington, D.C., USA, 137192.
Geological Setting of Type Material:
rocks in geothermal areas
Associated Minerals at Type Locality:
Reference:
Steiner, A. (1955): Wairakite, the calcium analogue of analcime, a new zeolite mineral. Mineralogical Magazine 30, 691-698.
Synonyms of Wairakite
Other Language Names for Wairakite
Relationship of Wairakite to other Species
Member of:
Other Members of this group:
Alflarsenite | NaCa2Be3Si4O13(OH) · 2H2O | Mon. 2 : P21 |
Amicite | K2Na2Al4Si4O16 · 5H2O | Mon. 2 |
Ammonioleucite | (NH4)(AlSi2O6) | Tet. 4/m : I41/a |
Analcime | Na(AlSi2O6) · H2O | Tric. 1 : P1 |
Bellbergite | (K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2O | Hex. |
Bikitaite | LiAlSi2O6 · H2O | Tric. 1 : P1 |
Boggsite | Ca8Na3(Si,Al)96O192 · 70H2O | Orth. mmm (2/m 2/m 2/m) : Imma |
Brewsterite Subgroup | Zeolite Group. | |
Chabazite-Levyne Subgroup | M[Al2Si4O12] · 6H2O | |
Chiavennite | CaMnBe2Si5O13(OH)2 · 2H2O | Mon. 2/m : P21/b |
Clinoptilolite Subgroup | M3-6(Si30Al6)O72 · 20H2O | |
Cowlesite | CaAl2Si3O10 · 6H2O | Orth. mmm (2/m 2/m 2/m) |
Dachiardite Subgroup | Zeolite Group. | |
Direnzoite | NaK6MgCa2(Al13Si47O120) · 36H2O | Orth. mmm (2/m 2/m 2/m) : Pmmn |
Edingtonite | Ba[Al2Si3O10] · 4H2O | Orth. 2 2 2 : P21 21 21 |
Epistilbite | CaAl2Si6O16 · 5H2O | Mon. |
Erionite Subgroup | M2[Al4Si14O36] · 15H2O | |
Faujasite Subgroup | M3.5[Al7Si17O48] · 32H2O | |
Ferrierite Subgroup | Zeolite Group. | |
Ferrochiavennite | Ca1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2O | Mon. 2/m : P21/b |
Flörkeite | (K3Ca2Na)[Al8Si8O32] · 12H2O | Tric. 1 : P1 |
Garronite Subgroup | ||
Gaultite | Na4Zn2Si7O18 · 5H2O | Orth. mm2 : Fdd2 |
Gismondine Subgroup | Zeolite Group. | |
Gmelinite Subgroup | In 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K. | |
Gobbinsite | Na5(Si11Al5)O32 · 11H2O | Orth. mmm (2/m 2/m 2/m) : Pnma |
Goosecreekite | Ca[Al2Si6O16] · 5H2O | Mon. 2 : P21 |
Gottardiite | Na3Mg3Ca5Al19Si117O272 · 93H2O | Orth. mmm (2/m 2/m 2/m) : Cmca |
Heulandite Subgroup | (Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O | |
Hsianghualite | Ca3Li2(Be3Si3O12)F2 | Iso. 4 3 2 : I41 3 2 |
Kirchhoffite | Cs(BSi2O6) | Tet. 4/mmm (4/m 2/m 2/m) : I41/acd |
Laumontite | CaAl2Si4O12 · 4H2O | Mon. 2/m : B2/m |
Loomisite | Ba[Be2P2O8] · H2O | Mon. m |
Lovdarite | K2Na6Be4Si14O36 · 9H2O | Orth. mm2 |
Maricopaite | Pb7Ca2(Si,Al)48O100 · 32H2O | Orth. |
Martinandresite | Ba2(Al4Si12O32) · 10H2O | Orth. mmm (2/m 2/m 2/m) : Pmmn |
Mazzite Subgroup | Zeolite Group. | |
Merlinoite | (K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O | Orth. mmm (2/m 2/m 2/m) : Immm |
Montesommaite | (K,Na)9Al9Si23O64 · 10H2O | Orth. mm2 : Fdd2 |
Mordenite | (Na2,Ca,K2)4(Al8Si40)O96 · 28H2O | Orth. |
Mutinaite | Na3Ca4Si85Al11O192 · 60H2O | Orth. mmm (2/m 2/m 2/m) : Pnma |
Nabesite | Na2BeSi4O10 · 4H2O | Orth. 2 2 2 : P21 21 21 |
Natrolite Subgroup | A subgroup of the Zeolite Group. | |
Offretite | KCaMg(Si13Al5)O36 · 15H2O | Hex. 6 m2 : P6m2 |
Pahasapaite | Li8(Ca,Li,K)10.5Be24(PO4)24 · 38H2O | Iso. 2 3 : I2 3 |
Parthéite | Ca2(Si4Al4) O15 (OH)2 · 4H2O | Mon. 2/m : B2/b |
Paulingite Subgroup | Paulingite was originally described in 1960. | |
Perlialite | K9Na(Ca,Sr)[Al2Si4O12]6 · 15H2O | Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm |
Phillipsite Subgroup | Zeolite Group. | |
Pollucite | (Cs,Na)2(Al2Si4O12) · 2H2O | Iso. m3m (4/m 3 2/m) : Ia3d |
Roggianite | Ca2Be(OH)2Al2Si4O13 · 2.5H2O | Tet. 4/mmm (4/m 2/m 2/m) : I4/mcm |
Stilbite Subgroup | M6-7[Al8-9Si27-28O72] · nH2O | |
Terranovaite | (Na,Ca)8(Si68Al12)O160 · 29H2O | Orth. |
Thomsonite Subgroup | The large majority of "thomsonite" is thomsonite-Ca. | |
Tschernichite | (Ca,Na2)[Al2Si4O12] · 4-8H2O | Tet. 4/mmm (4/m 2/m 2/m) : P4/mmm |
Tschörtnerite | Ca4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2O | Iso. m3m (4/m 3 2/m) : Fm3m |
UM1996-38-SiO:AlCaHNa | Na-Ca-Al-Si-O-H | |
UM1999-33-SiO:AlHKNa | K7Na5Al12Si20O64 · 24H2O | |
UM2002-40-SiO:AlCaHKMgNa | (Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2O | Tet. 4 2 2 : P41 2 2 |
Unnamed (Ca analogue of Merlinoite) | (Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ? | |
Weinebeneite | CaBe3(PO4)2(OH)2 · 4H2O | Mon. m : Bb |
Wenkite | (Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2O | Hex. 6 m2 : P62m |
Willhendersonite | KCa[Al3Si3O12] · 5H2O | Tric. 1 : P1 |
Yugawaralite | CaAl2Si6O16 · 4H2O | Mon. m : Pb |
Forms a series with:
Common Associates
Associated Minerals Based on Photo Data:
3 photos of Wairakite associated with Pyrite | FeS2 |
2 photos of Wairakite associated with Dmisteinbergite | Ca(Al2Si2O8) |
1 photo of Wairakite associated with Calcite | CaCO3 |
1 photo of Wairakite associated with Quartz | SiO2 |
1 photo of Wairakite associated with Epidote | (CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH) |
1 photo of Wairakite associated with Okenite | Ca10Si18O46 · 18H2O |
1 photo of Wairakite associated with Heulandite Subgroup | (Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O |
Related Minerals - Strunz-mindat Grouping
9.GB.05 | Ammonioleucite | (NH4)(AlSi2O6) |
9.GB.05 | Analcime | Na(AlSi2O6) · H2O |
9.GB.05 | Hsianghualite | Ca3Li2(Be3Si3O12)F2 |
9.GB.05 | Lithosite | K6Al4Si8O25 · 2H2O |
9.GB.05 | Leucite | K(AlSi2O6) |
9.GB.05 | Pollucite | (Cs,Na)2(Al2Si4O12) · 2H2O |
9.GB.05 va | Germanate-analcime | NaAlGe2O6 · H2O |
9.GB.05 va | Germanate-leucite | KAlGe2O6 |
9.GB.05 | Kirchhoffite | Cs(BSi2O6) |
9.GB.05 | Fabrièsite | Na3Al3Si3O12 · 2H2O |
9.GB.10 | Laumontite | CaAl2Si4O12 · 4H2O |
9.GB.15 | Yugawaralite | CaAl2Si6O16 · 4H2O |
9.GB.20 | Roggianite | Ca2Be(OH)2Al2Si4O13 · 2.5H2O |
9.GB.25 | Goosecreekite | Ca[Al2Si6O16] · 5H2O |
9.GB.30 | Montesommaite | (K,Na)9Al9Si23O64 · 10H2O |
9.GB.35 | Parthéite | Ca2(Si4Al4) O15 (OH)2 · 4H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Wairakite
mindat.org URL:
https://www.mindat.org/min-4230.html
Please feel free to link to this page.
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References for Wairakite
Reference List:
Steiner, A. (1955) Wairakite, the calcium analogue of analcime, a new zeolite mineral. Mineralogical Magazine and Journal of the Mineralogical Society, 30 (230) 691-698 doi:10.1180/minmag.1955.030.230.02
Kiss, Klara, Page, Harold T. (1969) Electron Microscopic Identification of Single Crystals of Wairakite, a Rare Component in Clays. Clays and Clay Minerals, 17 (1) 31-35 doi:10.1346/ccmn.1969.0170106
Takéuchi, Yoshio, Mazzi, Fiorenzo, Haga, Nobuhiko, Galli, Ermano (1979) The crystal structure of wairakite. American Mineralogist, 64 (9-10) 993-1001
Henderson, C. M. B., Bell, A. M. T., Kohn, S. C., Page, C. S. (1998) Leucite-pollucite structure-type variability and the structure of a synthetic end-member calcium wairakite (CaAl2Si4O12·2H2O) Mineralogical Magazine, 62 (2) 165-178 doi:10.1180/002646198547558
Neuhoff, Philip S., Stebbins, Jonathan F., Bird, Dennis K. (2003) Si-Al disorder and solid solutions in analcime, chabazite, and wairakite. American Mineralogist, 88 (2) 410-423 doi:10.2138/am-2003-2-317
Localities for Wairakite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Algeria | |
| Marignac (1988) |
Argentina | |
| Tschernich (1992) |
| Vattuone et al. (2001) |
Pablo Rodrigo Leal et al. (2011) | |
Australia | |
| Bottrill et al. (2008) |
Bolivia | |
| Camacho (2014) |
Brazil | |
| Ruiz (2001) |
Canada | |
| Canadian Museum of Nature collection |
| Tschernich (1992) |
| Pe-Piper et al. (2002) |
| GOLD (1972) |
Gold (1969) | |
Chile | |
| Fuentes et al. (2004) |
Czech Republic | |
| Jiří Zachariáš et al. (2014) |
Ecuador | |
| R. S. Bowman and S. E. Delap (Eds.) |
El Salvador | |
| implications for metal transport in natural systems. Journal of volcanology and geothermal research (1) +1 other reference |
Ethiopia | |
| Gebregziabher (1998) +1 other reference |
France | |
| B +1 other reference |
| Mas et al. (2006) |
Germany | |
| Hentschel |
Iceland | |
| Viereck et al. (1982) |
| Tamjidi +1 other reference |
| Lahan (2012) |
| Kristmannsdottir et al. (1978) |
| Franzson et al. (2005, April) |
| Ágústsdóttir et al. (1994) |
Indonesia | |
| ... |
| Etzel et al. (2015) |
Italy | |
| Cardiano et al. (2008) |
| Bird et al. (1984) |
| Lapis (12) |
Japan | |
| Yotaro Seki (1973) |
| INOUE et al. (1991) |
| Onuki et al (1988) |
Yotaro Seki (1973) | |
| Aoki et al. (1980) |
| Alfredo Petrov specimen confirmed by ... +1 other reference |
Yotaro Seki (1973) | |
| Scott et al. (1998) |
| Yotaro Seki (1973) |
| Yotaro Seki (1973) |
| Yotaro Seki (1973) |
| Econ Geol (1984) |
| Harada et al. (1976) |
| Yotaro Seki (1973) +1 other reference |
| Yotaro Seki (1973) +1 other reference |
| Yotaro Seki (1973) |
| Yotaro Seki (1973) +1 other reference |
Knut Eldjarn specimen | |
| Aoki et al. (1980) |
| Yotaro Seki (1973) |
Jordan | |
| Khoury et al. (1985) |
Mexico | |
| Econ Geol (1984) +1 other reference |
| Hinojosa et al. (2005) |
Namibia | |
| Wartha et al. (2006) |
New Zealand | |
| R. Martin collection |
| their origin +1 other reference |
| Courtney et al. (1990) |
| a coincidental trapping of fluids being ... +2 other references |
Mauriohooho | |
| Krupp et al. (1987) |
Browne et al. (1989) | |
Steiner (1955) +3 other references | |
Nicaragua | |
| Darce (1990) |
Philippines | |
| Bird et al. (1984) |
Romania | |
| Kristály et al. (2003) |
| Hirtopanu (2006) +1 other reference |
Russia | |
| Frolova et al. (2010, April) |
| Frolova et al. (2010, April) |
Spain | |
| Strasser et al. (2006) |
Sweden | |
| Rincon (2022) |
Taiwan | |
Bird et al. (1984) | |
Turkey | |
| Helvaci (1998) |
Ukraine | |
| Emetz et al. (2005) |
USA | |
| ... |
| Bird et al. (1984) |
| Van Nostrand Reinholt Press: 371 +3 other references |
| Van Nostrand Reinholt Press: 371 +6 other references |
| Eckel et al. (1997) |
| Eckel et al. (1997) |
| Heinrich et al. (2004) |
| Cole et al. (1984) |
| Castor et al. (2004) |
| Bargar et al. (1997) |
| Micro Probe Vol. 6 No. 5 Fall 1987 |
| Whetten (1965) |
AmMin 50:752 | |
| Donnelly (1962) |
| Micro Probe Vol. 10 N0. 3 Spring '01 |
| Cannon (1975) |
Tschernich (1992) | |
| Cannon (1975) |
| Bargar +1 other reference |
Bird et al. (1984) +1 other reference |
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Toi mine, Izu City, Shizuoka Prefecture, Japan