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Willhendersonite

A valid IMA mineral species
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About WillhendersoniteHide

08208890014946603764314.jpg
Bill Henderson
Formula:
KCa[Al3Si3O12] · 5H2O
Colour:
Colorless, white
Lustre:
Vitreous
Hardness:
3
Specific Gravity:
2.10 - 2.18
Crystal System:
Triclinic
Member of:
Name:
Named in 1984 by Donald R. Peacor, P. J. Dunn, William B. Simmons, E. Tillmans, and R. X. Fischer in honor of William "Bill" A. Henderson Jr. [October 5, 1932 Winthrop, Massachusetts, USA - April 20, 2014 Guilford, Connecticut, USA], chemist with American Cyanamid Company of Stamford, Connecticut (USA). In late 1980, Dr. William A. Henderson, Jr. submitted a specimen to P.J.D. that he had obtained several years earlier from Mr. Gianni Porcellini of Rimini, Italy. Bill was an avid life-long mineral collector and columnist for the Mineralogical Record. He was elected as a member of the Micromounters Hall of Fame in 1997.
Isostructural with:

Unique IdentifiersHide

Mindat ID:
4294
Long-form identifier:
mindat:1:1:4294:5
GUID
(UUID V4):
6e99d892-d10f-48ac-9e09-a7e12ec617f4

IMA Classification of WillhendersoniteHide

Classification of WillhendersoniteHide

9.GD.10

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
D : Chains of 6-membered rings – tabular zeolites
77.1.2.3

77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
16.10.13

16 : Silicates Containing Aluminum and other Metals
10 : Aluminosilicates of Ca and alkalis

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
WhdIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of WillhendersoniteHide

Vitreous
Transparency:
Transparent
Colour:
Colorless, white
Streak:
White
Hardness:
Tenacity:
Very brittle
Cleavage:
Perfect
{100} {010} {001}
Density:
2.10 - 2.18 g/cm3 (Measured)    2.20 g/cm3 (Calculated)

Optical Data of WillhendersoniteHide

Type:
Biaxial (+/-)
RI values:
nα = 1.505(3) nβ = 1.511(3) nγ = 1.517(3)
2V:
Measured: 87° (3), Calculated: 88°
Birefringence:
0.012
Max Birefringence:
δ = 0.012
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
strong

Chemistry of WillhendersoniteHide

Mindat Formula:
KCa[Al3Si3O12] · 5H2O
Common Impurities:
Na

Crystallography of WillhendersoniteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 9.206(2) Å, b = 9.216(2) Å, c = 9.500(4) Å
α = 92.34(3)°, β = 92.70(3)°, γ = 90.12(3)°
Ratio:
a:b:c = 0.999 : 1 : 1.031
Unit Cell V:
808 ų
Z:
2
Twinning:
Complex, by rotation about [111]; reflection across (001); by rotation about [110] or reflection across (110)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0004627WillhendersoniteFischer R X, Kahlenberg V, Lengauer C L, Tillmanns E (2008) Thermal behavior and structural transformation in the chabazite-type zeolite willhendersonite, KCaAl3Si3O12*5H2O American Mineralogist 93 1317-13252008Mayen, Eifel district, Germany0293
0004628WillhendersoniteFischer R X, Kahlenberg V, Lengauer C L, Tillmanns E (2008) Thermal behavior and structural transformation in the chabazite-type zeolite willhendersonite, KCaAl3Si3O12*5H2O American Mineralogist 93 1317-13252008Mayen, Eifel district, Germany0293
0004629WillhendersoniteFischer R X, Kahlenberg V, Lengauer C L, Tillmanns E (2008) Thermal behavior and structural transformation in the chabazite-type zeolite willhendersonite, KCaAl3Si3O12*5H2O American Mineralogist 93 1317-13252008Mayen, Eifel district, Germany0293
0014793WillhendersoniteTillmanns E, Fischer R X, Baur W H (1984) Chabazite-type framework in the new zeolite willhendersonite, KCaAl3Si3O12*5H2O Neues Jahrbuch fur Mineralogie, Monatshefte 1984 547-55819840293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.16 Å(100)
5.18 Å(30)
4.09 Å(40)
3.93 Å(20)
3.71 Å(30)
2.804 Å(50)
2.907 Å(60)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
10 : Basalt-hosted zeolite minerals

Type Occurrence of WillhendersoniteHide

General Appearance of Type Material:
"Trellis-like" twinned aggregates, and as tabular crystals.
Place of Conservation of Type Material:
Smithsonian Institution - NMNH 148655 (holotype) and NMNH148656 (cotype)
Geological Setting of Type Material:
Quaternary basic potassic lavas.
Associated Minerals at Type Locality:
Reference:
Peacor, D.R., Dunn P.J., Simmons W.B., Tillmanns, E., Fischer, R.X. (1984) Willhendersonite, a new zeolite isostructural with chabazite. American Mineralogist 69: 186-189.

Other Language Names for WillhendersoniteHide

Relationship of Willhendersonite to other SpeciesHide

Member of:
Other Members of this group:
AlflarseniteNaCa2Be3Si4O13(OH) · 2H2OMon. 2 : P21
AmiciteK2Na2Al4Si4O16 · 5H2OMon. 2
Ammonioleucite(NH4)(AlSi2O6)Tet. 4/m : I41/a
AnalcimeNa(AlSi2O6) · H2OTric. 1 : P1
Bellbergite(K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2OHex.
BikitaiteLiAlSi2O6 · H2OTric. 1 : P1
BoggsiteCa8Na3(Si,Al)96O192 · 70H2OOrth. mmm (2/m 2/m 2/m) : Imma
Brewsterite SubgroupZeolite Group.
Chabazite-Levyne SubgroupM[Al2Si4O12] · 6H2O
ChiavenniteCaMnBe2Si5O13(OH)2 · 2H2OMon. 2/m : P21/b
Clinoptilolite SubgroupM3-6(Si30Al6)O72 · 20H2O
CowlesiteCaAl2Si3O10 · 6H2OOrth. mmm (2/m 2/m 2/m)
Dachiardite SubgroupZeolite Group.
DirenzoiteNaK6MgCa2(Al13Si47O120) · 36H2OOrth. mmm (2/m 2/m 2/m) : Pmmn
EdingtoniteBa[Al2Si3O10] · 4H2OOrth. 2 2 2 : P21 21 21
EpistilbiteCaAl2Si6O16 · 5H2OMon.
Erionite SubgroupM2[Al4Si14O36] · 15H2O
Faujasite SubgroupM3.5[Al7Si17O48] · 32H2O
Ferrierite SubgroupZeolite Group.
FerrochiavenniteCa1-2Fe[(Si,Al,Be)5Be2O13(OH)2] · 2H2OMon. 2/m : P21/b
Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2OTric. 1 : P1
Garronite Subgroup
GaultiteNa4Zn2Si7O18 · 5H2OOrth. mm2 : Fdd2
Gismondine SubgroupZeolite Group.
Gmelinite SubgroupIn 1997, gmelinite was split into Gmelinite-Ca, Gmelinite-Na and Gmelinite-K.
GobbinsiteNa5(Si11Al5)O32 · 11H2OOrth. mmm (2/m 2/m 2/m) : Pnma
GoosecreekiteCa[Al2Si6O16] · 5H2OMon. 2 : P21
GottardiiteNa3Mg3Ca5Al19Si117O272 · 93H2OOrth. mmm (2/m 2/m 2/m) : Cmca
Heulandite Subgroup(Na/Ca/K)5-6[Al8-9 Si27-28 O72] · nH2O
HsianghualiteCa3Li2(Be3Si3O12)F2Iso. 4 3 2 : I41 3 2
KirchhoffiteCs(BSi2O6)Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
LaumontiteCaAl2Si4O12 · 4H2OMon. 2/m : B2/m
Loomisite Ba[Be2P2O8] · H2OMon. m
LovdariteK2Na6Be4Si14O36 · 9H2OOrth. mm2
MaricopaitePb7Ca2(Si,Al)48O100 · 32H2OOrth.
MartinandresiteBa2(Al4Si12O32) · 10H2OOrth. mmm (2/m 2/m 2/m) : Pmmn
Mazzite SubgroupZeolite Group.
Merlinoite(K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2OOrth. mmm (2/m 2/m 2/m) : Immm
Montesommaite(K,Na)9Al9Si23O64 · 10H2OOrth. mm2 : Fdd2
Mordenite(Na2,Ca,K2)4(Al8Si40)O96 · 28H2OOrth.
MutinaiteNa3Ca4Si85Al11O192 · 60H2OOrth. mmm (2/m 2/m 2/m) : Pnma
NabesiteNa2BeSi4O10 · 4H2OOrth. 2 2 2 : P21 21 21
Natrolite SubgroupA subgroup of the Zeolite Group.
OffretiteKCaMg(Si13Al5)O36 · 15H2OHex. 6 m2 : P6m2
PahasapaiteLi8(Ca,Li,K)10.5Be24(PO4)24 · 38H2OIso. 2 3 : I2 3
ParthéiteCa2(Si4Al4) O15 (OH)2 · 4H2OMon. 2/m : B2/b
Paulingite SubgroupPaulingite was originally described in 1960.
PerlialiteK9Na(Ca,Sr)[Al2Si4O12]6 · 15H2OHex. 6/mmm (6/m 2/m 2/m) : P6/mmm
Phillipsite SubgroupZeolite Group.
Pollucite(Cs,Na)2(Al2Si4O12) · 2H2OIso. m3m (4/m 3 2/m) : Ia3d
RoggianiteCa2Be(OH)2Al2Si4O13 · 2.5H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mcm
Stilbite SubgroupM6-7[Al8-9Si27-28O72] · nH2O
Terranovaite(Na,Ca)8(Si68Al12)O160 · 29H2OOrth.
Thomsonite SubgroupThe large majority of "thomsonite" is thomsonite-Ca.
Tschernichite(Ca,Na2)[Al2Si4O12] · 4-8H2OTet. 4/mmm (4/m 2/m 2/m) : P4/mmm
TschörtneriteCa4(Ca,Sr,K,Ba)3Cu3[Al3Si3O12]4(OH)8 · nH2OIso. m3m (4/m 3 2/m) : Fm3m
UM1996-38-SiO:AlCaHNaNa-Ca-Al-Si-O-H
UM1999-33-SiO:AlHKNaK7Na5Al12Si20O64 · 24H2O
UM2002-40-SiO:AlCaHKMgNa(Mg,Ca,Na,K)7.5(Al12.8Si51.2)O128 · 65H2OTet. 4 2 2 : P41 2 2
Unnamed (Ca analogue of Merlinoite)(Ca,K,Na)5(Ca,Ba)2Al9Si23O64 · 23H2O ?
WairakiteCa(Al2Si4O12) · 2H2OMon. 2/m : B2/m
WeinebeneiteCaBe3(PO4)2(OH)2 · 4H2OMon. m : Bb
Wenkite(Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2OHex. 6 m2 : P62m
YugawaraliteCaAl2Si6O16 · 4H2OMon. m : Pb

Common AssociatesHide

Associated Minerals Based on Photo Data:
12 photos of Willhendersonite associated with Thomsonite-CaNaCa2[Al5Si5O20] · 6H2O
10 photos of Willhendersonite associated with Pyroxene GroupADSi2O6
7 photos of Willhendersonite associated with Flörkeite(K3Ca2Na)[Al8Si8O32] · 12H2O
7 photos of Willhendersonite associated with FluorapatiteCa5(PO4)3F
7 photos of Willhendersonite associated with FluorophlogopiteKMg3(Si3Al)O10F2
7 photos of Willhendersonite associated with Phillipsite-CaCa3(Si10Al6)O32 · 12H2O
5 photos of Willhendersonite associated with ApatiteCa5(PO4)3(Cl/F/OH)
5 photos of Willhendersonite associated with Phillipsite Subgroup
4 photos of Willhendersonite associated with Clinopyroxene Subgroup
4 photos of Willhendersonite associated with Gismondine Subgroup

Related Minerals - Strunz-mindat GroupingHide

9.GD.05Gmelinite-CaCa2(Si8Al4O24] · 11H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.GD.05Gmelinite-KK4(Si8Al4O24) · 11H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.GD.05Gmelinite-NaNa4(Si8Al4O24] · 11H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.GD.10Chabazite-Ca(Ca,K2,Na2)2[Al2Si4O12]2 · 12H2OTric. 1 : P1
9.GD.10Chabazite-K(K2,Ca,Na2,Sr,Mg)2[Al2Si4O12]2 · 12H2OTrig. 3m (3 2/m) : R3m
9.GD.10Chabazite-Na(Na2,K2,Ca,Sr,Mg)2[Al2Si4O12]2 · 12H2OTrig. 3m : R3m
9.GD.10Chabazite-SrSr2[Al2Si4O12]2 · 12H2OTrig. 3m (3 2/m) : R3m
9.GD.10Chabazite-Mg(Mg0.7K0.5Ca0.5Na0.1)[Al3Si9O24] · 10H2O Trig. 3m (3 2/m) : R3m
9.GD.15Lévyne-Ca(Ca,Na2,K2)[Al2Si4O12] · 6H2OTrig. 3m (3 2/m) : R3m
9.GD.15Lévyne-Na(Na2,Ca,K2)[Al2Si4O12] · 6H2OTrig. 3m (3 2/m) : R3m
9.GD.20Bellbergite(K,Ba,Sr)2Sr2Ca2(Ca,Na)4[Al3Si3O12]6 · 30H2OHex.
9.GD.20Erionite-Ca(Ca,K2,Na2)2[Al4Si14O36] · 15H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.GD.20Erionite-K(K2,Ca,Na2)2[Al4Si14O36] · 15H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.GD.20Erionite-Na(Na2,K2,Ca)2[Al4Si14O36] · 15H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.GD.25OffretiteKCaMg(Si13Al5)O36 · 15H2OHex. 6 m2 : P6m2
9.GD.25Wenkite(Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2OHex. 6 m2 : P62m
9.GD.30Faujasite-Ca(Ca,Na2,Mg)3.5[Al7Si17O48] · 32H2OIso. m3m (4/m 3 2/m) : Fd3m
9.GD.30Faujasite-Mg(Mg,Na2,Ca)3.5[Al7Si17O48] · 32H2OIso. m3m (4/m 3 2/m) : Fd3m
9.GD.30Faujasite-Na(Na2,Ca,Mg)3.5[Al7Si17O48] · 32H2OIso. m3m (4/m 3 2/m) : Fd3m
9.GD.35MaricopaitePb7Ca2(Si,Al)48O100 · 32H2OOrth.
9.GD.35Mordenite(Na2,Ca,K2)4(Al8Si40)O96 · 28H2OOrth.
9.GD.40Dachiardite-KK4(Si20Al4O48) · 13H2OMon.
9.GD.40Dachiardite-Ca(Ca,Na2,K2)5Al10Si38O96 · 25H2OMon. 2/m : B2/m
9.GD.40Dachiardite-Na(Na2,Ca,K2)5Al10Si38O96 · 25H2OMon. 2/m : B2/m
9.GD.45EpistilbiteCaAl2Si6O16 · 5H2OMon.
9.GD.50Ferrierite-K(K,Na)5(Si31Al5)O72 · 18H2OOrth. mmm (2/m 2/m 2/m) : Immm
9.GD.50Ferrierite-Mg[Mg2(K,Na)2Ca0.5](Si29Al7)O72 · 18H2OOrth. mmm (2/m 2/m 2/m) : Pnnm
9.GD.50Ferrierite-Na(Na,K)5(Si31Al5)O72 · 18H2OMon. 2/m
9.GD.50Ferrierite-NH4(NH4,Mg0.5)5(Al5Si31O72) · 22H2OOrth. mmm (2/m 2/m 2/m) : Immm
9.GD.55BikitaiteLiAlSi2O6 · H2OTric. 1 : P1

Fluorescence of WillhendersoniteHide

Not fluorescent

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for WillhendersoniteHide

References for WillhendersoniteHide

Reference List:

Localities for WillhendersoniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Styria
    • Südoststeiermark District
      • Bad Gleichenberg
        • Wilhelmsdorf
Walter (1984) +3 other references
Germany
 
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Mayen
Peacor et al. (1984)
in the collection of Christof Schäfer
      • Vordereifel
        • Ettringen
Hentschel (1983) +1 other reference
in the collection of Christof Schäfer
        • Kottenheim
          • Winfeld
in the collection of Christof Schäfer
    • Vulkaneifel
      • Daun
        • Üdersdorf
Blaß et al. (1993)
      • Gerolstein
        • Gerolstein
          • Roth
Blaß et al. (2012)
        • Hillesheim
Hentschel (1993)
        • Hohenfels-Essingen
Personally collected by Günter Frenz
Italy
 
  • Lazio
    • Rieti Province
      • Rieti
        • Santa Rufina
  • Umbria
    • Perugia Province
      • Spoleto
Wheeler et al. (1996) +2 other references
    • Terni Province
      • San Venanzo
Peacor et al. (1984) +4 other references
  • Veneto
Mattioli et al. (2016)
Mattioli et al. (2021)
    • Verona Province
      • Soave
Mattioli et al. (2008) +1 other reference
USA
 
  • Hawaii
    • Honolulu County
      • Oahu Island
        • Honolulu
in the collection of Christof Schäfer
 
矿物 and/or 产地  
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