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Adranosite

A valid IMA mineral species

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Photos of Adranosite (17)

Adranosite Gallery Search Photos of Adranosite

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Adranosite

La Fossa crater, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Adranosite

La Fossa crater, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Adranosite

La Fossa crater, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Adranosite

La Fossa crater, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Adranosite

La Fossa crater, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Adranosite

La Fossa crater, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Adranosite

La Fossa crater, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

Adranosite

La Fossa crater, Vulcano Island, Lipari, Eolie Islands, Metropolitan City of Messina, Sicily, Italy

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About AdranositeHide

Formula:

(NH₄)₄NaAl₂(SO₄)₄Cl(OH)₂

Colour:

Colorless, white

Lustre:

Vitreous

Specific Gravity:

2.15

Crystal System:

Tetragonal

Name:

After the Greek name of the ancient fire god Adranos (Latin: Adranus) who,according to legend, lived under Mount Etna before being driven out by Hephaestus (Latin: Vulcan). Adranos was worshipped all over Sicily, but particularly in the town of Adranus, now named Adrano.

Type Locality:

ⓘ La Fossa crater, Vulcano Island, Lipari, Eolie Islands (Aeolian Islands), Metropolitan City of Messina, Sicily, Italy

The Al analogue of Adranosite-(Fe).

Unique combination of elements. One of a few ammonium-sodium sulfates among acmonidesite, adranosite-(Fe), lecontite, möhnite, and therasiasite.

In the crystal structure there are: (1) NaO₄Cl₂ tetragonal square bipyramids, that have common Cl in corners; (2) AlO₆ octahedra and SO₄ tetrahedra that join to form spiral chains parallel to [001].

Unique IdentifiersHide

Mindat ID:

39324

Long-form identifier:

mindat:1:1:39324:3

GUID
(UUID V4):

0da2ab47-a438-4897-b3c2-0125e50654e9

IMA Classification of AdranositeHide

IMA status:

Approved

Approval year:

2008

Classification of AdranositeHide

Strunz-mindat (2024):

7.BC.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H₂O
C : With medium-sized and large cations

Dana 8th ed.:

30.4.5.

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
4 : Miscellaneous

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Arn	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AdranositeHide

Lustre:

Vitreous

Transparency:

Translucent

Colour:

Colorless, white

Streak:

White

Cleavage:

None Observed

Fracture:

None observed

Density:

2.15(1) g/cm³ (Measured) 2.176 g/cm³ (Calculated)

Comment:

Measured by flotation in a tribromo- methane–trichloromethane mixture. Calculated for the empirical formula.

Optical Data of AdranositeHide

Type:

Uniaxial (-)

RI values:

n_ω = 1.550(1) n_ε = 1.540(1)

Max Birefringence:

δ = 0.010

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

Low

Chemistry of AdranositeHide

Mindat Formula:

(NH₄)₄NaAl₂(SO₄)₄Cl(OH)₂

Elements listed:

Al, Cl, H, N, Na, O, S - search for minerals with similar chemistry

Common Impurities:

Crystallography of AdranositeHide

Crystal System:

Tetragonal

Class (H-M):

4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal

Space Group:

I4₁/acd

Cell Parameters:

a = 18.118(3) Å, c = 11.320(3) Å

Ratio:

a:c = 1 : 0.625

Unit Cell V:

3,715.92 Å³ (Calculated from Unit Cell)

Morphology:

Acicular crystals with pointed terminations. The most common forms are {100}, {110}, and {111}.

Twinning:

None observed.

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0006333	Adranosite	Demartin F, Gramaccioli C M, Campostrini I (2010) Adranosite, (NH4)4NaAl2(SO4)4Cl(OH)2, a new ammonium sulfate chloride from La Fossa Crater, Vulcano, Aeolian Islands, Italy The Canadian Mineralogist 48 315-321		2010	La Fossa Crater, Vulcano, Aeolian Islands, Italy	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Adranosite'
loop_
_publ_author_name
'Demartin F'
'Gramaccioli C M'
'Campostrini I'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 48 
_journal_year 2010
_journal_page_first 315
_journal_page_last 321
_publ_section_title
;
 Adranosite, (NH4)4NaAl2(SO4)4Cl(OH)2, a new ammonium sulfate chloride
 from La Fossa Crater, Vulcano, Aeolian Islands, Italy
;
_database_code_amcsd 0006333
_chemical_compound_source 'La Fossa Crater, Vulcano, Aeolian Islands, Italy'
_chemical_formula_sum 'Na Al2 S4 Cl N4 O18 H18'
_cell_length_a 18.118
_cell_length_b 18.118
_cell_length_c 11.320
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 3715.925
_exptl_crystal_density_diffrn      2.155
_symmetry_space_group_name_H-M 'I 41/a c d'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,1/2+z'
  '1/4-y,3/4-x,3/4+z'
  '3/4-y,1/4-x,1/4+z'
  '1/4+y,3/4+x,3/4-z'
  '3/4+y,1/4+x,1/4-z'
  '1/4+y,3/4-x,1/4-z'
  '3/4+y,1/4-x,3/4-z'
  '1/4-y,3/4+x,1/4+z'
  '3/4-y,1/4+x,3/4+z'
  '1/2+x,-y,z'
  '+x,1/2-y,1/2+z'
  '1/2-x,y,-z'
  '-x,1/2+y,1/2-z'
  '1/2+x,y,1/2-z'
  '+x,1/2+y,-z'
  '1/2-x,-y,1/2+z'
  '-x,1/2-y,+z'
  '1/4+y,1/4+x,1/4+z'
  '3/4+y,3/4+x,3/4+z'
  '1/4-y,1/4-x,1/4-z'
  '3/4-y,3/4-x,3/4-z'
  '1/4-y,1/4+x,3/4-z'
  '3/4-y,3/4+x,1/4-z'
  '1/4+y,1/4-x,3/4+z'
  '3/4+y,3/4-x,1/4+z'
  '-x,y,1/2+z'
  '1/2-x,1/2+y,+z'
  'x,-y,1/2-z'
  '1/2+x,1/2-y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,1/2-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
Na   0.50000   0.25000   0.12500   0.01640
Al   0.30294   0.55294   0.12500   0.01470
S   0.37582   0.39982   0.13783   0.01670
Cl   0.50000   0.25000   0.37500   0.03090
N   0.32267   0.23391   0.37650   0.02690
O1   0.37981   0.48138   0.11043   0.01850
O2   0.31502   0.36716   0.07200   0.02950
O3   0.36366   0.39176   0.26733   0.01910
O4   0.44711   0.36856   0.10786   0.02800
O5   0.26221   0.50000   0.25000   0.01570
H1   0.30130   0.28370   0.39070   0.10000
H2   0.36770   0.23620   0.32780   0.14200
H3   0.33110   0.20750   0.45260   0.12900
H4   0.28350   0.20440   0.33070   0.18500
H5   0.21270   0.50000   0.25000   0.02800
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Na 0.01420 0.01420 0.02090 0.00000 0.00000 0.00000
Al 0.01560 0.01560 0.01270 -0.00040 0.00070 0.00070
S 0.01880 0.01770 0.01360 0.00280 0.00060 -0.00130
Cl 0.03200 0.03200 0.02860 0.00160 0.00000 0.00000
N 0.03610 0.02170 0.02290 0.00790 0.00710 0.00120
O1 0.01890 0.01500 0.02160 0.00070 0.00400 0.00310
O2 0.03320 0.02760 0.02760 -0.00220 -0.01300 -0.00770
O3 0.02240 0.02070 0.01430 0.00390 0.00500 0.00260
O4 0.02650 0.02760 0.03000 0.01250 0.01240 0.00540
O5 0.01430 0.01610 0.01650 0.00000 0.00000 0.00460

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
6.398 Å	(80)
4.530 Å	(86)
3.202 Å	(47)
3.020 Å	(65)
2.980 Å	(100)
2.739 Å	(36)
2.265 Å	(87)
1.902 Å	(44)

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 7: Great Oxidation Event	<2.4
45a : [Sulfates, arsenates, selenates, antimonates]
45b : [Other oxidized fumarolic minerals]
Stage 10b: Anthropogenic minerals	<10 Ka
55 : Anthropogenic mine minerals

Type Occurrence of AdranositeHide

Type Locality:

ⓘ La Fossa crater, Vulcano Island, Lipari, Eolie Islands (Aeolian Islands), Metropolitan City of Messina, Sicily, Italy

General Appearance of Type Material:

Colorless to white sprays of prismatic crystals up to 0.3 mm in length.

Place of Conservation of Type Material:

University of Milan, Italy (#2008-06).

Geological Setting of Type Material:

In an active medium-temperature (~250°C) intracrater fumarole on pyroclastic breccia.

Associated Minerals at Type Locality:

Sassolite	Panichiite	Demicheleite-(I)	Demicheleite-(Cl)	Demicheleite-(Br)
Bismuthinite	Anhydrite	Alunite	Aiolosite

Synonyms of AdranositeHide

Adranosite-(Al)

IMA2008-057

Other Language Names for AdranositeHide

German:Adranosit

Common AssociatesHide

Associated Minerals Based on Photo Data:

3 photos of Adranosite associated with Brontesite	(NH₄)₃PbCl₅
3 photos of Adranosite associated with Alunite	KAl₃(SO₄)₂(OH)₆
3 photos of Adranosite associated with D'Ansite-(Fe)	Na₂₁Fe²⁺(SO₄)₁₀Cl₃
2 photos of Adranosite associated with Realgar	As₄S₄
1 photo of Adranosite associated with Therasiaite	(NH₄)₃KNa₂Fe²⁺Fe³⁺(SO₄)₃Cl₅
1 photo of Adranosite associated with Argesite	(NH₄)₇Bi₃Cl₁₆
1 photo of Adranosite associated with Lucabindiite	(K,NH₄)As₄O₆(Cl,Br)
1 photo of Adranosite associated with Russoite	(NH₄)ClAs₂O₃(H₂O)_0.5

Related Minerals - Strunz-mindat Grouping Hide

7.BC.	Adranosite-(Fe)	(NH₄)₄NaFe³⁺₂(SO₄)₄Cl(OH)₂	Tet. 4/mmm (4/m 2/m 2/m) : I4₁/acd
7.BC.	D'Ansite-(Mn)	Na₂₁Mn²⁺(SO₄)₁₀Cl₃	Iso. 4 3m : I4 3d
7.BC.	Agaite	Pb₃CuTeO₅(OH)₂(CO₃)	Orth. mm2 : Pca2₁
7.BC.	D'Ansite-(Fe)	Na₂₁Fe²⁺(SO₄)₁₀Cl₃	Iso. 4 3m : I4 3d
7.BC.	Acmonidesite	(NH₄,K,Pb)₈NaFe²⁺₄(SO₄)₅Cl₈	Orth. 2 2 2 : C2 2 2₁
7.BC.	Backite	Pb₂AlTeO₆Cl	Trig. 3 2 : P3 1 2
7.BC.	Hagstromite	Pb₈Cu²⁺(Te⁶⁺O₆)₂(CO₃)Cl₄	Orth. mmm (2/m 2/m 2/m) : Ibam
7.BC.	Wildcatite	CaFe³⁺Te⁶⁺O₅(OH)	Trig. 3m (3 2/m) : P3 1m
7.BC.	Franksousaite	PbCu(Se⁶⁺O₄)(OH)₂	Mon. 2/m : P2₁/m
7.BC.	Zincochenite	Pb₄Zn(OH)₆(SO₄)₂	Tric. 1 : P1
7.BC.	Viskontite	Pb₅Cu₂(SO₄)₃(SeO₃)(OH)₆	Orth. mm2 : Pmn2₁
7.BC.05	D'Ansite	Na₂₁Mg(SO₄)₁₀Cl₃	Iso. 4 3m : I4 3m
7.BC.07	Apatelite	Fe₃(SO₄)₂(OH)₅ · 0.5H₂O
7.BC.07	Unnamed (Ba-Fe Vanadate)	Ba, Fe, V, O, H
7.BC.10	Alunite	KAl₃(SO₄)₂(OH)₆	Trig. 3m : R3m
7.BC.10	Ammonioalunite	(NH₄)Al₃(SO₄)₂(OH)₆	Trig.
7.BC.10	Ammoniojarosite	(NH₄)Fe³⁺₃(SO₄)₂(OH)₆	Trig. 3m : R3m
7.BC.10	Argentojarosite	AgFe³⁺₃(SO₄)₂(OH)₆	Trig. 3m : R3m
7.BC.10	Beaverite-(Cu)	Pb(Fe³⁺₂Cu)(SO₄)₂(OH)₆	Trig. 3m (3 2/m) : R3m
7.BC.10	Dorallcharite	TlFe³⁺₃(SO₄)₂(OH)₆	Trig. 3m (3 2/m) : R3m
7.BC.10	Huangite	Ca_0.5Al₃(SO₄)₂(OH)₆	Trig. 3m (3 2/m) : R3m
7.BC.10	Hydroniumjarosite	(H₃O)Fe³⁺₃(SO₄)₂(OH)₆	Trig. 3m (3 2/m) : R3m
7.BC.10	Jarosite	KFe³⁺₃(SO₄)₂(OH)₆	Trig. 3m (3 2/m) : R3m
7.BC.10	Natroalunite-2c	(Na,Ca_0.5,K)Al₃(SO₄)₂(OH)₆	Trig. 3m (3 2/m) : R3m
7.BC.10	Natroalunite	NaAl₃(SO₄)₂(OH)₆	Trig. 3m : R3m
7.BC.10	Natrojarosite	NaFe₃(SO₄)₂(OH)₆	Trig. 3m : R3m
7.BC.10	Osarizawaite	Pb(Al₂Cu²⁺)(SO₄)₂(OH)₆	Trig. 3m (3 2/m) : R3m
7.BC.10	Plumbojarosite	Pb_0.5Fe³⁺₃(SO₄)₂(OH)₆	Trig. 3m (3 2/m) : R3m
7.BC.10	Schlossmacherite	(H₃O)Al₃(SO₄)₂(OH)₆	Trig. 3m (3 2/m) : R3m
7.BC.10	Walthierite	Ba_0.5Al₃(SO₄)₂(OH)₆	Trig.
7.BC.10	Beaverite-(Zn)	Pb(Fe³⁺₂Zn)(SO₄)₂(OH)₆	Trig. 3m (3 2/m) : R3m
7.BC.15	Ye'elimite	Ca₄Al₆(SO₄)O₁₂	Iso. 4 3 2 : I4₁ 3 2
7.BC.20	Atlasovite	K(BiO)Cu₆Fe³⁺(SO₄)₅O₃Cl	Tet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.20	Nabokoite	KCu₇(SO₄)₅(Te⁴⁺O₃)OCl	Tet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.20	Puninite	Na₂Cu₃O(SO₄)₃	Mon. 2/m : B2/b
7.BC.25	Chlorothionite	K₂Cu(SO₄)Cl₂	Orth. mmm (2/m 2/m 2/m) : Pnma
7.BC.30	Euchlorine	KNaCu₃(SO₄)₃O	Mon. 2/m
7.BC.30	Fedotovite	K₂Cu₃(SO₄)₃O	Mon. 2/m : B2/b
7.BC.35	Kamchatkite	KCu₃(SO₄)₂OCl	Orth. mmm (2/m 2/m 2/m) : Pnma
7.BC.40	Piypite	K₄Cu₄O₂(SO₄)₄ · (Na,Cu)Cl	Tet. 4 : I4
7.BC.45	Klyuchevskite	K₃Cu₃(Fe³⁺,Al)(SO₄)₄O₂	Mon. 2
7.BC.45	Alumoklyuchevskite	K₃Cu₃(Al,Fe³⁺)(SO₄)₄O₂	Tric. 1 : P1
7.BC.45	Belousovite	KZn(SO₄)Cl	Mon. 2/m : P2₁/b
7.BC.47	Müllerite	Pb₂Fe³⁺(Te⁶⁺O₆)Cl	Trig. 3 2 : P3₁ 1 2
7.BC.50	Caledonite	Pb₅Cu₂(SO₄)₃(CO₃)(OH)₆	Orth. mm2 : Pmn2₁
7.BC.50	Elasmochloite	Na₃Cu₆BiO₄(SO₄)₅	Mon. 2/m
7.BC.52	Eleomelanite	(K₂Pb)Cu₄O₂(SO₄)₄	Mon. 2/m
7.BC.55	Wherryite	Pb₇Cu₂(SO₄)₄(SiO₄)₂(OH)₂	Mon. 2/m : B2/m
7.BC.55	Falgarite	K₄(VO)₃(SO₄)₅	Mon. 2/m : B2/b
7.BC.57	Krasheninnikovite	KNa₂CaMg(SO₄)₃F	Hex. 6/mmm (6/m 2/m 2/m) : P6₃/mcm
7.BC.60	Mammothite	Pb₆Cu₄AlSb⁵⁺O₂(OH)₁₆Cl₄(SO₄)₂	Mon. 2 : B2
7.BC.60	Wulffite	K₃NaCu₄O₂(SO₄)₄	Orth. mm2
7.BC.60	Parawulffite	K₅Na₃Cu₈O₄(SO₄)₈	Mon. 2/m : P2/b
7.BC.62	Shuvalovite	K₂(Ca₂Na)(SO₄)₃F	Orth. mmm (2/m 2/m 2/m) : Pnma
7.BC.65	Linarite	PbCu(SO₄)(OH)₂	Mon. 2/m : P2₁/m
7.BC.65	Schmiederite	Pb₂Cu₂(Se⁶⁺O₄)(Se⁴⁺O₃)(OH)₄	Mon. 2/m : P2₁/m
7.BC.65	Munakataite	Pb₂Cu₂(Se⁴⁺O₃)(SO₄)(OH)₄	Mon. 2/m : P2₁/m
7.BC.65	Therasiaite	(NH₄)₃KNa₂Fe²⁺Fe³⁺(SO₄)₃Cl₅	Mon. m : Bb
7.BC.65	Saccoite	Ca₂Mn³⁺₂F(OH)₈ · 0.5(SO₄)	Tet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.70	Chenite	Pb₄Cu(SO₄)₂(OH)₆	Tric. 1 : P1
7.BC.75	Krivovichevite	Pb₃Al(OH)₆(SO₄)(OH)	Trig. 3m : R3c
7.BC.80	Anhydrokainite	KMg(SO₄)Cl

Fluorescence of AdranositeHide

In UV light:

Not fluorescent.

Other InformationHide

Notes:

The mineral is not hygroscopic and is stable in open air.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for AdranositeHide

mindat.org URL:

https://www.mindat.org/min-39324.html
Please feel free to link to this page.

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for AdranositeHide

Reference List:

Ciriotti, M.E., Fascio, L. & Pasero, M. (2009) Italian Type Minerals. Edizioni Plus, Università di Pisa, Pisa, Italy, 357 pp.

Demartin, F., Gramaccioli, C.M., Campostrini, I. (2010) Adranosite, (NH₄)₄NaAl₂(SO4)Cl(OH)₂, a new ammonium sulfate chloride from La Fossa crater, Vulcano, Aeolian Islands, Italy. The Canadian Mineralogist, 48, 315-321.

(2023) Adranosite. Handbook of Mineralogy. Mineralogical Society of America

Localities for AdranositeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Germany
North Rhine-Westphalia Cologne Aachen Alsdorf ⓘ Anna mine	Witzke et al. (2015)

Hungary
Baranya County Pécs District ⓘ Pécs-Vasas	2015 May 16-19 +2 other references

Italy
Campania Naples Pozzuoli Solfatara di Pozzuoli ⓘ "Bocca Grande" fumarole	Russo et al. (2017)
Sicily Metropolitan City of Messina Eolie Islands (Aeolian Islands) Lipari Vulcano Island ⓘ La Fossa crater (TL)	Demartin et al. (2010)

Adranosite

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