SUPPORT US. If mindat.org is important to you, click here to donate to our Fall 2019 fundraiser!
登录注册
主页关于 MindatMindat手册Mindat的历史版权Who We Are联系我们于 Mindat.org刊登广告
捐赠给 MindatCorporate Sponsorship赞助板页已赞助的板页在 Mindat刊登 广告的广告商于 Mindat.org刊登广告
Learning CenterWhat is a mineral?The most common minerals on earthInformation for EducatorsMindat ArticlesThe Elements书籍及杂志
搜索矿物的性质搜索矿物的化学Advanced Locality Search随意显示任何一 种矿物Random Locality使用minID搜索邻近产地Search Articles搜索词汇表更多搜索选项
搜索:
矿物名称:
地区产地名称:
关键字:
 
Mindat手册添加新照片Rate Photos产区编辑报告Coordinate Completion Report添加词汇表项目
Mining Companies统计会员列表Mineral Museums矿物展及活动The Mindat目录表设备设置
照片搜索Photo Galleries今天最新的照片昨天最新的照片用户照片相集过去每日精选照片相集Mineral Photography

Adranosite-(Fe)

This page is currently not sponsored. Click here to sponsor this page.
Hide all sections | Show all sections

About Adranosite-(Fe)Hide

Formula:
(NH4)4NaFe3+2(SO4)4Cl(OH)2
Alternative crystal-chemical formula, emphasising the presence of -Na-Cl-Na-Cl- chains in the structure:(NH4)4Fe3+2(OH)2(SO4)4.NaCl; some NH4 may be replaced by K.
Colour:
pale yellow
Lustre:
Vitreous
Specific Gravity:
2.18
Crystal System:
Tetragonal
Name:
For the relation to Adranosite-(Al).
Isostructural with:
The Fe3+ analogue of Adranosite-(Al). Chemically related to acmonidesite and therasiasite.

Originally described as an anthropogenic phase that has formed on a burning coal dump ["Unnamed (NH4-Fe-Na-Cl Sulphate)"]. Subsequently found in a natural fumarole.
Structurally, an unusual salt inclusion phase (Kolitsch & Brandstätter, 2007; Mitolo et al., 2013).

In the crystal structure, beside the NaCl chains, there are:
- helicoidal [FeO4(OH)2SO4]n chains
- NaO4Cl2 square tetragonal bipyramids that share Cl-bearing corners
- NH4+ ions are located in cages, and the ammonium-bearing sites have the coordination number 9.

Synonymous with UM2011-17-SOCl:FeHNNa.


Classification of Adranosite-(Fe)Hide

Approved
Approval Year:
2011
7.BC.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations

Physical Properties of Adranosite-(Fe)Hide

Vitreous
Colour:
pale yellow
Streak:
white
Cleavage:
Perfect
{001}
Density:
2.18(1) g/cm3 (Measured)    2.195 g/cm3 (Calculated)

Optical Data of Adranosite-(Fe)Hide

Type:
Uniaxial (-)
RI values:
nω = 1.580(1) nε = 1.570(1)
Max Birefringence:
δ = 0.010
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemical Properties of Adranosite-(Fe)Hide

Formula:
(NH4)4NaFe3+2(SO4)4Cl(OH)2

Alternative crystal-chemical formula, emphasising the presence of -Na-Cl-Na-Cl- chains in the structure:(NH4)4Fe3+2(OH)2(SO4)4.NaCl; some NH4 may be replaced by K.
IMA Formula:
(NH4)4NaFe2(SO4)4Cl(OH)2
Common Impurities:
K,Al

Crystallography of Adranosite-(Fe)Hide

Crystal System:
Tetragonal
Class (H-M):
4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Space Group:
I41/acd
Cell Parameters:
a = 18.261(2) Å, c = 11.562(1) Å
Ratio:
a:c = 1 : 0.633
Unit Cell V:
3,855.51 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Acicular.
Twinning:
none
Comment:
Cell of anthropogenic material: a = 18.259(3), c = 11.557(2) A (Kolitsch and Brandstätter, 2007).

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.134 Å(100)
6.462 Å(36)
4.569 Å(83)
3.232 Å(29)
3.047 Å(79)
2.891 Å(11)
2.156 Å(7)
1.697 Å(7)

Occurrences of Adranosite-(Fe)Hide

Paragenetic Mode(s):
•  Fumarolic

Type Occurrence of Adranosite-(Fe)Hide

General Appearance of Type Material:
acicular crystals up to 1 mm in length, in aggregates; probable forms (the most common):{100}, {110}, and {111}
Place of Conservation of Type Material:
Dipartimento di Chimica Strutturale e Stereochimica Inorganica, Università degli Studi di Milano, sample number 2010-02)
C.L. Garavelli Museum, Dipartimento Geomineralogico, Università di Bari.
Geological Setting of Type Material:
pyroclasic breccia among fumaroles
Associated Minerals at Type Locality:

Synonyms of Adranosite-(Fe)Hide

Other Language Names for Adranosite-(Fe)Hide

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Adranosite-(Fe) associated with Clairite(NH4)2Fe3(SO4)4(OH)3 · 3H2O
1 photo of Adranosite-(Fe) associated with MetavoltineNa6K2FeFe6(SO4)12O2 · 18H2O

Related Minerals - Nickel-Strunz GroupingHide

7.BC.Adranosite(NH4)4NaAl2(SO4)4Cl(OH)2Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.BC.05D'AnsiteNa21Mg(SO4)10Cl3Iso.
7.BC.10AluniteKAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Ammonioalunite(NH4)Al3(SO4)2(OH)6Trig.
7.BC.10Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10DorallchariteTlFe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10HuangiteCa0.5Al3(SO4)2(OH)6Trig.
7.BC.10Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10JarositeKFe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Natroalunite-2c(Na,Ca0.5,K)Al3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10NatroaluniteNaAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10PlumbojarositePb0.5Fe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig.
7.BC.10WalthieriteBa0.5Al3(SO4)2(OH)6Trig.
7.BC.10Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.15Ye'elimiteCa4Al6(SO4)O12Iso.
7.BC.20AtlasoviteK(BiO)Cu6Fe3+(SO4)5O3ClTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.20NabokoiteKCu7(SO4)5(Te4+O3)OClTet.
7.BC.25ChlorothioniteK2Cu(SO4)Cl2Orth. mmm (2/m 2/m 2/m) : Pnma
7.BC.30EuchlorineKNaCu3(SO4)3OMon.
7.BC.30FedotoviteK2Cu3(SO4)3OMon. 2/m : B2/b
7.BC.35KamchatkiteKCu3(SO4)2OClOrth. mmm (2/m 2/m 2/m) : Pnma
7.BC.40PiypiteK4Cu4O2(SO4)4 · (Na,Cu)ClTet.
7.BC.45KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2Mon.
7.BC.45AlumoklyuchevskiteK3Cu3(Al,Fe3+)(SO4)4O2Tric. 1 : P1
7.BC.50CaledonitePb5Cu2(SO4)3(CO3)(OH)6Orth. mm2 : Pmn21
7.BC.55WherryitePb7Cu2(SO4)4(SiO4)2(OH)2Mon. 2/m : B2/m
7.BC.60MammothitePb6Cu4AlSb5+O2(OH)16Cl4(SO4)2Mon. 2 : B2
7.BC.65LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
7.BC.65SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon.
7.BC.65MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
7.BC.70ChenitePb4Cu(SO4)2(OH)6Tric. 1 : P1
7.BC.75KrivovichevitePb3Al(OH)6(SO4)(OH)Trig. 3m : R3c
7.BC.80AnhydrokainiteKMg(SO4)Cl

Fluorescence of Adranosite-(Fe)Hide

Other InformationHide

Special Storage/
Display Requirements:
stable in open air
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Adranosite-(Fe)Hide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
U. Kolitsch and F. Brandstätter (2007) A new salt-inclusion sulphate phase from a burning coal dump: crystal-structural, chemical and Raman-spectroscopic characterisation. 16th Croatian-Slovenian Crystallographic Meeting, Petrčane, Croatia, June 13-17, 2007; Book of Abstracts, 12.
Mitolo, D., Demartin, F., Garavelli, A., Campostrini, I., Pinto D., Gramaccioli, C. M., Acquafredda, P., Kolitsch, U. (2011) New fumarole minerals at Vulcano: Adranosite-(Fe). Poster, Geoitalia 2011, http://www.geoitalia.org/index.php?action=folder_list&lang=it&folder_id=310
Demartin, F., Garavelli, A., Campostrini, I., Gramaccioli, C.M., Kolitsch, U., Mitolo, D. and Pinto, D. (2011) Adranosite-(Fe), IMA 2011-006. CNMNC Newsletter No. 9, August 2011, page 2539; Mineralogical Magazine, 75, 2535-2540.
D. Mitolo, F. Demartin, A. Garavelli, I. Campostrini, D. Pinto, C. M. Gramaccioli, P. Acquafredda and U. Kolitsch (2013): Adranosite-(Fe), (NH4)4NaFe2(SO4)4Cl(OH)2, a new ammonium sulfate chloride from La Fossa Crater, Vulcano, Aeolian Islands, Italy. Can. Mineral. 51, 57-66.

Internet Links for Adranosite-(Fe)Hide

Localities for Adranosite-(Fe)Hide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Germany
 
  • North Rhine-Westphalia
    • Cologne
      • Aachen
        • Alsdorf
U. Kolitsch and F. Brandstätter (2007): A new salt-inclusion sulphate phase from a burning coal dump: crystal-structural, chemical and Raman-spectroscopic characterisation. 16th Croatian-Slovenian Crystallographic Meeting, Petrčane, Croatia, June 13-17, 2007; Book of Abstracts, 12; D. Mitolo, F. Demartin, A. Garavelli, I. Campostrini, D. Pinto, C. M. Gramaccioli, P. Acquafredda and U. Kolitsch (2013): Adranosite-(Fe), (NH4)4NaFe2(SO4)4Cl(OH)2, a new ammonium sulfate chloride from La Fossa Crater, Vulcano, Aeolian Islands, Italy. Can. Mineral. 51, 57-66; Witzke, T., de Wit, F., Kolitsch, U. and Blaß, G. (2015): Mineralogy of the Burning Anna I Coal Mine Dump, Alsdorf, Germany. Chapter 7, pp. 203-240, in: Stracher, G. B., Prakash, A. and Sokol, E. V.: Coal and Peat Fires: A Global Perspective, Volume 3: Case Studies - Coal Fires, Elsevier, 786 pp.
    • The Ruhr
      • Oberhausen
http://www.wagnerul.de/Haldenbrand.html (visual ID)
Hungary
 
  • Baranya County
    • Komló
Fehér B.-2014 HOM Miskolc
Italy
 
  • Campania
    • Naples
      • Pozzuoli
- Russo, M., Campostrini, I., Demartin, F. (2017): I minerali di origine fumarolica dei Campi Flegrei: Solfatara di Pozzuoli (Napoli) e dintorni. Micro, 15, 122-192.
        • Solfatara di Pozzuoli
- Russo, M., Campostrini, I., Demartin, F. (2017): I minerali di origine fumarolica dei Campi Flegrei: Solfatara di Pozzuoli (Napoli) e dintorni. Micro, 15, 122-192.
  • Sicily
    • Messina Province
      • Eolie Islands (Aeolian Islands)
        • Lipari
          • Vulcano Island
Mitolo, D., Demartin, F., Garavelli, A., Campostrini, I., Pinto D., Gramaccioli, C. M., Acquafredda, P., Kolitsch, U. (2011): New fumarole minerals at Vulcano: Adranosite-(Fe). Poster, Geoitalia 2011; Demartin, F., Garavelli, A., Campostrini, I., Gramaccioli, C.M., Kolitsch, U., Mitolo, D. and Pinto, D. (2011) Adranosite-(Fe), IMA 2011-006. CNMNC Newsletter No. 9, August 2011, page 2539; Mineralogical Magazine, 75, 2535-2540; D. Mitolo, F. Demartin, A. Garavelli, I. Campostrini, D. Pinto, C. M. Gramaccioli, P. Acquafredda and U. Kolitsch (2013): Adranosite-(Fe), (NH4)4NaFe2(SO4)4Cl(OH)2, a new ammonium sulfate chloride from La Fossa Crater, Vulcano, Aeolian Islands, Italy. Can. Mineral. 51, 57-66.
USA
 
  • Ohio
    • Huron Co.
      • Huron River
Dr Pete Richards
 
矿物 and/or 产地  
版权所有© mindat.org1993年至2019年,除了规定的地方。 Mindat.org全赖于全球数千个以上成员和支持者们的参与。
隐私政策 - 条款和条款细则 - 联络我们 Current server date and time: 2019.12.13 15:14:38 Page generated: 2019.12.9 09:41:43
Go to top of page