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Chlorothionite

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About ChlorothioniteHide

Formula:
K2Cu(SO4)Cl2
Colour:
Bright blue.
Hardness:
Specific Gravity:
2.67
Crystal System:
Orthorhombic
Name:
In allusion to the chemical composition, containing CHLORine and sulphur (THIO-).
This page provides mineralogical data about Chlorothionite.


Classification of ChlorothioniteHide

Approved, 'Grandfathered' (first described prior to 1959)
7.BC.25

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations
30.1.11.1

30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p>2:1
26.6

26 : Sulphates with Halide

Physical Properties of ChlorothioniteHide

Colour:
Bright blue.
Hardness:
2½ on Mohs scale
Density:
2.67 g/cm3 (Measured)    
Comment:
Measured values on artificial crystals.

Optical Data of ChlorothioniteHide

Type:
Biaxial (+)

Chemical Properties of ChlorothioniteHide

Formula:
K2Cu(SO4)Cl2

Crystallography of ChlorothioniteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pnma
Cell Parameters:
a = 7.73 Å, b = 6.07 Å, c = 16.29 Å
Ratio:
a:b:c = 1.273 : 1 : 2.684
Unit Cell V:
764.34 ų (Calculated from Unit Cell)
Morphology:
Crystalline incrustations.

Type Occurrence of ChlorothioniteHide

General Appearance of Type Material:
Bright blue crystalline incrustations.
Geological Setting of Type Material:
Active volcanic fumaroles.

Other Language Names for ChlorothioniteHide

Related Minerals - Nickel-Strunz GroupingHide

7.BC.Adranosite-(Fe)(NH4)4NaFe3+2(SO4)4Cl(OH)2Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.BC.Adranosite(NH4)4NaAl2(SO4)4Cl(OH)2Tet. 4/mmm (4/m 2/m 2/m) : I41/acd
7.BC.05D'AnsiteNa21Mg(SO4)10Cl3Iso.
7.BC.10AluniteKAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Ammonioalunite(NH4)Al3(SO4)2(OH)6Trig.
7.BC.10Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10DorallchariteTlFe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10HuangiteCa0.5Al3(SO4)2(OH)6Trig.
7.BC.10Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10JarositeKFe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Natroalunite-2c(Na,Ca0.5,K)Al3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10NatroaluniteNaAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10PlumbojarositePb0.5Fe3+3(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.10Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig.
7.BC.10WalthieriteBa0.5Al3(SO4)2(OH)6Trig.
7.BC.10Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Trig. 3m (3 2/m) : R3m
7.BC.15Ye'elimiteCa4Al6(SO4)O12Iso.
7.BC.20AtlasoviteK(BiO)Cu6Fe3+(SO4)5O3ClTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
7.BC.20NabokoiteKCu7(SO4)5(Te4+O3)OClTet.
7.BC.30EuchlorineKNaCu3(SO4)3OMon.
7.BC.30FedotoviteK2Cu3(SO4)3OMon. 2/m : B2/b
7.BC.35KamchatkiteKCu3(SO4)2OClOrth. mmm (2/m 2/m 2/m) : Pnma
7.BC.40PiypiteK4Cu4O2(SO4)4 · (Na,Cu)ClTet.
7.BC.45KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2Mon.
7.BC.45AlumoklyuchevskiteK3Cu3(Al,Fe3+)(SO4)4O2Tric. 1 : P1
7.BC.50CaledonitePb5Cu2(SO4)3(CO3)(OH)6Orth. mm2 : Pmn21
7.BC.55WherryitePb7Cu2(SO4)4(SiO4)2(OH)2Mon. 2/m : B2/m
7.BC.60MammothitePb6Cu4AlSb5+O2(OH)16Cl4(SO4)2Mon. 2 : B2
7.BC.65LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
7.BC.65SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon.
7.BC.65MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
7.BC.70ChenitePb4Cu(SO4)2(OH)6Tric. 1 : P1
7.BC.75KrivovichevitePb3Al(OH)6(SO4)(OH)Trig. 3m : R3c
7.BC.80AnhydrokainiteKMg(SO4)Cl

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

26.1KogarkoiteNa3(SO4)FMon.
26.2SulphohaliteNa6(SO4)2FClIso. m3m (4/m 3 2/m)
26.3SchaireriteNa21(SO4)7ClF6Trig. 3m (3 2/m)
26.4GaleiteNa15(SO4)5F4ClTrig.
26.5ConnelliteCu19(SO4)(OH)32Cl4 · 3H2OHex. 6 m2 : P62c
26.7KamchatkiteKCu3(SO4)2OClOrth. mmm (2/m 2/m 2/m) : Pnma
26.8SpangoliteCu6Al(SO4)(OH)12Cl · 3H2OTrig. 3m : P3 1c
26.9AubertiteCuAl(SO4)2Cl · 14H2OTric. 1
26.10Magnesioaubertite(Mg,Cu)Al(SO4)2Cl · 14H2O
26.11Svyazhinite(Mg,Mn2+,Ca)(Al,Fe3+)(SO4)2F · 14H2OTric.
26.12D'AnsiteNa21Mg(SO4)10Cl3Iso.
26.13AnhydrokainiteKMg(SO4)Cl
26.14KainiteKMg(SO4)Cl · 3H2OMon. 2/m : B2/m
26.15Mosesite(Hg2N)(Cl,SO4,MoO4) · H2OIso.
26.16Kleinite(Hg2N)(Cl,SO4) · nH2OHex. 6/mmm (6/m 2/m 2/m) : P63/mmc
26.17WilcoxiteMgAl(SO4)2F · 17H2OTric. 1 : P1
26.18CreediteCa3SO4Al2F8(OH)2 · 2H2OMon. 2/m : B2/b
26.19LannoniteMg2Ca4Al4(SO4)8F8 · 24H2O Tet. 4/m : I4/m
26.20Chukhrovite-(Y)Ca3(Y,Ce)(AlF6)2(SO4)F · 10H2OIso.
26.21Chukhrovite-(Ce)Ca3(Ce,Y)(AlF6)2(SO4)F · 10H2OIso.
26.22GrandreefitePb2(SO4)F2Mon. 2/m
26.23PseudograndreefitePb6(SO4)F10Orth. 2 2 2 : F2 2 2
26.24SundiusitePb10(SO4)O8Cl2Mon.
26.25CaracoliteNa3Pb2(SO4)3ClMon.
26.26MammothitePb6Cu4AlSb5+O2(OH)16Cl4(SO4)2Mon. 2 : B2
26.27AtlasoviteK(BiO)Cu6Fe3+(SO4)5O3ClTet. 4/mmm (4/m 2/m 2/m) : P4/ncc
26.28XitieshaniteFe3+(SO4)Cl · 6H2OMon. 2/m : P21/b
26.29NabokoiteKCu7(SO4)5(Te4+O3)OClTet.

Other InformationHide

Notes:
Soluble in water.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for ChlorothioniteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Scacchi (1872) Acc. Napoli, Rendus: 203.
Bellanca (1946) Periodico de Mineralogia-Roma: 15: 33 (artificial crystals).
Zambonini, Ferruccio (1910) Mineralogia Vesuviana. 368 pp., Naples: 329 (artificial crystals).
Goldschmidt, V. (1913) Atlas der Krystallformen. 9 volumes, atlas, and text: vol. 2: 2: 151 (artificial crystals).
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 547.
Zeitschrift für Kristallographie: 192: 1-52.

Internet Links for ChlorothioniteHide

Localities for ChlorothioniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Italy (TL)
 
  • Campania
    • Naples
      • Somma-Vesuvius Complex
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 547; Lapis (1994): 5 p.13-23,58.
Russia
 
  • Kamchatka Krai
Pekov, I. V., Zelenski, M. E., Zubkova, N. V., Yapaskurt, V. O., Chukanov, N. V., Belakovskiy, D. I., & Pushcharovsky, D. Y. (2012). Calciolangbeinite, K2Ca2 (SO4) 3, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 76(3), 673-682
      • Great Fissure eruption (Main Fracture)
        • Northern Breakthrough (North Breach)
          • Second scoria cone
Pekov, I.V., Zubkova, N.V., Yapaskurt, V.O., Lykova, I.S., Belakovskiy, D.I., Vigasina, M.F., Sidorov, E.G., Britvin, S.N., Pushscharovsky, D.Yu. (2015): New zinc and potassium chlorides from fumaroles of the Tolbachik volcano, Kamchatka, Russia: mineral data and crystal chemistry. I. Mellizinkalite, K3Zn2Cl7. European Journal of Mineralogy, 27, 247-253.
Pekov, I. V., Zelenski, M. E., Zubkova, N. V., Yapaskurt, V. O., Chukanov, N. V., Belakovskiy, D. I., & Pushcharovsky, D. Y. (2012). Calciolangbeinite, K2Ca2 (SO4) 3, a new mineral from the Tolbachik volcano, Kamchatka, Russia. Mineralogical Magazine, 76(3), 673-682.
 
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