Macfallite
A valid IMA mineral species
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About Macfallite
Formula:
Ca2Mn3+3(SiO4)(Si2O7)(OH)3
Mn may be replaced by minor Al.
Colour:
Reddish-brown, maroon, dull pink
Lustre:
Sub-Adamantine, Silky
Hardness:
5
Specific Gravity:
3.43
Crystal System:
Monoclinic
Name:
Named in 1979 by Paul (Paulus) Brian Moore, Jun Ito, and Ian M. Steele in honor of Russell Patterson MacFall [1 September 1903 Indianapolis, Indiana, USA - 6 September 1983 Coronado, California, USA] editor for Chicago Tribune newspaper and, earlier, for other newspapers. Russ was an amateur mineralogist interested in systematic mineralogy and an author of six books on popular mineralogy, paleontology, and geology. Russ was also a specialist in the minerals of the region where macfallite was first discovered.
This page provides mineralogical data about Macfallite.
Unique Identifiers
Mindat ID:
2508
Long-form identifier:
mindat:1:1:2508:5
GUID
(UUID V4):
(UUID V4):
8ceeebbe-2136-4a15-861d-310a3fea6b20
IMA Classification of Macfallite
Approved
Approval year:
1974
Classification of Macfallite
9.BG.15
9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
58.2.3.2
58 : SOROSILICATES Insular, Mixed, Single, and Larger Tetrahedral Groups
2 : Insular, Mixed, Single, and Larger Tetrahedral Groups with cations in [6] and higher coordination; single and double groups (n = 1, 2)
58 : SOROSILICATES Insular, Mixed, Single, and Larger Tetrahedral Groups
2 : Insular, Mixed, Single, and Larger Tetrahedral Groups with cations in [6] and higher coordination; single and double groups (n = 1, 2)
16.16.20
16 : Silicates Containing Aluminum and other Metals
16 : Aluminosilicates of Mn
16 : Silicates Containing Aluminum and other Metals
16 : Aluminosilicates of Mn
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Mcf | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Macfallite
Sub-Adamantine, Silky
Transparency:
Transparent, Translucent
Colour:
Reddish-brown, maroon, dull pink
Streak:
Brown with a reddish tint
Hardness:
5 on Mohs scale
Cleavage:
Perfect
{001}
{001}
Density:
3.43(2) g/cm3 (Measured) 3.53 g/cm3 (Calculated)
Optical Data of Macfallite
Type:
Biaxial (+/-)
RI values:
nα = 1.773 - 1.775 nβ = 1.795 nγ = 1.810 - 1.815
2V:
Measured: 86° , Calculated: 78° to 88°
Max Birefringence:
δ = 0.037 - 0.040
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
r < v medium
Pleochroism:
Visible
Comments:
X = colorless to yellow; Y = light brown; Z = dark brown to reddish brown.
Comments:
2V(meas.) = Very large
Chemistry of Macfallite
Mindat Formula:
Ca2Mn3+3(SiO4)(Si2O7)(OH)3
Mn may be replaced by minor Al.
Mn may be replaced by minor Al.
Common Impurities:
Ti,Al,Fe,Cr,V,Cu,Mg,K,Na,H2O
Crystallography of Macfallite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Setting:
P21/m
Cell Parameters:
a = 10.235(3) Å, b = 6.086(6) Å, c = 8.970(5) Å
β = 110.75(3)°
β = 110.75(3)°
Ratio:
a:b:c = 1.682 : 1 : 1.474
Unit Cell V:
522.50 ų (Calculated from Unit Cell)
Z:
2
Twinning:
By reflection on {100}, commonly repeated.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0000966 | Macfallite | Moore P B, Shen J, Araki T (1985) Crystal chemistry of the (M2)3+ phi2 sheet: Structural principles and crystal structures of ruizite, macfallite and orientite American Mineralogist 70 171-181 | 1985 | Lake Manganese, Copper Harbor, Keweenaw County, Michigan, USA | 0 | 293 | |
0004767 | Macfallite | Nagashima M, Rahmoun N S, Alekseev E V, Geiger C A, Armbruster T, Akasaka M (2008) Crystal chemistry of macfallite: Relationships to sursassite and pumpellyite American Mineralogist 93 1851-1857 | 2008 | Manganese Lake, Copper Harbor, Keweenaw County, Michigan | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
2.70 Å | (100) |
4.76 Å | (90) |
1.588 Å | (85) |
3.904 Å | (80) |
3.40 Å | (70) |
2.97 Å | (70) |
2.18 Å | (70) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Near-surface Processes | |
22 : Hydration and low-𝑇 subsurface aqueous alteration (see also #23) | |
High-𝑇 alteration and/or metamorphism | |
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits |
Type Occurrence of Macfallite
General Appearance of Type Material:
radial and framboidal aggregates
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 135923; The Natural History Museum, London, England, 1984,139.
Associated Minerals at Type Locality:
Reference:
Moore, P.B., Ito, J., and Steele, I.M. (1979) Macfallite and orientite: calcium manganese (III) silicates from upper Michigan. Mineralogical Magazine: 43: 325-331.
Synonyms of Macfallite
Other Language Names for Macfallite
Common Associates
Associated Minerals Based on Photo Data:
18 photos of Macfallite associated with Calcite | CaCO3 |
16 photos of Macfallite associated with Orientite | Ca8Mn3+10(SiO4)3(Si3O10)3(OH)10 · 4H2O |
9 photos of Macfallite associated with Braunite | Mn2+Mn3+6(SiO4)O8 |
1 photo of Macfallite associated with Ranciéite | (Ca,Mn2+)0.2(Mn4+,Mn3+)O2 · 0.6H2O |
1 photo of Macfallite associated with Pyrolusite | Mn4+O2 |
Related Minerals - Strunz-mindat Grouping
9.BG. | Shuiskite-(Cr) | Ca2Cr3+Cr3+2[Si2O6OH][SiO4](OH)2O |
9.BG. | Alnaperbøeite-(Ce) | Ca(Ce2.5Na0.5)(AlAl2Al)[Si2O7][SiO4]3O(OH)2 |
9.BG. | Magnesiovesuvianite | Ca19MgAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
9.BG. | Alumovesuvianite | Ca19AlAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
9.BG. | Zoisite-(Pb) | (CaPb)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG. | Vielleaureite-(Ce) | (Mn2+Ce)(MgAlMn2+)F[Si2O7][SiO4](OH) |
9.BG. | Heflikite | (CaCa)(AlAlSc)O[Si2O7][SiO4](OH) |
9.BG. | Zilbermintsite-(La) | (CaLa5)(Fe3+Al3Fe2+)[Si2O7][SiO4]5O(OH)3 |
9.BG.05b | Allanite-(Ce) | (CaCe)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Allanite-(La) | (CaLa)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Allanite-(Y) | (CaY)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05a | Clinozoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG.05b | Dissakisite-(Ce) | (CaCe)(AlAlMg)O[Si2O7][SiO4](OH) |
9.BG.05 | Dollaseite-(Ce) | (CaCe)(MgAlMg)F[Si2O7][SiO4](OH) |
9.BG.05a | Epidote | (CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05a | Hancockite | (CaPb)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05 | Khristovite-(Ce) | (CaCe)(MgAlMn2+)F[Si2O7][SiO4](OH) |
9.BG.05a | Mukhinite | (CaCa)(AlAlV3+)O[Si2O7][SiO4](OH) |
9.BG.05a | Piemontite | (CaCa)(AlAlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05 | Piemontite-(Sr) | (CaSr)(AlAlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Manganiandrosite-(La) | (Mn2+La)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Tweddillite | (CaSr)(Mn3+AlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Ferriallanite-(Ce) | (CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Niigataite | (CaSr)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG.05 | Manganiandrosite-(Ce) | (Mn2+Ce)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Dissakisite-(La) | (CaLa)(AlAlMg)O[Si2O7][SiO4](OH) |
9.BG.05 | Vanadoandrosite-(Ce) | (Mn2+Ce)(V3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Uedaite-(Ce) | (Mn2+Ce)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05a | Epidote-(Sr) | (CaSr)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Allanite-(Nd) | (CaNd)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Unnamed (Mg-analogue of Ferriallanite-(Ce)) | (CaCe)(Fe3+AlMg)O[Si2O7][SiO4](OH) |
9.BG.05b | Unnamed (Mn3+-analogue of Ferriakasakaite-(Ce)) | (CaCe)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Ferriallanite-(La) | (CaLa)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Åskagenite-(Nd) | (Mn2+Nd)(AlAlFe3+)O[Si2O7][SiO4]O |
9.BG.05 | Piemontite-(Pb) | (CaPb)(AlAlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Vanadoallanite-(La) | (CaLa)(V3+AlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Ferriandrosite-(La) | (Mn2+La)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Androsite-(Ce) | (Mn2+Ce)(AlAlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05a v | Unnamed (Ga-analogue of Epidote) | (CaCa)(AlAlGa3+)O[Si2O7][SiO4](OH) |
9.BG.05b | UM1989-32-SiO:AlCaFeHREE | (Ca0.5◻0.5REE)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Manganiakasakaite-(La) | (CaLa)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Ferriakasakaite-(Ce) | (CaCe)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.9.BG. | Ferriakasakaite-(La) | (CaLa)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.9.BG. | Ferriandrosite-(Ce) | (Mn2+Ce)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.9.BG | Ferriperbøeite-(Ce) | CaCe3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.10 | Zoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG.15 | Sursassite | Mn2+2Al3(SiO4)(Si2O7)(OH)3 |
9.BG.20 | Julgoldite-(Fe2+) | Ca2Fe2+Fe3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.20 | Okhotskite | Ca2Mn2+Mn3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.20 | Pumpellyite-(Fe2+) | Ca2Fe2+Al2(Si2O7)(SiO4)(OH,O)2 · H2O |
9.BG.20 | Pumpellyite-(Fe3+) | Ca2Fe3+Al2(Si2O7)(SiO4)(OH,O)2 · H2O |
9.BG.20 | Pumpellyite-(Mg) | Ca2MgAl2(Si2O7)(SiO4)(OH)2 · H2O |
9.BG.20 | Pumpellyite-(Mn2+) | Ca2Mn2+Al2(Si2O7)(SiO4)(OH)2 · H2O |
9.BG.20 | Shuiskite-(Mg) | Ca2MgCr3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.20 | Julgoldite-(Fe3+) | Ca2Fe3+Fe3+2[Si2O6OH][SiO4](OH)2O |
9.BG.20 | Pumpellyite-(Al) | Ca2Al3(Si2O7)(SiO4)(OH,O)2 · H2O |
9.BG.20 | Poppiite | Ca2V3+V3+2[Si2O6OH][SiO4](OH)2O |
9.BG.20 | Julgoldite-(Mg) | Ca2MgFe3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.25 | Ganomalite | Pb9Ca5Mn(Si2O7)4(SiO4)O |
9.BG.25 | Wayneburnhamite | Pb9Ca6(Si2O7)3(SiO4)3 |
9.BG.30 | Rustumite | Ca10(Si2O7)2(SiO4)(OH)2Cl2 |
9.BG.35 | Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
9.BG.35 | Wiluite | Ca19MgAl4(Al,Mg)8(B,◻)4◻[Si2O7]4[(SiO4)10]O(O,OH)9 |
9.BG.35 | Manganvesuvianite | Ca19Mn3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
9.BG.35 | Fluorvesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(F,OH)9 |
9.BG.35 | Cyprine | Ca19Cu2+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
9.BG.35 | Hongheite | Ca19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9 |
9.BG.35 | Milanriederite | (Ca18[REE])Fe3+Al4(Mg4Al4)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
9.BG.35 | Manaevite-(Ce) | (Ca13Ce4[H2O]2)Mg(Al3Mg)(Mg3Ti3Fe3+2)(◻4)◻[Si2O7]4[(SiO4)8(H4O4)2]O(OH)9 |
9.BG.40 | Vyuntspakhkite-(Y) | (Y,Yb)4Al2.5-1.5(Si,Al)1.5-2.5(SiO4)4O(OH)7 |
9.BG.45 | Dellaite | Ca6Si3O11(OH)2 |
9.BG.50 | Gatelite-(Ce) | CaCe3(AlAl2Mg)[Si2O7][SiO4]3O(OH)2 |
9.BG.50 | Perbøeite-(Ce) | CaCe3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.50 | Ferriperbøeite-(La) | CaLa3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.50 | Perbøeite-(La) | CaLa3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.55 | Västmanlandite-(Ce) | CaCe3(MgAl2Mg)[Si2O7][SiO4]3F(OH)2 |
9.BG.60 | Radekškodaite-(La) | (CaLa5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3 |
9.BG.60 | Radekškodaite-(Ce) | (CaCe5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3 |
9.BG.60 | Radekškodaite Group | (CaM5)([Fe3+Al3]Fe2+)[Si2O7][SiO4]5O(OH)3 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Macfallite
mindat.org URL:
https://www.mindat.org/min-2508.html
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References for Macfallite
Localities for Macfallite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Italy | |
| Frank K. Mazdab collection (see https://www.rockptx.com/fkm-151-to-fkm-175/#FKM-171 for analytical data) +1 other reference |
| //doi.org/10.57635/MICRO.2023.21.7 |
| Palenzona (1990) |
Japan | |
| Miyajima et al. (1994) |
Serbia | |
| Pačevski et al. (2016) +1 other reference |
USA (TL) | |
| Moore et al. (1979) +2 other references |
| Steven Kuitems |
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Manganese Mine, Copper Harbor, Grant Township, Keweenaw County, Michigan, USA