Manaevite-(Ce)
A valid IMA mineral species
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About Manaevite-(Ce)
Formula:
(Ca13Ce4[H2O]2)Mg(Al3Mg)(Mg3Ti3Fe3+2)(◻4)◻[Si2O7]4[(SiO4)8(H4O4)2]O(OH)9
The formula is a partial simplification of the full structural formula. The large (VII-IX)-coordinated (X4)2(X3)8(X2)8(X1) sites are here combined (e.g. Ca19) and are typically filled with Ca, although other large cations such as the REE may be present. The square-pyramidal Y1 site can host a variety of M2+ and M3+ ions and is the basis for the distinction of several species. The VI-coordinated Y2 site typically is filled with Al, whereas the also VI-coordinated Y3 site may contain Al, Mg, and other cations of similar charge and size. The tetrahedral T1 site is typically vacant but may contain B (less commonly Al); the trigonal T2 site is also typically vacant but may also contain B. Some of the (SiO4) may be replaced by (H4O4), akin to the Si4+ ↔︎ 4H+ hydrogarnet substitution. Among the oxygen that are not part of the silica tetrahedra, there are eight "O11" that typically occur as OH, two "O10" that are typically O & OH or OH & OH (the latter arrangement notably when Y1 is an M2+ cation). There may also be up to three "O12" that in most vesuvianite-group minerals are absent (and are not included here), but may be present particularly when T1 is occupied.
Note that in lieu of published structural data, the Y2 and Y3 site occupancies denoted here are distributed as per other members of the other vesuvianite group minerals (i.e. Y2 = Al-dominant; Ti & Fe3+ assigned to Y3). These occupancies may be re-assigned with updated data. Justification for the -(REE) suffix is that REE (in this case predominately Ce) is the dominant cation in the X3 site.
Note that in lieu of published structural data, the Y2 and Y3 site occupancies denoted here are distributed as per other members of the other vesuvianite group minerals (i.e. Y2 = Al-dominant; Ti & Fe3+ assigned to Y3). These occupancies may be re-assigned with updated data. Justification for the -(REE) suffix is that REE (in this case predominately Ce) is the dominant cation in the X3 site.
Colour:
dark orange
Lustre:
Vitreous, Greasy
Hardness:
4½
Specific Gravity:
3.80
Crystal System:
Tetragonal
Member of:
Name:
The new mineral is named in honor of Nikolay Mikhailovich Manaev (27.02.1936–02.03.2012), a former chief geologist of the Kovdorslyuda Mining and Dressing Company and a prominent mineral collector, for his contribution to the geology, mineralogy and exploitation of the world-largest Kovdor phlogopite deposit, Kola Peninsula, Russia.
Type Locality:
First group member with essential REE (rare earth elements) and hydrogarnet-like H4O4 substitution of the orthosilicate group.
Chemically related to dissakisite-(Ce), dollaseite-(Ce), gatelite-(Ce), västmanlandite-(Ce), and somewhat to khristovite-(Ce) and some unnamed species.
Chemically related to dissakisite-(Ce), dollaseite-(Ce), gatelite-(Ce), västmanlandite-(Ce), and somewhat to khristovite-(Ce) and some unnamed species.
Unique Identifiers
Mindat ID:
53139
Long-form identifier:
mindat:1:1:53139:3
GUID
(UUID V4):
(UUID V4):
43cb7581-09d9-4f79-980c-aa22ea8ee18b
IMA Classification of Manaevite-(Ce)
Approved
IMA Formula:
Ca11(Ce,H2O,Ca)8Mg(Al,Fe)4(Mg,Ti,Fe3+)8[Si2O7]4[(SiO4)8(H4O4)2](OH)9
Classification of Manaevite-(Ce)
9.BG.35
9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Mv-Ce | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Manaevite-(Ce)
Vitreous, Greasy
Colour:
dark orange
Streak:
brownish orange
Hardness:
4½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
none
Fracture:
Irregular/Uneven, Conchoidal
Density:
3.80(3) g/cm3 (Measured) 3.72 g/cm3 (Calculated)
Optical Data of Manaevite-(Ce)
Type:
Uniaxial (-)
RI values:
nω = 1.760(5) nε = 1.750(5)
Max Birefringence:
δ = 0.010
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
strong dispersion
Pleochroism:
Weak
Comments:
[O (light yellowish-brown) < E (brown)]
Comments:
Sometimes slightly biaxial(2 V = 0°–5°)
Chemistry of Manaevite-(Ce)
Mindat Formula:
(Ca13Ce4[H2O]2)Mg(Al3Mg)(Mg3Ti3Fe3+2)(◻4)◻[Si2O7]4[(SiO4)8(H4O4)2]O(OH)9
The formula is a partial simplification of the full structural formula. The large (VII-IX)-coordinated (X4)2(X3)8(X2)8(X1) sites are here combined (e.g. Ca19) and are typically filled with Ca, although other large cations such as the REE may be present. The square-pyramidal Y1 site can host a variety of M2+ and M3+ ions and is the basis for the distinction of several species. The VI-coordinated Y2 site typically is filled with Al, whereas the also VI-coordinated Y3 site may contain Al, Mg, and other cations of similar charge and size. The tetrahedral T1 site is typically vacant but may contain B (less commonly Al); the trigonal T2 site is also typically vacant but may also contain B. Some of the (SiO4) may be replaced by (H4O4), akin to the Si4+ ↔︎ 4H+ hydrogarnet substitution. Among the oxygen that are not part of the silica tetrahedra, there are eight "O11" that typically occur as OH, two "O10" that are typically O & OH or OH & OH (the latter arrangement notably when Y1 is an M2+ cation). There may also be up to three "O12" that in most vesuvianite-group minerals are absent (and are not included here), but may be present particularly when T1 is occupied.
Note that in lieu of published structural data, the Y2 and Y3 site occupancies denoted here are distributed as per other members of the other vesuvianite group minerals (i.e. Y2 = Al-dominant; Ti & Fe3+ assigned to Y3). These occupancies may be re-assigned with updated data. Justification for the -(REE) suffix is that REE (in this case predominately Ce) is the dominant cation in the X3 site.
The formula is a partial simplification of the full structural formula. The large (VII-IX)-coordinated (X4)2(X3)8(X2)8(X1) sites are here combined (e.g. Ca19) and are typically filled with Ca, although other large cations such as the REE may be present. The square-pyramidal Y1 site can host a variety of M2+ and M3+ ions and is the basis for the distinction of several species. The VI-coordinated Y2 site typically is filled with Al, whereas the also VI-coordinated Y3 site may contain Al, Mg, and other cations of similar charge and size. The tetrahedral T1 site is typically vacant but may contain B (less commonly Al); the trigonal T2 site is also typically vacant but may also contain B. Some of the (SiO4) may be replaced by (H4O4), akin to the Si4+ ↔︎ 4H+ hydrogarnet substitution. Among the oxygen that are not part of the silica tetrahedra, there are eight "O11" that typically occur as OH, two "O10" that are typically O & OH or OH & OH (the latter arrangement notably when Y1 is an M2+ cation). There may also be up to three "O12" that in most vesuvianite-group minerals are absent (and are not included here), but may be present particularly when T1 is occupied.
Note that in lieu of published structural data, the Y2 and Y3 site occupancies denoted here are distributed as per other members of the other vesuvianite group minerals (i.e. Y2 = Al-dominant; Ti & Fe3+ assigned to Y3). These occupancies may be re-assigned with updated data. Justification for the -(REE) suffix is that REE (in this case predominately Ce) is the dominant cation in the X3 site.
Crystallography of Manaevite-(Ce)
Crystal System:
Tetragonal
Class (H-M):
4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Space Group:
P4/nnc
Setting:
P4/nnc
Cell Parameters:
a = 15.9247(13) Å, c = 11.9661(10) Å
Ratio:
a:c = 1 : 0.751
Unit Cell V:
3,034.56 ų (Calculated from Unit Cell)
Z:
2
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
5.98 Å | (27) |
4.61 Å | (30) |
3.289 Å | (31) |
2.991 Å | (100) |
2.787 Å | (95) |
2.636 Å | (81) |
2.503 Å | (47) |
1.659 Å | (25) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 3a: Earth’s earliest Hadean crust | >4.50 |
7 : Ultramafic igneous rocks | |
Stage 4b: Highly evolved igneous rocks | >3.0 |
35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Manaevite-(Ce)
Place of Conservation of Type Material:
Collections of the (1) Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18-2, Moscow 119071, Russia, registration number 5075/1; (2) the Mineralogical Museum of St. Petersburg State University, St. Petersburg, Russia, registra
Geological Setting of Type Material:
skarn-like metasomatic rock
Synonyms of Manaevite-(Ce)
Relationship of Manaevite-(Ce) to other Species
Member of:
Other Members of this group:
Alumovesuvianite | Ca19AlAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 | Tet. 4/m : P4/n |
Cyprine | Ca19Cu2+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 | Tet. 4/m : P4/n |
Fluorvesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(F,OH)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
Hongheite | Ca19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
Magnesiovesuvianite | Ca19MgAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 | Tet. 4/m : P4/n |
Manganvesuvianite | Ca19Mn3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 | Tet. 4/m : P4/n |
Milanriederite | (Ca18[REE])Fe3+Al4(Mg4Al4)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
Wiluite | Ca19MgAl4(Al,Mg)8(B,◻)4◻[Si2O7]4[(SiO4)10]O(O,OH)9 | Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc |
Related Minerals - Strunz-mindat Grouping
9.BG. | Shuiskite-(Cr) | Ca2Cr3+Cr3+2[Si2O6OH][SiO4](OH)2O |
9.BG. | Alnaperbøeite-(Ce) | Ca(Ce2.5Na0.5)(AlAl2Al)[Si2O7][SiO4]3O(OH)2 |
9.BG. | Magnesiovesuvianite | Ca19MgAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
9.BG. | Alumovesuvianite | Ca19AlAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
9.BG. | Zoisite-(Pb) | (CaPb)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG. | Vielleaureite-(Ce) | (Mn2+Ce)(MgAlMn2+)F[Si2O7][SiO4](OH) |
9.BG. | Heflikite | (CaCa)(AlAlSc)O[Si2O7][SiO4](OH) |
9.BG. | Zilbermintsite-(La) | (CaLa5)(Fe3+Al3Fe2+)[Si2O7][SiO4]5O(OH)3 |
9.BG.05b | Allanite-(Ce) | (CaCe)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Allanite-(La) | (CaLa)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Allanite-(Y) | (CaY)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05a | Clinozoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG.05b | Dissakisite-(Ce) | (CaCe)(AlAlMg)O[Si2O7][SiO4](OH) |
9.BG.05 | Dollaseite-(Ce) | (CaCe)(MgAlMg)F[Si2O7][SiO4](OH) |
9.BG.05a | Epidote | (CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05a | Hancockite | (CaPb)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05 | Khristovite-(Ce) | (CaCe)(MgAlMn2+)F[Si2O7][SiO4](OH) |
9.BG.05a | Mukhinite | (CaCa)(AlAlV3+)O[Si2O7][SiO4](OH) |
9.BG.05a | Piemontite | (CaCa)(AlAlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05 | Piemontite-(Sr) | (CaSr)(AlAlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Manganiandrosite-(La) | (Mn2+La)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Tweddillite | (CaSr)(Mn3+AlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Ferriallanite-(Ce) | (CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Niigataite | (CaSr)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG.05 | Manganiandrosite-(Ce) | (Mn2+Ce)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Dissakisite-(La) | (CaLa)(AlAlMg)O[Si2O7][SiO4](OH) |
9.BG.05 | Vanadoandrosite-(Ce) | (Mn2+Ce)(V3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Uedaite-(Ce) | (Mn2+Ce)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05a | Epidote-(Sr) | (CaSr)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Allanite-(Nd) | (CaNd)(AlAlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Unnamed (Mg-analogue of Ferriallanite-(Ce)) | (CaCe)(Fe3+AlMg)O[Si2O7][SiO4](OH) |
9.BG.05b | Unnamed (Mn3+-analogue of Ferriakasakaite-(Ce)) | (CaCe)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Ferriallanite-(La) | (CaLa)(Fe3+AlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Åskagenite-(Nd) | (Mn2+Nd)(AlAlFe3+)O[Si2O7][SiO4]O |
9.BG.05 | Piemontite-(Pb) | (CaPb)(AlAlMn3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Vanadoallanite-(La) | (CaLa)(V3+AlFe2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Ferriandrosite-(La) | (Mn2+La)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05 | Androsite-(Ce) | (Mn2+Ce)(AlAlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05a v | Unnamed (Ga-analogue of Epidote) | (CaCa)(AlAlGa3+)O[Si2O7][SiO4](OH) |
9.BG.05b | UM1989-32-SiO:AlCaFeHREE | (Ca0.5◻0.5REE)(AlAlFe3+)O[Si2O7][SiO4](OH) |
9.BG.05b | Manganiakasakaite-(La) | (CaLa)(Mn3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.05b | Ferriakasakaite-(Ce) | (CaCe)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.9.BG. | Ferriakasakaite-(La) | (CaLa)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.9.BG. | Ferriandrosite-(Ce) | (Mn2+Ce)(Fe3+AlMn2+)O[Si2O7][SiO4](OH) |
9.BG.9.BG | Ferriperbøeite-(Ce) | CaCe3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.10 | Zoisite | (CaCa)(AlAlAl)O[Si2O7][SiO4](OH) |
9.BG.15 | Macfallite | Ca2Mn3+3(SiO4)(Si2O7)(OH)3 |
9.BG.15 | Sursassite | Mn2+2Al3(SiO4)(Si2O7)(OH)3 |
9.BG.20 | Julgoldite-(Fe2+) | Ca2Fe2+Fe3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.20 | Okhotskite | Ca2Mn2+Mn3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.20 | Pumpellyite-(Fe2+) | Ca2Fe2+Al2(Si2O7)(SiO4)(OH,O)2 · H2O |
9.BG.20 | Pumpellyite-(Fe3+) | Ca2Fe3+Al2(Si2O7)(SiO4)(OH,O)2 · H2O |
9.BG.20 | Pumpellyite-(Mg) | Ca2MgAl2(Si2O7)(SiO4)(OH)2 · H2O |
9.BG.20 | Pumpellyite-(Mn2+) | Ca2Mn2+Al2(Si2O7)(SiO4)(OH)2 · H2O |
9.BG.20 | Shuiskite-(Mg) | Ca2MgCr3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.20 | Julgoldite-(Fe3+) | Ca2Fe3+Fe3+2[Si2O6OH][SiO4](OH)2O |
9.BG.20 | Pumpellyite-(Al) | Ca2Al3(Si2O7)(SiO4)(OH,O)2 · H2O |
9.BG.20 | Poppiite | Ca2V3+V3+2[Si2O6OH][SiO4](OH)2O |
9.BG.20 | Julgoldite-(Mg) | Ca2MgFe3+2[Si2O6OH][SiO4](OH)2(OH) |
9.BG.25 | Ganomalite | Pb9Ca5Mn(Si2O7)4(SiO4)O |
9.BG.25 | Wayneburnhamite | Pb9Ca6(Si2O7)3(SiO4)3 |
9.BG.30 | Rustumite | Ca10(Si2O7)2(SiO4)(OH)2Cl2 |
9.BG.35 | Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
9.BG.35 | Wiluite | Ca19MgAl4(Al,Mg)8(B,◻)4◻[Si2O7]4[(SiO4)10]O(O,OH)9 |
9.BG.35 | Manganvesuvianite | Ca19Mn3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
9.BG.35 | Fluorvesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(F,OH)9 |
9.BG.35 | Cyprine | Ca19Cu2+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
9.BG.35 | Hongheite | Ca19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9 |
9.BG.35 | Milanriederite | (Ca18[REE])Fe3+Al4(Mg4Al4)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9 |
9.BG.40 | Vyuntspakhkite-(Y) | (Y,Yb)4Al2.5-1.5(Si,Al)1.5-2.5(SiO4)4O(OH)7 |
9.BG.45 | Dellaite | Ca6Si3O11(OH)2 |
9.BG.50 | Gatelite-(Ce) | CaCe3(AlAl2Mg)[Si2O7][SiO4]3O(OH)2 |
9.BG.50 | Perbøeite-(Ce) | CaCe3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.50 | Ferriperbøeite-(La) | CaLa3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.50 | Perbøeite-(La) | CaLa3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 |
9.BG.55 | Västmanlandite-(Ce) | CaCe3(MgAl2Mg)[Si2O7][SiO4]3F(OH)2 |
9.BG.60 | Radekškodaite-(La) | (CaLa5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3 |
9.BG.60 | Radekškodaite-(Ce) | (CaCe5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3 |
Fluorescence of Manaevite-(Ce)
none
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Manaevite-(Ce)
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https://www.mindat.org/min-53139.html
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References for Manaevite-(Ce)
Reference List:
Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2018) CNMNC Newsletter 45, New minerals and nomenclature modifications approved in 2018. Mineralogical Magazine, 82 (5) 1225-1232 doi:10.1180/mgm.2018.160
Moiseev, Mikhail M., Panikorovskii, Taras L., Aksenov, Sergey M., Mazur, Anton S., Mikhailova, Julia A., Yakovenchuk, Victor N., Bazai, Ayya V., Ivanyuk, Gregory Yu., Agakhanov, Atali A., Shilovskikh, Vladimir V., Pekov, Igor V., Kasatkin, Anatoly V., Rusakov, Vyacheslav S., Yapaskurt, Vasiliy O., Karpenko, Vladimir Yu., Krivovichev, Sergey V. (2020) Insights into crystal chemistry of the vesuvianite-group: manaevite-(Ce), a new mineral with complex mechanisms of its hydration. Physics and Chemistry of Minerals, 47 (3) doi:10.1007/s00269-020-01086-7
Localities for Manaevite-(Ce)
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Russia (TL) | |
| Mineralogical Magazine +2 other references |
Mineralogical Magazine +2 other references |
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Kovdor Phlogopite mine, Kovdor Massif, Murmansk Oblast, Russia