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Grangeiro, Larissa P.; Vilalva, Frederico C. J.; Vlach, Silvio R. F.; Oliveira, Armando L. S. de (2025) Zircon out, Elpidite in: Deformation-Driven Zirconosilicate Evolution in Peralkaline Granites: A Case Study of the Papanduva Pluton (Brazil). Minerals, 15 (7). doi:10.3390/min15070667

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Reference TypeJournal (article/letter/editorial)
TitleZircon out, Elpidite in: Deformation-Driven Zirconosilicate Evolution in Peralkaline Granites: A Case Study of the Papanduva Pluton (Brazil)
JournalMinerals
AuthorsGrangeiro, Larissa P.Author
Vilalva, Frederico C. J.Author
Vlach, Silvio R. F.Author
Oliveira, Armando L. S. deAuthor
Year2025Volume<   15   >
Issue<   7   >
URL
DOIdoi:10.3390/min15070667Search in ResearchGate
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Mindat Ref. ID18582344Long-form Identifiermindat:1:5:18582344:3
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Full ReferenceGrangeiro, Larissa P.; Vilalva, Frederico C. J.; Vlach, Silvio R. F.; Oliveira, Armando L. S. de (2025) Zircon out, Elpidite in: Deformation-Driven Zirconosilicate Evolution in Peralkaline Granites: A Case Study of the Papanduva Pluton (Brazil). Minerals, 15 (7). doi:10.3390/min15070667
Plain TextGrangeiro, Larissa P.; Vilalva, Frederico C. J.; Vlach, Silvio R. F.; Oliveira, Armando L. S. de (2025) Zircon out, Elpidite in: Deformation-Driven Zirconosilicate Evolution in Peralkaline Granites: A Case Study of the Papanduva Pluton (Brazil). Minerals, 15 (7). doi:10.3390/min15070667
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Abstract/NotesThe peralkaline granites of the Papanduva Pluton (South Brazil) display a remarkable facies dichotomy, with zircon dominant in massive facies and diverse zirconosilicates (Zr-Si) in foliated facies. This study employs petrography and mineral chemistry (major and trace elements) to elucidate the textural diversity and compositional evolution of these minerals. Three discrete zirconosilicate groups were identified: Na-rich elpidite ( euhedral, vein-like, and granular varieties), Na-poor (Na,K)Zr-Si-I, and silica-rich (Na,K)Zr-Si-II. Contrary to the expected crystallization sequences, trace element data reveal that REE enrichment correlates with deformation intensity rather than paragenetic order, with vein-like aggregates along deformation features showing the highest REE concentrations. Statistical analysis demonstrates significant correlations between REE contents and alkali exchange patterns. We propose a three-stage evolutionary model involving magmatic crystallization, deformation-enhanced fluid interaction, and late-stage recrystallization, with a progressive evolution from Na-dominated to K-dominated conditions. This study provides new insights into closed-system fluid evolution in agpaitic environments and highlights deformation as a primary control on element mobility in peralkaline granitic systems.

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LocalityCitation Details
Papanduva pluton, Morro Redondo complex, Tijucas do Sul, Paraná, Brazil

Mineral Occurrences

LocalityMineral(s)
Papanduva pluton, Morro Redondo complex, Tijucas do Sul, Paraná, Brazil Aegirine, Aenigmatite, Albite, Alkali Feldspar, Amphibole Supergroup, Arfvedsonite, Astrophyllite, Augite, Britholite-(Ce), Chevkinite Group, Elpidite, Feldspar Group, Granite, Ilmenite, Mesoperthite, Nacareniobsite-(Ce), Narsarsukite, Neptunite, Quartz, Richterite, Riebeckite, Turkestanite, Zircon


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To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
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