Tugtupite
A valid IMA mineral species
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About Tugtupite
The Type Locale for Tugtupite
Tugtup Agtakôrfia, Tunulliarfik Fjord, Ilímaussaq complex, Kujalleq, Greenland
Tugtup Agtakôrfia, Tunulliarfik Fjord, Ilímaussaq complex, Kujalleq, Greenland
Formula:
Na4BeAlSi4O12Cl
Colour:
Commonly red, also white to pink, bluish white, greenish white
Lustre:
Sub-Vitreous, Waxy, Greasy, Dull
Hardness:
4
Specific Gravity:
2.33
Crystal System:
Tetragonal
Member of:
Name:
Named after its discovery locality, Tugtup Agtâkorfia, Narsaq municipality, Greenland.
See also: Sodalite Group.
Piezoelectric.
Piezoelectric.
Visit gemdat.org for gemological information about Tugtupite.
Unique Identifiers
Mindat ID:
4044
Long-form identifier:
mindat:1:1:4044:6
GUID
(UUID V4):
(UUID V4):
7af3906a-ad1e-497a-9eb3-ac2c672b69d7
IMA Classification of Tugtupite
Approved
First published:
1962
Classification of Tugtupite
9.FB.10
9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.3.7
76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
17.3.5
17 : Silicates Containing other Anions
3 : Silicates with chloride (including aluminosilicates)
17 : Silicates Containing other Anions
3 : Silicates with chloride (including aluminosilicates)
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Ttp | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Tugtupite
Sub-Vitreous, Waxy, Greasy, Dull
Transparency:
Translucent
Colour:
Commonly red, also white to pink, bluish white, greenish white
Comment:
colorless in transmitted light
Streak:
white
Hardness:
4 on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
On {101}; on {110} fair.
On {101}; on {110} fair.
Fracture:
Step-Like
Comment:
Usually shows cleavage because of the great number of planes associated with the cleavage forms.
Density:
2.33 g/cm3 (Measured) 2.34 g/cm3 (Calculated)
Optical Data of Tugtupite
Type:
Uniaxial (+)
RI values:
nω = 1.496 nε = 1.502
Birefringence:
0.006
Max Birefringence:
δ = 0.006
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
Anomalously biaxial
Pleochroism:
Weak
Comments:
Weak lilac to weak red-orange.
Chemistry of Tugtupite
Mindat Formula:
Na4BeAlSi4O12Cl
Common Impurities:
Fe,Ga,Mg,Ca,K,H2O,S
Crystallography of Tugtupite
Crystal System:
Tetragonal
Class (H-M):
4 - Disphenoidal
Space Group:
I4
Cell Parameters:
a = 8.640(1) Å, c = 8.873(1) Å
Ratio:
a:c = 1 : 1.027
Unit Cell V:
662.4 ų
Z:
2
Morphology:
Short tetragonal prisms with pyramids, sphenoids, and bisphenoids. Fine-grained aggregates; massive.
Twinning:
On (101), penetration twinning resulting in pseudocubic triplets; pseudotrigonal contact twins with composition planes (101) and (011).
Comment:
Pseudo-cubic. Cell parameters from Hassan and Grundy (1991).
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0003450 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 293 | ||
0003451 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 306 | ||
0003452 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 338 | ||
0003453 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 386 | ||
0003454 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 483 | ||
0003455 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 579 | ||
0003456 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 692 | ||
0003457 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 789 | ||
0003458 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 869 | ||
0003459 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 917 | ||
0003460 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 982 | ||
0003461 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 1046 | ||
0003462 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 1094 | ||
0003463 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 1142 | ||
0003464 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 1175 | ||
0003465 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 1207 | ||
0003466 | Tugtupite | Antao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497 | 2004 | 0 | 1255 | ||
0005268 | Tugtupite | Hassan I, Grundy H D (1991) The crystal structure and thermal expansion of tugtupite, Na8[Al2Be2Si8O24]Cl2 The Canadian Mineralogist 29 385-390 | 1991 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
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Radiation - Copper Kα
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
6.19 Å | (40) |
6.11 Å | (10) |
4.43 Å | (10) |
3.59 Å | (40) |
3.54 Å | (100) |
2.52 Å | (20) |
2.06 Å | (10) |
2.04 Å | (10) |
Comments:
Canadian Mineralogist 29:385
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Near-surface Processes | |
22 : Hydration and low-𝑇 subsurface aqueous alteration (see also #23) | |
Stage 4b: Highly evolved igneous rocks | >3.0 |
35 : Ultra-alkali and agpaitic igneous rocks | |
Stage 7: Great Oxidation Event | <2.4 |
47g : [Halogen-bearing surface weathering minerals] |
Type Occurrence of Tugtupite
Place of Conservation of Type Material:
University of Copenhagen, Copenhagen, Denmark, 1970.276.
The Natural History Museum, London, England, 1967,394.
The Natural History Museum, London, England, 1967,394.
Geological Setting of Type Material:
As replacements of chkalovite in hydrothermal veins cutting sodalite syenite and syenite.
Associated Minerals at Type Locality:
Reference:
Sørenson, H. (1962) On the occurrence of steenstrupine in the Ilimaussaq massif, south-west greenland. Medd. om Grønland, 167(1), 1-251 (218-219).
Other Language Names for Tugtupite
Relationship of Tugtupite to other Species
Member of:
Other Members of this group:
Danalite | Be3Fe2+4(SiO4)3S | Iso. 4 3m : P4 3n |
Genthelvite | Be3Zn4(SiO4)3S | Iso. 4 3m : P4 3n |
Helvine | Be3Mn2+4(SiO4)3S | Iso. 4 3m : P4 3n |
Common Associates
Associated Minerals Based on Photo Data:
99 photos of Tugtupite associated with Chkalovite | Na2BeSi2O6 |
66 photos of Tugtupite associated with Analcime | Na(AlSi2O6) · H2O |
53 photos of Tugtupite associated with Sodalite | Na4(Si3Al3)O12Cl |
37 photos of Tugtupite associated with Polylithionite | KLi2Al(Si4O10)(F,OH)2 |
28 photos of Tugtupite associated with Arfvedsonite | [Na][Na2][Fe2+4Fe3+]Si8O22(OH)2 |
24 photos of Tugtupite associated with Albite | Na(AlSi3O8) |
18 photos of Tugtupite associated with Ussingite | Na2AlSi3O8OH |
14 photos of Tugtupite associated with Sphalerite | ZnS |
9 photos of Tugtupite associated with Aegirine | NaFe3+Si2O6 |
8 photos of Tugtupite associated with Natrolite | Na2Al2Si3O10 · 2H2O |
Related Minerals - Strunz-mindat Grouping
9.FB. | Steudelite | Na3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2O |
9.FB. | Sapozhnikovite | Na8(Al6Si6O24)(HS)2 |
9.FB. | Betzite | Na6Ca2(Al6Si6O24)Cl4 |
9.FB. | Slyudyankaite | Na28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2O |
9.FB. | Bolotinaite | (Na7◻)(Al6Si6O24)F · 4H2O |
9.FB. | Wenlanzhangite-(Y) | Y2V3+2V4+2(SiO4)2O4(OH)4 |
9.FB.05 | Afghanite | (Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6 |
9.FB.05 | Bystrite | (Na,K)7Ca(Al6Si6O24)(S5)Cl |
9.FB.05 | Cancrinite | (Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2O |
9.FB.05 | Cancrisilite | Na7(Al5Si7O24)(CO3) · 3H2O |
9.FB.05 | Davyne | (Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2 |
9.FB.05 | Franzinite | (Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2O |
9.FB.05 | Giuseppettite | (Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2 |
9.FB.05 | Hydroxycancrinite | Na8(Al6Si6O24)(OH)2 · 2H2O |
9.FB.05 | Liottite | (Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4 |
9.FB.05 | Microsommite | Na4K2Ca2(Al6Si6O24)(SO4)Cl2 |
9.FB.05 | Pitiglianoite | Na6K2(Al6Si6O24)(SO4) · 2H2O |
9.FB.05 | Quadridavyne | (Na,K)6Ca2(Al6Si6O24)Cl4 |
9.FB.05 | Sacrofanite | (Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2O |
9.FB.05 | Tounkite | (Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2O |
9.FB.05 | Vishnevite | (Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2O |
9.FB.05 | Marinellite | (Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2O |
9.FB.05 | Farneseite | (Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2O |
9.FB.05 | Alloriite | (Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6 |
9.FB.05 | Biachellaite | (Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2O |
9.FB.05 | Fantappièite | [Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2O |
9.FB.05 | Kyanoxalite | Na7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5) |
9.FB.05 | Balliranoite | (Na,K)6Ca2(Si6Al6O24)Cl2(CO3) |
9.FB.05 | Carbobystrite | Na8(Al6Si6O24)(CO3) · 3.5H2O |
9.FB.05 | Depmeierite | Na8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x |
9.FB.05 | Kircherite | Na5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2O |
9.FB.05 | Sulfhydrylbystrite | Na5K2Ca[Al6Si6O24](S5)2(SH) |
9.FB.10 | Bicchulite | Ca2(Al2SiO6)(OH)2 |
9.FB.10 | Danalite | Be3Fe2+4(SiO4)3S |
9.FB.10 | Genthelvite | Be3Zn4(SiO4)3S |
9.FB.10 va | Hackmanite | Na8Al6Si6O24(Cl2,S) |
9.FB.10 | Haüyne | Na3Ca(Si3Al3)O12(SO4) |
9.FB.10 | Helvine | Be3Mn2+4(SiO4)3S |
9.FB.10 | Kamaishilite | Ca2(Al2SiO6)(OH)2 |
9.FB.10 | Lazurite | Na7Ca(Al6Si6O24)(SO4)(S3) · H2O |
9.FB.10 | Nosean | Na8(Al6Si6O24)(SO4) · H2O |
9.FB.10 | Sodalite | Na4(Si3Al3)O12Cl |
9.FB.10 | Tsaregorodtsevite | (N(CH3)4)(AlSi5O12) |
9.FB.10 | Vladimirivanovite | Na6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2O |
9.FB.15 | Marialite | Na4Al3Si9O24Cl |
9.FB.15 | Meionite | Ca4Al6Si6O24CO3 |
9.FB.15 | Silvialite | (Ca,Na)4(Al6Si6O24)(SO4,CO3) |
Fluorescence of Tugtupite
Bright magenta-red to pink (SW UV). A stone was initially pink, and turned red immediately upon exposure to long-wave UV radiation. After the UV lamp was turned off, the stone returned to pink after several minutes. This chromatic change was repeatable.
Specifically, it becomes dark red when exposed to UV radiation (or is irradiated by X-rays), and the colour fades to a paler red, pink or white when kept in the dark or exposed to bright light for a few minutes. This colour behaviour is probably due to an electron trapped in a Cl vacancy and associated sulphur polyanions.
Specifically, it becomes dark red when exposed to UV radiation (or is irradiated by X-rays), and the colour fades to a paler red, pink or white when kept in the dark or exposed to bright light for a few minutes. This colour behaviour is probably due to an electron trapped in a Cl vacancy and associated sulphur polyanions.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Tugtupite
mindat.org URL:
https://www.mindat.org/min-4044.html
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References for Tugtupite
Localities for Tugtupite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Canada | |
| Olivier Langelier Collection |
| Horváth et al. (1990) |
Greenland | |
| Petersen (1995) +1 other reference |
Cran Cowan Specimen | |
Otter (2023) | |
Soerensen (1962) | |
Sørensen (1960) +2 other references | |
| Sørensen et al. (2001) |
Petersen et al. (2002) | |
Cole (2003) | |
| ørensen (1960) +1 other reference |
Russia | |
| World of Stones 95:5-6 +2 other references |
Men'shikov (2006) | |
Mikhailova et al. (2023) | |
| Lapis |
[World of Stones 95:5-6 | |
Yakovenchuk et al. (2011) | |
Ermolaeva et al. (2007) |
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Poudrette quarry, Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada