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Tugtupite

A valid IMA mineral species
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About TugtupiteHide

Formula:
Na4BeAlSi4O12Cl
Colour:
Commonly red, also white to pink, bluish white, greenish white
Lustre:
Sub-Vitreous, Waxy, Greasy, Dull
Hardness:
4
Specific Gravity:
2.33
Crystal System:
Tetragonal
Member of:
Name:
Named after its discovery locality, Tugtup Agtâkorfia, Narsaq municipality, Greenland.
See also: Sodalite Group.

Piezoelectric.




Unique IdentifiersHide

Mindat ID:
4044
Long-form identifier:
mindat:1:1:4044:6
GUID
(UUID V4):
7af3906a-ad1e-497a-9eb3-ac2c672b69d7

IMA Classification of TugtupiteHide

Classification of TugtupiteHide

9.FB.10

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.3.7

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
17.3.5

17 : Silicates Containing other Anions
3 : Silicates with chloride (including aluminosilicates)

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
TtpIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TugtupiteHide

Sub-Vitreous, Waxy, Greasy, Dull
Transparency:
Translucent
Colour:
Commonly red, also white to pink, bluish white, greenish white
Comment:
colorless in transmitted light
Streak:
white
Hardness:
Tenacity:
Brittle
Cleavage:
Distinct/Good
On {101}; on {110} fair.
Fracture:
Step-Like
Comment:
Usually shows cleavage because of the great number of planes associated with the cleavage forms.
Density:
2.33 g/cm3 (Measured)    2.34 g/cm3 (Calculated)

Optical Data of TugtupiteHide

Type:
Uniaxial (+)
RI values:
nω = 1.496 nε = 1.502
Birefringence:
0.006
Max Birefringence:
δ = 0.006
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
Anomalously biaxial
Pleochroism:
Weak
Comments:
Weak lilac to weak red-orange.

Chemistry of TugtupiteHide

Mindat Formula:
Na4BeAlSi4O12Cl
Common Impurities:
Fe,Ga,Mg,Ca,K,H2O,S

Crystallography of TugtupiteHide

Crystal System:
Tetragonal
Class (H-M):
4 - Disphenoidal
Space Group:
I4
Cell Parameters:
a = 8.640(1) Å, c = 8.873(1) Å
Ratio:
a:c = 1 : 1.027
Unit Cell V:
662.4 ų
Z:
2
Morphology:
Short tetragonal prisms with pyramids, sphenoids, and bisphenoids. Fine-grained aggregates; massive.
Twinning:
On (101), penetration twinning resulting in pseudocubic triplets; pseudotrigonal contact twins with composition planes (101) and (011).
Comment:
Pseudo-cubic. Cell parameters from Hassan and Grundy (1991).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0003450TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040293
0003451TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040306
0003452TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040338
0003453TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040386
0003454TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040483
0003455TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040579
0003456TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040692
0003457TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040789
0003458TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040869
0003459TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040917
0003460TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-49720040982
0003461TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497200401046
0003462TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497200401094
0003463TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497200401142
0003464TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497200401175
0003465TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497200401207
0003466TugtupiteAntao S M, Hassan I, Parise J B (2004) Tugtupite: High-temperature structures obtained from in situ synchrotron diffraction and Rietveld refinements American Mineralogist 89 492-497200401255
0005268TugtupiteHassan I, Grundy H D (1991) The crystal structure and thermal expansion of tugtupite, Na8[Al2Be2Si8O24]Cl2 The Canadian Mineralogist 29 385-39019910293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Radiation - Copper Kα
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
6.19 Å(40)
6.11 Å(10)
4.43 Å(10)
3.59 Å(40)
3.54 Å(100)
2.52 Å(20)
2.06 Å(10)
2.04 Å(10)
Comments:
Canadian Mineralogist 29:385

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
22 : Hydration and low-𝑇 subsurface aqueous alteration (see also #23)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Stage 7: Great Oxidation Event<2.4
47g : [Halogen-bearing surface weathering minerals]

Type Occurrence of TugtupiteHide

Place of Conservation of Type Material:
University of Copenhagen, Copenhagen, Denmark, 1970.276.
The Natural History Museum, London, England, 1967,394.
Geological Setting of Type Material:
As replacements of chkalovite in hydrothermal veins cutting sodalite syenite and syenite.
Associated Minerals at Type Locality:
Reference:
Sørenson, H. (1962) On the occurrence of steenstrupine in the Ilimaussaq massif, south-west greenland. Medd. om Grønland, 167(1), 1-251 (218-219).

Other Language Names for TugtupiteHide

German:Tugtupit
Simplified Chinese:硅铍铝钠石
铍方钠石
Spanish:Tugtupita
Traditional Chinese:矽鈹鋁鈉石
鈹方鈉石

Relationship of Tugtupite to other SpeciesHide

Member of:
Other Members of this group:
DanaliteBe3Fe2+4(SiO4)3SIso. 4 3m : P4 3n
GenthelviteBe3Zn4(SiO4)3SIso. 4 3m : P4 3n
HelvineBe3Mn2+4(SiO4)3SIso. 4 3m : P4 3n

Common AssociatesHide

Associated Minerals Based on Photo Data:
99 photos of Tugtupite associated with ChkaloviteNa2BeSi2O6
66 photos of Tugtupite associated with AnalcimeNa(AlSi2O6) · H2O
53 photos of Tugtupite associated with SodaliteNa4(Si3Al3)O12Cl
37 photos of Tugtupite associated with PolylithioniteKLi2Al(Si4O10)(F,OH)2
28 photos of Tugtupite associated with Arfvedsonite[Na][Na2][Fe2+4Fe3+]Si8O22(OH)2
24 photos of Tugtupite associated with AlbiteNa(AlSi3O8)
18 photos of Tugtupite associated with UssingiteNa2AlSi3O8OH
14 photos of Tugtupite associated with SphaleriteZnS
9 photos of Tugtupite associated with AegirineNaFe3+Si2O6
8 photos of Tugtupite associated with NatroliteNa2Al2Si3O10 · 2H2O

Related Minerals - Strunz-mindat GroupingHide

9.FB.SteudeliteNa3(K17Ca7)Ca4(Al24Si24O96)(SO3)6F6 · 4H2OHex. 6 m2 : P62c
9.FB.SapozhnikoviteNa8(Al6Si6O24)(HS)2Iso. 4 3m : P4 3n
9.FB.BetziteNa6Ca2(Al6Si6O24)Cl4Hex. 6 : P63
9.FB.SlyudyankaiteNa28Ca4(Si24Al24O96)(SO4)6(S6)1/3(CO2) · 2H2OTric. 1 : P1
9.FB.Bolotinaite(Na7◻)(Al6Si6O24)F · 4H2OIso. 4 3m : I4 3m
9.FB.Wenlanzhangite-(Y)Y2V3+2V4+2(SiO4)2O4(OH)4Tric. 1 : P1
9.FB.05Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClTrig. 3m : P3 1c
9.FB.05Cancrinite(Na,Ca,◻)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
9.FB.05CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex. 6mm : P63mc
9.FB.05Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
9.FB.05Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
9.FB.05Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
9.FB.05HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex. 6 : P63
9.FB.05Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex. 6 : P6
9.FB.05MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex. 6 2 2 : P63 2 2
9.FB.05PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex. 6 : P63
9.FB.05Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex. 6/m : P63/m
9.FB.05Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6 · 2H2OHex.
9.FB.05Tounkite(Na,Ca,K)8(Si6Al6)O24(SO4)2Cl · 0.5H2OHex. 6 2 2 : P62 2 2
9.FB.05Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
9.FB.05Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
9.FB.05Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
9.FB.05Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
9.FB.05Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
9.FB.05KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
9.FB.05Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
9.FB.05CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
9.FB.05DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
9.FB.05KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
9.FB.05SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P3 1c
9.FB.10BicchuliteCa2(Al2SiO6)(OH)2Iso. 4 3m : I4 3m
9.FB.10DanaliteBe3Fe2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10GenthelviteBe3Zn4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10 vaHackmaniteNa8Al6Si6O24(Cl2,S)
9.FB.10HaüyneNa3Ca(Si3Al3)O12(SO4)Iso. 4 3m : P4 3n
9.FB.10HelvineBe3Mn2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10KamaishiliteCa2(Al2SiO6)(OH)2Tet.
9.FB.10LazuriteNa7Ca(Al6Si6O24)(SO4)(S3) · H2OIso. 4 3m : P4 3n
9.FB.10NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
9.FB.10SodaliteNa4(Si3Al3)O12ClIso. 4 3m : P4 3n
9.FB.10Tsaregorodtsevite(N(CH3)4)(AlSi5O12)Orth. 2 2 2 : I2 2 2
9.FB.10VladimirivanoviteNa6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2OOrth. mmm (2/m 2/m 2/m)
9.FB.15MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
9.FB.15MeioniteCa4Al6Si6O24CO3Tet. 4/m : I4/m
9.FB.15Silvialite(Ca,Na)4(Al6Si6O24)(SO4,CO3)Tet. 4/m : I4/m

Fluorescence of TugtupiteHide

Bright magenta-red to pink (SW UV). A stone was initially pink, and turned red immediately upon exposure to long-wave UV radiation. After the UV lamp was turned off, the stone returned to pink after several minutes. This chromatic change was repeatable.
Specifically, it becomes dark red when exposed to UV radiation (or is irradiated by X-rays), and the colour fades to a paler red, pink or white when kept in the dark or exposed to bright light for a few minutes. This colour behaviour is probably due to an electron trapped in a Cl vacancy and associated sulphur polyanions.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TugtupiteHide

References for TugtupiteHide

Reference List:

Localities for TugtupiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
  • Québec
    • Abitibi-Témiscamingue
      • La Vallée-de-l'Or RCM
        • Réservoir-Dozois
Olivier Langelier Collection
    • Montérégie
      • La Vallée-du-Richelieu RCM
        • Mont Saint-Hilaire
Horváth et al. (1990)
Greenland
 
  • Kujalleq
Petersen (1995) +1 other reference
Cran Cowan Specimen
Otter (2023)
Soerensen (1962)
Sørensen (1960) +2 other references
        • Kvanefjeld deposit
Sørensen et al. (2001)
Petersen et al. (2002)
Cole (2003)
      • Tunulliarfik Fjord
ørensen (1960) +1 other reference
Russia
 
  • Murmansk Oblast
    • Khibiny Massif
World of Stones 95:5-6 +2 other references
Men'shikov (2006)
Mikhailova et al. (2023)
    • Lovozersky District
      • Alluaiv Mountain
        • Umbozero mine
Lapis
[World of Stones 95:5-6
Yakovenchuk et al. (2011)
Ermolaeva et al. (2007)
 
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