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Tsaregorodtsevite

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About TsaregorodtseviteHide

05948440015669808079021.jpg
Sergei V. Tsaregorodtsev
Formula:
(N(CH3)4)(AlSi5O12)
Colour:
Colourless to white
Lustre:
Vitreous
Hardness:
6
Crystal System:
Orthorhombic
Name:
Named after Sergei Vasil'evich Tsaregorodtsev (Сергея Васильевича Царегородцева) (1953-1986), Russian mineral collector of the Urals.
Sodalite Group. The mineral contains (as the only one known) the tetramethylammonium ion, [N(CH3)4]+.


Classification of TsaregorodtseviteHide

Approved
First Published:
1993
9.FB.10

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.3.8

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species

Physical Properties of TsaregorodtseviteHide

Vitreous
Transparency:
Transparent
Colour:
Colourless to white
Hardness:

Optical Data of TsaregorodtseviteHide

Type:
Biaxial (-)
RI values:
nα = 1.529 nγ = 1.531
2V:
Measured: 76°
Max Birefringence:
δ = 0.002
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
none

Chemical Properties of TsaregorodtseviteHide

Formula:
(N(CH3)4)(AlSi5O12)
IMA Formula:
N(CH3)4Si4(SiAl)O12

Crystallography of TsaregorodtseviteHide

Crystal System:
Orthorhombic
Cell Parameters:
a = 8.98 Å, b = 8.93 Å, c = 8.92 Å
Ratio:
a:b:c = 1.006 : 1 : 0.999
Unit Cell V:
715.31 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

Image Loading

Radiation - Copper Kα
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Type Occurrence of TsaregorodtseviteHide

Reference:
Pautov, L.A., Karpenko, V.Y., Sokolova, E.V., Ignatenko, K.I. (1993) Tsaregorodtsevite N(CH3)4[Si2(Si0.5Al0.5)O6]2 — a new mineral. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 128(1): 128-135.

Synonyms of TsaregorodtseviteHide

Other Language Names for TsaregorodtseviteHide

Relationship of Tsaregorodtsevite to other SpeciesHide

Other Members of this group:
Haüyne(Na,K)3(Ca,Na)(Al3Si3O12)(SO4,S,Cl)Iso. 4 3m : P4 3n
LazuriteNa6Ca2(Al6Si6O24)(SO4,S,S2,S3,Cl,OH)2Iso. 4 3m : P4 3n
NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
SodaliteNa8(Al6Si6O24)Cl2Iso. 4 3m : P4 3n
VladimirivanoviteNa6Ca2(Al6Si6O24)(SO4,S3,S2,Cl)2 · H2OOrth. mmm (2/m 2/m 2/m)

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Tsaregorodtsevite associated with QuartzSiO2
1 photo of Tsaregorodtsevite associated with ClinochloreMg5Al(AlSi3O10)(OH)8

Related Minerals - Nickel-Strunz GroupingHide

9.FB.05Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClHex.
9.FB.05Cancrinite(Na,Ca,☐)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
9.FB.05CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex.
9.FB.05Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
9.FB.05Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
9.FB.05Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Hex.
9.FB.05HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex.
9.FB.05Liottite(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4Hex.
9.FB.05MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex.
9.FB.05PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex.
9.FB.05Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex.
9.FB.05Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6•2H2OHex.
9.FB.05Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex.
9.FB.05Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
9.FB.05Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
9.FB.05Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
9.FB.05Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
9.FB.05Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
9.FB.05KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
9.FB.05Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
9.FB.05CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
9.FB.05DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (x<0.5)Hex. 6 : P63
9.FB.05KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
9.FB.10BicchuliteCa2(Al2SiO6)(OH)2Iso. 4 3m : I4 3m
9.FB.10DanaliteBe3Fe2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10GenthelviteBe3Zn4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10Haüyne(Na,K)3(Ca,Na)(Al3Si3O12)(SO4,S,Cl)Iso. 4 3m : P4 3n
9.FB.10HelvineBe3Mn2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10KamaishiliteCa2(Al2SiO6)(OH)2Tet.
9.FB.10LazuriteNa6Ca2(Al6Si6O24)(SO4,S,S2,S3,Cl,OH)2Iso. 4 3m : P4 3n
9.FB.10NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
9.FB.10SodaliteNa8(Al6Si6O24)Cl2Iso. 4 3m : P4 3n
9.FB.10TugtupiteNa4BeAlSi4O12ClTet. 4 : I4
9.FB.15MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
9.FB.15MeioniteCa4Al6Si6O24CO3Tet. 4/m : I4/m
9.FB.15Silvialite(Ca,Na)4(Al6Si6O24)(SO4,CO3)Tet. 4/m : I4/m

Related Minerals - Dana Grouping (8th Ed.)Hide

76.2.3.1SodaliteNa8(Al6Si6O24)Cl2Iso. 4 3m : P4 3n
76.2.3.2NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
76.2.3.3Haüyne(Na,K)3(Ca,Na)(Al3Si3O12)(SO4,S,Cl)Iso. 4 3m : P4 3n
76.2.3.4LazuriteNa6Ca2(Al6Si6O24)(SO4,S,S2,S3,Cl,OH)2Iso. 4 3m : P4 3n
76.2.3.5BicchuliteCa2(Al2SiO6)(OH)2Iso. 4 3m : I4 3m
76.2.3.6KamaishiliteCa2(Al2SiO6)(OH)2Tet.
76.2.3.7TugtupiteNa4BeAlSi4O12ClTet. 4 : I4

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for TsaregorodtseviteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Leoni, L., Mellini, M., Merlino, S., Orlandi, P. (1979) Cancrinite-like minerals: new data and crystal chemical considerations. Rendiconti della Società Italiana di Mineralogia e Petrologia: 35: 713-719.
Hassan, I., Grundy, H.D. (1984) The crystal structures of sodalite-group minerals. Acta Crystallographica: B40: 6-13.
Sokolova, E.V., Rybakov, V.B., Pautov, L.A. (1991) The crystal structure of a new natural tetramethylammonium aluminosilicate [N(CH3)4][Si2(Si0.5Al0.5)O6]2. Soviet Physics - Doklady: 36: 267-269.
Pautov, L.A., Karpenko, V.Y., Sokolova, E.V., Ignatenko, K.I. (1993) Tsaregorodtsevite N(CH3)4[Si2(Si0.5Al0.5)O6]2 — a new mineral. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 128(1): 128-135.
Sokolova, E.V., Rybakov, V.B., Pautov, L.A., Pushcharovskii, D.Y. (1993) Structural changes in tsaregorodtsevite. Doklady Akademii Nauk SSSR: 332: 309-312.
Sokolova, E.V., Rybakov, V.B., Pautov, L.A., Pushcharovskii, D.Y. (1993) Structural changes in tsaregorodtsevite. Physics–Doklady: 38: 400-402.
Jambor, J.L., Roberts, A.C., Vanko, D.A. (1994) New mineral names. American Mineralogist: 79: 1009-1014.
Sherriff, B.L., Sokolova, E.V., Cramer, J., Kunath-Fandrei, G., Jäger, C., Pautov, L.A. (1997) Changes in the crystal structure of tsaregorodtsevite [N(CH3)4][Si2(Si0.5Al0.5)O6]2 on heating. American Mineralogist: 82: 405-415.
Manadrino, J.A. (1997) New Minerals 1990-1994. Mineralogical Record, Tuscon, Arizona.

Internet Links for TsaregorodtseviteHide

Localities for TsaregorodtseviteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Poland
 
  • Lower Silesian Voivodeship
    • Kłodzko County
      • Nowa Ruda
        • Słupiec Mine
Ł. Kruszewski PXRD data
  • Silesian Voivodeship
    • Wodzisław Co.
      • Radlin
Łukasz Kruszewski (2012) Unique chloride assemblage of exhalative origin from burning coal-mining dump in Radlin (Rybnik Coal Area, S Poland). Mineralogical Society of Poland Special Papers 40
Russia (TL)
 
  • Khanty-Mansi Autonomous Okrug
    • Man'-Khambo Mountains
Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
 
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