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Liottite

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About LiottiteHide

Formula:
(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4
Colour:
colourless
Hardness:
5
Crystal System:
Hexagonal
Name:
Named in 1977 by S. Merlino and P. Orlandi in honor of Luciano Liotti (1932 - 2006), a mineral collector who donated the material in which liottite was first found.
This page provides mineralogical data about Liottite.


Classification of LiottiteHide

Approved
Approval Year:
1975
9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
76.2.5.9

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
17.10.5

17 : Silicates Containing other Anions
10 : Silicates with sulphate, molybdate or tungstate

Physical Properties of LiottiteHide

Colour:
colourless
Streak:
white
Hardness:

Optical Data of LiottiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.530 nε = 1.528
Max Birefringence:
δ = 0.002
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemical Properties of LiottiteHide

Formula:
(Na,K)16Ca8(Al6Si6O24)3(SO4)5Cl4
IMA Formula:
Na16Ca8Si18Al18O72(SO4)5Cl4
Common Impurities:
Fe

Crystallography of LiottiteHide

Crystal System:
Hexagonal
Class (H-M):
6 - Trigonal Dipyramidal
Space Group:
P6
Cell Parameters:
a = 12.84 Å, c = 16.09 Å
Ratio:
a:c = 1 : 1.253
Unit Cell V:
2,297.29 ų (Calculated from Unit Cell)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0005509LiottiteBallirano P, Merlino S, Bonaccorsi E, Maras A (1996) The crystal structure of liottite, a six-layer member of the cancrinite group The Canadian Mineralogist 34 1021-103019960293
CIF Raw Data - click here to close

Type Occurrence of LiottiteHide

Synonyms of LiottiteHide

Other Language Names for LiottiteHide

German:Liottit
Spanish:Liottita

Relationship of Liottite to other SpeciesHide

Other Members of this group:
Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClHex.
Cancrinite(Na,Ca,☐)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex.
CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex.
KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex.
PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex.
Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex.
Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6•2H2OHex.
SulfhydrylbystriteNa5K2Ca[Al6Si6O24](S5)2(SH)Trig. 3m : P3 1c
Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex.
UM2004-48-SiO:AlClCaNaS(Na,Ca)8(Si6Al6)O24(SO4)1.7Cl1.3
UM2009-23-SiO:AlCCaClHKNaS(Na,Ca)24K10[(Si,Al)60O120](SO4)5.6Cl1.5(CO3)0.4·11H2OTrig. 3 : P3
Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Liottite associated with MelaniteCa3Fe3+2(SiO4)3
3 photos of Liottite associated with SanidineK(AlSi3O8)
2 photos of Liottite associated with GrossularCa3Al2(SiO4)3
1 photo of Liottite associated with VesuvianiteCa19Fe3+Al4(Al6Mg2)(☐4)☐[Si2O7]4[(SiO4)10]O(OH)9
1 photo of Liottite associated with Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2
1 photo of Liottite associated with Augite(CaxMgyFez)(Mgy1Fez1)Si2O6

Related Minerals - Nickel-Strunz GroupingHide

9.FB.05Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClHex.
9.FB.05Cancrinite(Na,Ca,☐)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
9.FB.05CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex.
9.FB.05Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
9.FB.05Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
9.FB.05Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
9.FB.05HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex.
9.FB.05MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex.
9.FB.05PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex.
9.FB.05Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex.
9.FB.05Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6•2H2OHex.
9.FB.05Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex.
9.FB.05Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
9.FB.05Marinellite(Na,K)42Ca6(Al6Si6O24)6(SO4)8Cl2 · 3H2OTrig. 3m : P3 1c
9.FB.05Farneseite(Na,Ca,K)56(Al6Si6O24)7(SO4)12 · 6H2OHex. 6/m : P63/m
9.FB.05Alloriite(Na,Ca,K)26Ca4(Al6Si6O24)4(SO4)6Cl6Trig. 3m : P3 1c
9.FB.05Biachellaite(Na,Ca,K)8(Al6Si6O24)(SO4)2(OH)0.5 · H2OTrig. 3 : P3
9.FB.05Fantappièite[Na82.5Ca33K16.5](Si99Al99O396)(SO4)33 · 4H2OTrig. 3 : R3
9.FB.05KyanoxaliteNa7(Al6-xSi6+xO24)(C2O4)0.5+x · 5H2O (0 < x < 0.5)Hex. 6 : P63
9.FB.05Balliranoite(Na,K)6Ca2(Si6Al6O24)Cl2(CO3)Hex. 6 : P63
9.FB.05CarbobystriteNa8(Al6Si6O24)(CO3) · 3.5H2OTrig. 3m : P3 1c
9.FB.05DepmeieriteNa8(Al6Si6O24)(PO4,CO3)1-x · 3H2O (xHex. 6 : P63
9.FB.05KircheriteNa5Ca2K(Al6Si6O24)(SO4)2 · 0.33H2OTrig. 3 2 : R3 2
9.FB.10BicchuliteCa2(Al2SiO6)(OH)2Iso. 4 3m : I4 3m
9.FB.10DanaliteBe3Fe2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10GenthelviteBe3Zn4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10Haüyne(Na,K)3(Ca,Na)(Al3Si3O12)(SO4,S,Cl)Iso. 4 3m : P4 3n
9.FB.10HelvineBe3Mn2+4(SiO4)3SIso. 4 3m : P4 3n
9.FB.10KamaishiliteCa2(Al2SiO6)(OH)2Tet.
9.FB.10LazuriteNa6Ca2(Al6Si6O24)(SO4,S,S2,S3,Cl,OH)2Iso. 4 3m : P4 3n
9.FB.10NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
9.FB.10SodaliteNa4(Si3Al3)O12ClIso. 4 3m : P4 3n
9.FB.10Tsaregorodtsevite(N(CH3)4)(AlSi5O12)Orth.
9.FB.10TugtupiteNa4BeAlSi4O12ClTet. 4 : I4
9.FB.15MarialiteNa4Al3Si9O24ClTet. 4/m : I4/m
9.FB.15MeioniteCa4Al6Si6O24CO3Tet. 4/m : I4/m
9.FB.15Silvialite(Ca,Na)4(Al6Si6O24)(SO4,CO3)Tet. 4/m : I4/m

Related Minerals - Dana Grouping (8th Ed.)Hide

76.2.5.1Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
76.2.5.2Bystrite(Na,K)7Ca(Al6Si6O24)(S5)ClHex.
76.2.5.3Cancrinite(Na,Ca,☐)8(Al6Si6O24)(CO3,SO4)2 · 2H2OHex. 6 : P63
76.2.5.4CancrisiliteNa7(Al5Si7O24)(CO3) · 3H2OHex.
76.2.5.5Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
76.2.5.6Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
76.2.5.7Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
76.2.5.8HydroxycancriniteNa8(Al6Si6O24)(OH)2 · 2H2OHex.
76.2.5.10MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex.
76.2.5.11PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex.
76.2.5.12Quadridavyne(Na,K)6Ca2(Al6Si6O24)Cl4Hex.
76.2.5.13Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6•2H2OHex.
76.2.5.14Tounkite(Na,Ca,K)8(Al6Si6O24)(SO4)2Cl · H2OHex.
76.2.5.15Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
76.2.5.16Wenkite(Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2OHex.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

17.10.1NoseanNa8(Al6Si6O24)(SO4) · H2OIso. 4 3m : P4 3n
17.10.2PitiglianoiteNa6K2(Al6Si6O24)(SO4) · 2H2OHex.
17.10.3Vishnevite(Na,K)8(Al6Si6O24)(SO4,CO3) · 2H2OHex. 6 : P63
17.10.4Haüyne(Na,K)3(Ca,Na)(Al3Si3O12)(SO4,S,Cl)Iso. 4 3m : P4 3n
17.10.6Latiumite(Ca,K)4(Si,Al)5O11(SO4,CO3)Mon.
17.10.7Tuscanite(K(Ca,Na)6(Si,Al)10O22[SO4,CO3,(OH)2] · H2OMon.
17.10.8MicrosommiteNa4K2Ca2(Al6Si6O24)(SO4)Cl2Hex.
17.10.9Delhayelite(Na,K)10Ca5Al6Si32O80(Cl2,F2,SO4)3 · 18H2OOrth.
17.10.10HydrodelhayeliteKCa2AlSi7O17(OH)2 · 6H2OOrth.
17.10.11Davyne(Na,K)6Ca2(Al6Si6O24)(Cl2,SO4)2Hex. 6/m : P63/m
17.10.12Afghanite(Na,K)22Ca10(Si24Al24O96)(SO4)6Cl6Trig. 3m : P3 1c
17.10.13Franzinite(Na,K)6Ca2(Al6Si6O24)(SO4)2 · 0.5H2OHex.
17.10.14Giuseppettite(Na,K,Ca)7-8(Al6Si6O24)(SO4,Cl)1-2Trig. 3m : P3 1c
17.10.15Sacrofanite(Na61K19Ca32)(Si84Al84O336)(SO4)26Cl2F6•2H2OHex.
17.10.16Chessexite(Na,K)4Ca2(Mg,Zn)3Al8(SO4)10(SiO4)2 · 40H2OOrth.
17.10.17InneliteNa2CaBa4Ti3(Si2O7)2(SO4)2O4Tric. 1 : P1
17.10.18ThaumasiteCa3(SO4)[Si(OH)6](CO3) · 12H2OHex. 6 : P63
17.10.19Ellestadite
17.10.20ChlorellestaditeCa5(SiO4)1.5(SO4)1.5ClHex. 6/m : P63/m
17.10.21HydroxylellestaditeCa5(SiO4)1.5(SO4)1.5(OH)Hex. 6/mmm (6/m 2/m 2/m) : P63/mcm
17.10.22FluorellestaditeCa5(SiO4)1.5(SO4)1.5FHex.
17.10.23MattheddleitePb5(SiO4)1.5(SO4)1.5(Cl,OH)Hex. 6/m : P63/m
17.10.24QueititePb4Zn2(SO4)(SiO4)(Si2O7)Mon. 2 : P21
17.10.25RoeblingitePb2Ca6Mn2+(Si3O9)2(SO4)2(OH)2 · 4H2OMon. 2/m : B2/m
17.10.26YoshimuraiteBa2Mn2Ti(Si2O7)(PO4)O(OH)Tric. 1 : P1
17.10.27KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.
17.10.28Wenkite(Ba,K)4(Ca,Na)6[(Si,Al)20O39(OH)2](SO4)3 · 0.5H2OHex.
17.10.29MacquartiteCu2Pb7(CrO4)4(SiO4)2(OH)2Mon.
17.10.30WeliniteMn2+6(W6+,Mg)2(SiO4)2(O,OH)6Trig. 3 : P3

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for LiottiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Merlino, S., Orlandi, P. (1977) Liottite, a new mineral in the cancrinite-davyne group. American Mineralogist: 62: 321-326.
Leoni, L., Mellini, M., Merlino, S., Orlandi, P. (1979) Cancrinite-like minerals: new data and crystal chemical considerations. Rendiconti della Società Italiana di Mineralogia e Petrologia: 35: 713-719.
Rinaldi, R., Wenk, H.R. (1979) Stacking variations in cancrinite minerals. Acta Crystallographica: A35: 825-828.
Hassan, I., Grundy, H.D. (1984) The crystal structures of sodalite-group minerals. Acta Crystallographica: B40: 6-13.
Ballirano, P., Maras, A., Buseck, P.R. (1996) Crystal chemistry and IR spectroscopy of Cl- and SO4-bearing cancrinite-like minerals. American Mineralogist: 81: 1003-1012.
Ballirano, P., Merlino, S., Bonaccorsi, E., Maras, A. (1996) The crystal structure of liottite, a six-layer member of the cancrinite group. Canadian Mineralogist: 34: 1021-1030.

Internet Links for LiottiteHide

Localities for LiottiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Italy
 
  • Campania
    • Naples
      • Bacoli
Punzo I. (1996): La liottite di Torregaveta. Notizie del Gr. Miner. Geol. Napoletano, 1, 1, 3; www.geocities.com/gmgn/n1_96-4.htm; Fedele L., Tarzia M., Belkin H.E., De Vivo B., Lima A., Lowenstern J.B. (2006): Magmatic–hydrothermal fluid interaction and mineralization in alkali-syenite nodules from the Breccia Museo pyroclastic deposit, Naples, Italy. In: De Vivo B. (ed.), Volcanism in the Campania Plain: Vesuvius, Campi Flegrei and Ignimbrites. Developments in Volcanology, vol. 9, Elsevier B.V., Amsterdam, pages 125-161.
Russo, M. (2010) I minerali dell'Isola di Procida. Poster. Publisher: Associazione Vivara Onlus.
in the collection of Luigi Mattei
  • Lazio
    • Metropolitan City of Rome Capital
      • Magliano Romano
Liotti L. and Tealdi E. (1983): Il vulcanismo Sabatino ed i minerali della Caldera di Sacrofano. Riv. Miner. Ital., 2, 35-58.
      • Sacrofano
    • Viterbo Province
Stoppani, F.S., Curti, E. (1982): I Minerali del Lazio. Ed. Olimpia, Firenze, 154-158
      • Onano
Cresta, S., Duronio, F., Mancinella, D. (2002): Geositi e sistema delle arre protette del Lazio: idee per la geoconservazione. Il Cercapietre, 1-2/2002, 48-55
      • Valentano
Collected & analyzed by Rossano Carlini
  • Tuscany
    • Grosseto Province
      • Pitigliano
Merlino, S., Orlandi, P. (1977) Liottite, a new mineral in the cancrinite-davyne group. American Mineralogist: 62: 321-326
 
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