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Ashburtonite

A valid IMA mineral species
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About AshburtoniteHide

Formula:
Pb4Cu4(Si4O12)(HCO3)4(OH)3Cl · H2O
Colour:
Blue
Lustre:
Vitreous
Specific Gravity:
4.69 (Calculated)
Crystal System:
Tetragonal
Name:
Named in 1991 by Joel Denison Grice, Ernest (Ernie) Henry Nickel, and Robert A. Gault for the type locality near the Ashburton Downs pastoral lease and homestead, Western Australia, Australia.
Closely related to cerchiaraite group and bobmeyerite.


Unique IdentifiersHide

Mindat ID:
388
Long-form identifier:
mindat:1:1:388:1
GUID
(UUID V4):
1b222b53-700b-4550-be05-e95556431462

IMA Classification of AshburtoniteHide

Classification of AshburtoniteHide

9.CF.05

9 : SILICATES (Germanates)
C : Cyclosilicates
F : [Si4O12]8- 4-membered single rings, with insular complex anions
78.4.2.1

78 : Unclassified Silicates
4 :
17.4.13

17 : Silicates Containing other Anions
4 : Silicates with carbonates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
AhbIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of AshburtoniteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of AshburtoniteHide

Vitreous
Transparency:
Transparent
Colour:
Blue
Streak:
Pale blue
Tenacity:
Very brittle
Cleavage:
None Observed
Fracture:
Conchoidal
Density:
4.69 g/cm3 (Calculated)

Optical Data of AshburtoniteHide

Type:
Uniaxial (+)
RI values:
nω = 1.786(3) nε = 1.800(4)
Max Birefringence:
δ = 0.014
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High

Chemistry of AshburtoniteHide

Mindat Formula:
Pb4Cu4(Si4O12)(HCO3)4(OH)3Cl · H2O

Crystallography of AshburtoniteHide

Crystal System:
Tetragonal
Cell Parameters:
a = 14.234(7) Å, c = 6.103(5) Å
Ratio:
a:c = 1 : 0.429
Unit Cell V:
1,236.51 ų (Calculated from Unit Cell)
Z:
2
Comment:
I4/m, I4 and I4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001412AshburtoniteGrice J D, Nickel E H, Gault R A (1991) Ashburtonite, a new bicarbonate-silicate mineral from Ashburton Downs, Western Australia: Description and structure determination American Mineralogist 76 1701-170719910293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.2 Å(100)
4.495 Å(100)
3.333 Å(100)
3.013 Å(90)
5.644 Å(70)
2.611 Å(50)
2.805 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)

Type Occurrence of AshburtoniteHide

General Appearance of Type Material:
Clusters of clear blue, prismatic crystals up to 0.4 mm long.
Place of Conservation of Type Material:
Collection of the Canadian Museum of Nature under catalog no. CMN 58391 and in the Museum of Victoria, Melbourne, under catalog no. M40712.
Geological Setting of Type Material:
An assemblage of secondary minerals in a weathered shear zone that cuts a series of shales and graywackes.
Associated Minerals at Type Locality:
Reference:
Grice, J. D., Nickel, E. H., Gault, R. A. (1991): Ashburtonite, a new bicarbonate-silicate mineral from Ashburton Downs, Western Australia: Description and structure determination: American Mineralogist: 76, 1701-1707.

Synonyms of AshburtoniteHide

Other Language Names for AshburtoniteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
7 photos of Ashburtonite associated with CaledonitePb5Cu2(SO4)3(CO3)(OH)6
4 photos of Ashburtonite associated with BotallackiteCu2(OH)3Cl
3 photos of Ashburtonite associated with CerussitePbCO3
2 photos of Ashburtonite associated with QuartzSiO2
1 photo of Ashburtonite associated with DiaboleitePb2CuCl2(OH)4
1 photo of Ashburtonite associated with ClinoatacamiteCu2(OH)3Cl

Related Minerals - Strunz-mindat GroupingHide

9.CF.BobmeyeritePb4(Al3Cu)(Si4O12)(S0.5Si0.5O4)(OH)7Cl(H2O)3Orth. mmm (2/m 2/m 2/m) : Pnnm
9.CF.10Kainosite-(Y)Ca2(Y,Ce)2(Si4O12)(CO3) · H2OOrth. mmm (2/m 2/m 2/m)
9.CF.15ClinophosinaiteNa12(Ca,Sr)4(Si4O12)(PO4)4Mon. 2/m : P2/b
9.CF.15Phosinaite-(Ce)Na13Ca2(Ce,La,Th,Nd,Pr)(Si4O12)(PO4)4Orth. 2 2 2 : P21 21 2
9.CF.20StrakhoviteNaBa3Mn2+2Mn3+2Si6O19(OH)3Orth. mmm (2/m 2/m 2/m)
9.CF.25Cerchiaraite-(Mn)Ba4Mn3+4(Si4O12)O2(OH)4Cl2[Si2O3(OH)4]Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
9.CF.25Cerchiaraite-(Al)Ba4Al4O3(OH)3(Si4O12)[Si2O3(OH)4]Cl Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm
9.CF.25Cerchiaraite-(Fe)Ba4Fe3+4O3(OH)3(Si4O12)[Si2O3(OH)4]Cl Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm

Other InformationHide

Notes:
Decomposes rapidly in concentrated HCl and slowly in 0.2 M HCl, 1:1 HNO3, and concentrated H2SO4.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for AshburtoniteHide

References for AshburtoniteHide

Localities for AshburtoniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Western Australia
    • Ashburton Shire
Nickel et al. (1993)
Amer.Min. (1991)
USA
 
  • Arizona
    • Maricopa County
      • Osborn Mining District
        • Tonopah
          • Belmont Mountain
Collected by and in the collection of ... +1 other reference
      • Painted Rock Mountains
        • Painted Rock Mining District
          • Theba
PXRD analyzed by Tony Kampf. +1 other reference
 
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