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Imogolite

A valid IMA mineral species
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About ImogoliteHide

Formula:
Al2SiO3(OH)4
Colour:
White, blue, green, brown, black
Lustre:
Vitreous, Resinous, Waxy
Hardness:
2 - 3
Specific Gravity:
2.70
Name:
For the Japanese name, Imogo, of the brownish yellow volcanic ash soil of Japan in which it occurs.
Described in 1962, rejected by the IMA, but the name Imogolite was approved by the AIPEA Nomenclature Committee at its 1970 Tokyo meeting (Clays and Clay Minerals 19, 131 (1971). Reapproved by the CNMMN in 1986.

Widespread component of volcanic-ash-derived soils, but occurs also in other environments. The nano-sized particles have a tube-like morphology. There is longer-range order along the tube but with a cross-section of a few nanometers. The mineral essentially consists of a single modified gibbsite sheet rolled into a tube.

Related to allophane, another nanomineral.


Unique IdentifiersHide

Mindat ID:
2021
Long-form identifier:
mindat:1:1:2021:9
GUID
(UUID V4):
b0e69d60-253d-4b8b-81a5-5bf034502f1d

IMA Classification of ImogoliteHide

Approved
First published:
1962
Approval history:
Rejected in 1962, approved in 1986.

Classification of ImogoliteHide

9.ED.20

9 : SILICATES (Germanates)
E : Phyllosilicates
D : Phyllosilicates with kaolinite layers composed of tetrahedral and octahedral nets
71.1.5.3

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
1 : Sheets of 6-membered rings with 1:1 layers

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
ImoIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
ImoWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of ImogoliteHide

Vitreous, Resinous, Waxy
Transparency:
Transparent, Translucent
Colour:
White, blue, green, brown, black
Hardness:
2 - 3 on Mohs scale
Tenacity:
Brittle
Fracture:
Conchoidal
Density:
2.70 g/cm3 (Measured)    2.70 g/cm3 (Calculated)

Optical Data of ImogoliteHide

Type:
Isotropic
RI values:
n = 1.47 - 1.51
Birefringence:
Isotropic minerals have no birefringence
Surface Relief:
Moderate

Chemistry of ImogoliteHide

Mindat Formula:
Al2SiO3(OH)4

Crystallography of ImogoliteHide

Cell Parameters:
c = 8.4 Å
Morphology:
Conchoidal to earthy; as microscopic threadlike particles, and bundles of fine tubes, each about 20Å in diameter
Comment:
5.1 perpendicular to c axis

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
9 : Lava/xenolith minerals (hornfels, sanidinite facies)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
48 : Soil leaching zone minerals<0.6

Type Occurrence of ImogoliteHide

Geological Setting of Type Material:
Decomposition product of volcanic ash in soils in humid environments.
Reference:
Yoshinaga, N., Aomine, S. (1962) Imogolite in some Ando soils. Soil Science and Plant Nutrition: 8: 114-121.

Other Language Names for ImogoliteHide

German:Imogolit
Japanese:芋子石
Spanish:Imogolita

Related Minerals - Strunz-mindat GroupingHide

9.ED.ClinochrysotileMon. 2/m
9.ED.05DickiteAl2(Si2O5)(OH)4Mon. m : Bb
9.ED.05KaoliniteAl2(Si2O5)(OH)4Tric. 1 : P1
9.ED.05NacriteAl2(Si2O5)(OH)4Mon. m : Bb
9.ED.05Odinite(Fe,Mg,Al,Fe,Ti,Mn)2.4((Si,Al)2O5)(OH)4Mon. m : Bm
9.ED.10HalloysiteAl2(Si2O5)(OH)4Mon. m : Bb
9.ED.10HisingeriteFe3+2(Si2O5)(OH)4 · 2H2OMon.
9.ED.10HydrohalloysiteAl2Si2O5(OH)4 · 2H2OMon. m
9.ED.15AmesiteMg2Al(AlSiO5)(OH)4Tric. 1 : P1
9.ED.15AntigoriteMg3(Si2O5)(OH)4Mon. m : Bm
9.ED.15Berthierine(Fe2+,Fe3+,Al)3(Si,Al)2O5(OH)4Mon. m : Bm
9.ED.15Brindleyite(Ni,Al)3(Si,Al)2O5(OH)4Mon.
9.ED.15CaryopiliteMn2+3Si2O5(OH)4Mon.
9.ED.15CronstedtiteFe2+2Fe3+((Si,Fe3+)2O5)(OH)4Trig. 3m : P3 1m
9.ED.15Fraipontite(Zn,Al)3((Si,Al)2O5)(OH)4Mon.
9.ED.15Greenalite(Fe2+,Fe3+)2-3Si2O5(OH)4Mon.
9.ED.15KellyiteMn2+2Al(AlSiO5)(OH)4Hex. 6 : P63
9.ED.15LizarditeMg3(Si2O5)(OH)4Trig. 3m : P3 1m
9.ED.15ManandoniteLi2Al4(Si2AlB)O10(OH)8Orth. 2 2 2 : C2 2 21
9.ED.15NépouiteNi3Si2O5(OH)4Orth.
9.ED.15PecoraiteNi3(Si2O5)(OH)4Mon.
9.ED.15GuidottiiteMn2Fe3+(Fe3+SiO5)(OH)4Hex. 6 : P63
9.ED.15 vaChromoamesiteMg2(Al,Cr)(AlSiO5)(OH)4
9.ED.20Allophane(Al2O3)(SiO2)1.3-2 · 2.5-3H2OAmor.
9.ED.20ChrysocollaCu2-xAlx(H2-xSi2O5)(OH)4 · nH2O, x < 1Orth.
9.ED.20Neotocite(Mn,Fe,Mg)SiO3 · H2OAmor.
9.ED.25BismutoferriteFe3+2Bi(SiO4)2(OH)Mon. m : Bm
9.ED.25ChapmaniteFe3+2Sb3+(Si2O5)O3(OH)Mon. m : Bm
9.ED.30PianliniteAl2Si2O6(OH)2Orth.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ImogoliteHide

References for ImogoliteHide

Reference List:

Localities for ImogoliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada
 
McKeague et al. (1981)
Wang et al. (1982)
Wang et al. (1986)
China
 
  • Fujian
    • Xiamen
      • Tong'an District
Acta Petrologica et Mineralogica 11 (2)
Indonesia
 
  • West Java Province
    • Bandung Regency
      • Tangkuban Parahu Volcano
Dani Lukman Hakim (2016)
Japan
 
  • Gunma Prefecture
    • Kiryu City
Specimens supplied to Iwamoto by Yoshio ...
  • Kumamoto Prefecture
Russell et al. (1969) +1 other reference
  • Tochigi Prefecture
    • Kanuma City
Alfredo Petrov collection
New Zealand
 
Childs et al. (1983)
  • Southland Region
Childs et al. (1983)
Tanzania
 
  • Pwani Region
    • Kisarawe District
      • Pugu Hills
Schwaighofer et al. (1987)
UK
 
Tait et al. (1978)
USA
 
  • Hawaii
    • Maui County
Wada et al. (1972)
Bernard et al. (2004)
 
矿物 and/or 产地  
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