| Reference Type | Journal (article/letter/editorial) |
|---|
| Title | Geochemistry of cassiterite and skarn minerals as indicators for formation mechanism and fluid evolution of the newly discovered Jinshui skarn tin deposit in the East Kunlun orogenic belt, NW China |
|---|
| Journal | Ore Geology Reviews |
|---|
| Authors | Zhang, Xing-Kai | Author |
|---|
| Jiang, Shao-Yong | Author |
| Su, Hui-Min | Author |
| Wang, Wei | Author |
| Xia, Qinglin | Author |
| Liu, Yunpeng | Author |
| Li, Shien | Author |
| Year | 2025 |
|---|
| Page(s) | 106541 |
|---|
| URL | |
|---|
| DOI | doi:10.1016/j.oregeorev.2025.106541Search in ResearchGate |
|---|
| Generate Citation Formats |
| Classification | Not set | LoC | Not set |
|---|
| Mindat Ref. ID | 18141744 | Long-form Identifier | mindat:1:5:18141744:8 |
|---|
|
| GUID | 0 |
|---|
| Full Reference | Zhang, Xing-Kai, Jiang, Shao-Yong, Su, Hui-Min, Wang, Wei, Xia, Qinglin, Liu, Yunpeng, Li, Shien (2025) Geochemistry of cassiterite and skarn minerals as indicators for formation mechanism and fluid evolution of the newly discovered Jinshui skarn tin deposit in the East Kunlun orogenic belt, NW China. Ore Geology Reviews, 106541 doi:10.1016/j.oregeorev.2025.106541 |
|---|
| Plain Text | Zhang, Xing-Kai, Jiang, Shao-Yong, Su, Hui-Min, Wang, Wei, Xia, Qinglin, Liu, Yunpeng, Li, Shien (2025) Geochemistry of cassiterite and skarn minerals as indicators for formation mechanism and fluid evolution of the newly discovered Jinshui skarn tin deposit in the East Kunlun orogenic belt, NW China. Ore Geology Reviews, 106541 doi:10.1016/j.oregeorev.2025.106541 |
|---|
| In | Link this record to the correct parent record (if possible) |
|---|
| Abstract/Notes | Discovery of the Jinshui skarn-type tin deposit marked the first instance of a tin deposit to be uncovered in the central segment of the East Kunlun Orogenic Belt (EKOB) in northwestern China. To determine the timing of tin mineralization and elucidate the progression of the ore-forming hydrothermal system, we conducted geochronology of cassiterite and trace element analysis on various minerals hosted in skarn ores. The U–Pb dating results of the cassiterite indicate that tin mineralization took place at 392.9 ± 5.8 Ma, which closely aligns with the syenogranite emplacement at 396.1 ± 2.1 Ma in the Jinshui deposit. This correlation suggests a temporal link between tin mineralization and granitic magmatism. The deposit is characterized by two generations of cassiterite, with trace element analyses consistently showing that the dark cathodoluminescent cores have relatively high W and U concentrations, whereas the bright rims are enriched in Sc, Ti, V, Zr, In, and Hf. Additionally, the Zr/Hf ratios confirm that the syenogranite was the source of the ore-forming fluids. During the prograde skarn stage, the ore-forming fluids maintained an equilibrium closed system. Initially, the ore-forming fluid experienced reducing conditions, characterized by a low water-to-rock (W/R) ratio and a neutral to slightly alkaline pH. This fluid subsequently evolved into an oxidizing fluid with an elevated W/R ratio and an acidic pH. During the retrograde skarn stage, the fluid continued to exhibit high levels of oxygen fugacity. As the mineralization process progressed from the oxide stage to the quartz-cassiterite-sulfide stage, the presence of cassiterite indicates that the ore-forming fluid experienced two increases in oxygen fugacity, and this fluctuation may be attributed to the mixing of external fluids. The post-collisional extensional environment provided the tectonic background for the formation of the Jinshui tin deposit. Magmas derived from mantle sources ascended, and partial melting of the felsic crustal materials led to the formation of the Jinshui syenogranite after differentiation. Skarn-type tin deposits formed at the favorable locations of the contact between the granite body and the Sn-rich Jinshuikou Group. |
|---|
These are the references the publisher has listed as being connected to the article. Please check the article itself for the full list of references which may differ. Not all references are currently linkable within the Digital Library.
 | |
 | |
 | |
 | |
 | |
| Chen (2020) China. Lithos Proto-Tethys magmatic evolution along northern Gondwana: Insights from Late Silurian–Middle Devonian A-type magmatism, East Kunlun Orogen, Northern Tibetan Plateau 356–357 |
 | Cheng, Yanbo, Spandler, Carl, Kemp, Anthony, Mao, Jingwen, Rusk, Brian, Hu, Yi, Blake, Kevin (2019) Controls on cassiterite (SnO2) crystallization: Evidence from cathodoluminescence, trace-element chemistry, and geochronology at the Gejiu Tin District. American Mineralogist, 104 (1) 118-129 doi:10.2138/am-2019-6466 |
 | |
| Cui (2011) Acta Petrol. Sin. Early Ordovician island arc of Qimantag Mountain, eastern Kunlun: Evidences from geochemistry, Sm-Nd isotope and geochronology of intermediate-basic igneous rocks 27, 3365 |
 | Dong, Yunpeng, Sun, Shengsi, Santosh, M., Zhao, Jie, Sun, Jiaopeng, He, Dengfeng, Shi, Xiaohui, Hui, Bo, Cheng, Chao, Zhang, Guowei (2021) Central China Orogenic Belt and amalgamation of East Asian continents. Gondwana Research, 100. 131-194 doi:10.1016/j.gr.2021.03.006 |
 | |
 | |
| Feng (2020) Mineral Deposits Discovery of zoned garnet and epidote in Chagangnuoer iron deposit, western Tianshan Mountains, Xinjiang, and its significance 39, 805 |
| Feng (2024) Mineral Deposits Paleo-Tethys tectonic evolution and related large-scale metallogenic features in East Kunlun Orogen 43, 1316 |
 | |
| Gao (2010) Geol. Bull. China Zircon LA-ICP-MS U-Pb dating and geological significance of Bashierxi granite in the eastern Kunlun area, China 29, 1001 |
 | Gao, Yongbao; Hattori, Keiko; Bagas, Leon; Chen, Conglin; Li, Wenyuan; Wang, Yalei; Li, Kan; Sui, Qinglin; Wu, Huanhuan (2023) Origin of Silurian granite in the Baiganhu field, Eastern Kulun Terrane, NW China: Implications for the tectonic setting of Sn-W mineralization. Ore Geology Reviews, 163. doi:10.1016/j.oregeorev.2023.105749 |
 | |
 | Grew, E. S., Locock, A. J., Mills, S. J., Galuskina, I. O., Galuskin, E. V., Hålenius, U. (2013) Nomenclature of the garnet supergroup. American Mineralogist, 98 (4) 785-811 doi:10.2138/am.2013.4201 |
 | |
 | Guo, Jia; Zhang, Rongqing; Sun, Weidong; Ling, Mingxing; Hu, Yongbin; Wu, Kai; Luo, Ming; Zhang, Lichuan (2018) Genesis of tin-dominant polymetallic deposits in the Dachang district, South China: Insights from cassiterite U–Pb ages and trace element compositions. Ore Geology Reviews, 95. doi:10.1016/j.oregeorev.2018.03.023 |
 | Guo, Xianzheng; Jia, Qunzi; Lü, Xinbiao; Li, Jinchao; Kong, Huilei; Yao, Xuegang (2020) The Permian Sn metallogenic event and its geodynamic setting in East Kunlun, NW China: Evidence from zircon and cassiterite geochronology, geochemistry, and Sr–Nd–Hf isotopes of the Xiaowolong skarn Sn deposit. Ore Geology Reviews, 118. doi:10.1016/j.oregeorev.2020.103370 |
| Halden (1996) Can. Mineral. Determination of Lyapounov exponents to characterize the oscillatory distribution of trace elements in minerals 34, 1127 |
 | Harlaux, Matthieu; Kouzmanov, Kalin; Gialli, Stefano; Marger, Katharina; Bouvier, Anne-Sophie; Baumgartner, Lukas P.; Rielli, Andrea; Dini, Andrea; Chauvet, Alain; Kalinaj, Miroslav; et al. (2021) Fluid mixing as primary trigger for cassiterite deposition: Evidence from in situ δ18O-δ11B analysis of tourmaline from the world-class San Rafael tin (-copper) deposit, Peru. Earth and Planetary Science Letters, 563. 116889 doi:10.1016/j.epsl.2021.116889 |
 | He, Changtong; Qin, Kezhang; Zhao, Junxing; Evans, Noreen J.; Li, Jinxiang; Zhou, Qifeng; Wang, Fangyue; Li, Guangming (2023) Late beryllium enrichment during dynamic growth of vesuvianite and scapolite from the Cuonadong Sn-W-Be skarn, Tibet. Ore Geology Reviews, 157. doi:10.1016/j.oregeorev.2023.105442 |
 | He, Xiaohu, Zhao, Jianxin, Zhou, Renjie, Feng, Yuexing, Leonard, Nicole, Li, Fei, Liu, Zheng, Li, Wanting, Tan, Shucheng (2022) The distribution and substitution mechanism of trace elements in cassiterites: Constraints from LA-ICP-MS U Pb dating, elemental mapping and in situ trace element analyses of the Gejiu tin polymetallic deposit, SW China. Chemical Geology, 609. 121063 doi:10.1016/j.chemgeo.2022.121063 |
 | |
 | |
 | Huang, Wen-Qing; Ni, Pei; Pan, Jun-Yi; Zhou, Jun-Gui; Shui, Ting; Chen, Hui; Fan, Ming-Sen; Cui, Jian-Ming; Meng, Fan-Wei; Ding, Jun-Ying (2023) Relationship between cathodoluminescence response and trace element characterization of cassiterite from the Yunling tin deposit in western Yunnan, China: Implications for substitution mechanism and ore genesis. Ore Geology Reviews, 161. doi:10.1016/j.oregeorev.2023.105610 |
 | |
 | |
| Jiang (1992) , 1 |
| Jiang (1993) Geol. China Soft base hard base suture zone 03, 30 |
 | Jiang, Hai, Jiang, Shao-Yong, Li, Wen-Qian, Zhao, Kui-Dong, Peng, Ning-Jun (2018) Highly fractionated Jurassic I-type granites and related tungsten mineralization in the Shirenzhang deposit, northern Guangdong, South China: Evidence from cassiterite and zircon U-Pb ages, geochemistry and Sr-Nd-Pb-Hf isotopes. Lithos, 312. 186-203 doi:10.1016/j.lithos.2018.04.030 |
 | |
| Jiang (2020) Chin. Sci. Bull. Spatiotemporal distribution, geological characteristics and metallogenic mechanism of tungsten and tin deposits in China: An overview 65, 3730 |
 | |
 | Jiang, Shao-Yong, Xie, Hailin, Ren, Wenqi, Wang, Bin, Yuan, Feng, Liu, Xiufeng, Su, Hui-Min (2024) Discovery and Significance of Layered Chromite Mineralization in Mafic-Ultramafic Rocks from the Gayahe Area of the East Kunlun Orogenic Belt, Northwestern China. Journal of Earth Science, 35 (4) 1367-1372 doi:10.1007/s12583-024-0041-0 |
 | Jiang, Xiaojia; Chen, Xin; Zheng, Youye; Gao, Shunbao; Zhang, Zhaolu; Zhang, Yongchao; Zhang, Shuzhi (2020) Decoding the oxygen fugacity of ore-forming fluids from garnet chemistry, the Longgen skarn Pb-Zn deposit, Tibet. Ore Geology Reviews, 126. doi:10.1016/j.oregeorev.2020.103770 |
| Li (2006) Geol. Bull. China Geological features and origin of the Baigan Lake W-Sn deposit in the Ruoqiang area, East Kunlun Mountains, China 25, 277 |
| Li (2006) Earth Sci. Front. SHRIMP U-Pb zircon age of the granulite from the Qingshuiquan area, Central Eastern Kunlun Suture Zone 13, 311 |
 | Li, Yang, Zhang, Rong-Qing, He, Sheng, Chiaradia, Massimo, Li, Xian-Hua (2022) Pulsed exsolution of magmatic ore-forming fluids in tin-tungsten systems: a SIMS cassiterite oxygen isotope record. Mineralium Deposita, 57 (3) 343-352 doi:10.1007/s00126-022-01093-4 |
| Not Yet Imported: - journal-article : 10.18654/1000-0569/2023.04.07
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
| Liao (2016) Bull. Mineral. Petrol. Geochem. Petrologic and geochemical characteristics of the Hongshuihe iron deposit in Qinghai Province: Implication for ore genesis 35, 285 |
| Liu (2013) J. Earth Sci. Discovery of the Middle Devonian A-type granite from the Eastern Kunlun orogen and its tectonic implications 38, 947 |
| Liu (2013) Acta Petrol. Sin. Early Paleozoic tectonic transition from ocean subduction to collisional orogeny in the Eastern Kunlun region: Evidence from Huxiaoqin mafic rocks 29, 2093 |
| Liu (2023) J. Earth Sci. Petrogenesis and tectonic implications of Silurian to Devonian intermediate rocks from east part of East Kunlun orogenic belt 48, 2398 |
 | |
 | |
 | Liu, Shiyu, Liu, Yuping, Ye, Lin, Wei, Chen, Cai, Yi, Chen, Weihong (2021) Genesis of Dulong Sn-Zn-In Polymetallic Deposit in Yunnan Province, South China: Insights from Cassiterite U-Pb Ages and Trace Element Compositions. Minerals, 11 (2) 199 doi:10.3390/min11020199 |
 | Liu, Tong, Jiang, Shao-Yong, Cao, Shoulin, Wang, Wei, Su, Hui-Min, Yang, De, Li, Hua, He, Shuyue (2024) Cobalt enrichment and metallogenic mechanism of the Galinge skarn iron deposit in the Eastern Kunlun metallogenic belt, western China. Ore Geology Reviews, 170. 106147 doi:10.1016/j.oregeorev.2024.106147 |
 | Liu, Yongsheng, Hu, Zhaochu, Gao, Shan, Günther, Detlef, Xu, Juan, Gao, Changgui, Chen, Haihong (2008) In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard. Chemical Geology, 257 (1) 34-43 doi:10.1016/j.chemgeo.2008.08.004 |
| Long (2006) Geochimica Zircon U–Pb geochronology and geological implications of the granitoids in Jinshuikou, East Kunlun, NW China , 367 |
 | |
| Ma (2021) Geol. Bull. China Controls on crystallization of cassiterite from the southern Hunan Evidence from cathodoluminescence trace elements and geochronology 40, 1737 |
| Mao (2019) Econ. Geol. (Special Publications) Geology and metallogeny of tungsten and tin deposits in China 22, 411 |
| Not Yet Imported: Acta Petrologica Sinica - journal-article : 10.18654/1000-0569/2023.05.01
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
| Meinert (1997) Explor. Min. Geol. Application of skarn deposit zonation models to mineral exploration 2, 185 |
 | |
 | |
| Meyer (2024) Miner. Deposita Mineral chemistry of the Geyer SW tin skarn deposit: understanding variable fluid/rock ratios and metal fluxes 1–27 |
 | |
 | Möller, P, Dulski, P, Szacki, W, Malow, G, Riedel, E (1988) Substitution of tin in cassiterite by tantalum, niobium, tungsten, iron and manganese. Geochimica et Cosmochimica Acta, 52 (6) 1497-1503 doi:10.1016/0016-7037(88)90220-7 |
 | Müller, Barbara, Frischknecht, Rolf, Seward, Terry, Heinrich, Christoph, Camargo Gallegos, Willy (2001) A fluid inclusion reconnaissance study of the Huanuni tin deposit (Bolivia), using LA-ICP-MS micro-analysis. Mineralium Deposita, 36 (7) 680-688 doi:10.1007/s001260100195 |
 | Murray, Richard W., Buchholtz ten Brink, Marilyn R., Jones, David L., Gerlach, David C., Russ III, G.Price (1990) Rare earth elements as indicators of different marine depositional environments in chert and shale. Geology, 18 (3) 268 doi:10.1130/0091-7613(1990)018<0268:reeaio>2.3.co;2 |
 | Murciego, A., Garcla Sanchez, A., Dusausoy, Y., Martin Pozas, J. M., Ruck, R. (1997) Geochemistry and EPR of cassiterites from the Iberian Hercynian Massif. Mineralogical Magazine, 61 (406) 357-365 doi:10.1180/minmag.1997.061.406.03 |
 | Nazari-Dehkordi, Teimoor, Wang, Xiao-Lei, Hofmann, Axel, Zhang, Rong-Qing, Robb, Laurence, Ueckermann, Henriette (2023) Trace element compositions and geochronology of cassiterite from the Bushveld Large Igneous Province, South Africa. Journal of Geochemical Exploration, 254. 107310 doi:10.1016/j.gexplo.2023.107310 |
 | |
 | Ni, Pei; Pan, Jun-Yi; Han, Liang; Cui, Jian-Ming; Gao, Yan; Fan, Ming-Sen; Li, Wen-Sheng; Chi, Zhe; Zhang, Kai-Han; Cheng, Zhi-Lin; et al. (2023) Tungsten and tin deposits in South China: Temporal and spatial distribution, metallogenic models and prospecting directions. Ore Geology Reviews, 157. doi:10.1016/j.oregeorev.2023.105453 |
| Pan (2011) |
 | |
 | Park, Changyun, Song, Yungoo, Kang, Il-Mo, Shim, Jaecheon, Chung, Donghoon, Park, Chan-Soo (2017) Metasomatic changes during periodic fluid flux recorded in grandite garnet from the Weondong W-skarn deposit, South Korea. Chemical Geology, 451. 135-153 doi:10.1016/j.chemgeo.2017.01.011 |
| Peng (2024) Northwest. Geol. The characteristics of granite associated with tin and mineralization in northwest China 57, 27 |
| Not Yet Imported: - journal-article : 10.5194/gchron-3-123-2021
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
 | |
| Ren (2009) Aca Petrol. Sinica LA-ICP-MS U-Pb zircon dating and geochemical characteristics of diabase-dykes from the Qingshuiquan area, eastern Kunlun orogenic belt 25, 1135 |
 | Ren, Tao, Li, Huan, Algeo, Thomas J., Girei, Musa Bala, Wu, Jinghua, Liu, Biao (2024) Nature and timing of Sn mineralization in southern Hunan, South China: Constraints from LA-ICP-MS cassiterite U-Pb geochronology and trace element composition. American Mineralogist, 109 (3) 606-623 doi:10.2138/am-2022-8823 |
 | |
 | |
| Su (2023) Earth Sci. Present situation and research direction of strategic critical mineral exploration: taking Qinghai province as an example 48, 1543 |
 | Su, Hui-Min; Che, Yu-Ying; Liu, Tong; Li, Hua; Liu, Li; Jin, Tao; He, Shuyue (2024) Multiple generations of garnet and their genetic significance in the Niukutou cobalt-rich Pb-Zn-(Fe) skarn deposit, East Kunlun orogenic belt, western China. Ore Geology Reviews, 174. doi:10.1016/j.oregeorev.2024.106308 |
 | |
| Tian (2016) Acta Petrol. Mineral. The characteristics of Early Paleozoic postorogenic granite in the East Kunlun orogen: A casestudy of Dagangou granite 35, 371 |
| Tian (2022) |
 | Tian, Zhen-Dong; Leng, Cheng-Biao; Zhang, Xing-Chun; Zafar, Tehseen; Zhang, Le-Jun; Hong, Wei; Lai, Chun-Kit (2019) Chemical composition, genesis and exploration implication of garnet from the Hongshan Cu-Mo skarn deposit, SW China. Ore Geology Reviews, 112. doi:10.1016/j.oregeorev.2019.103016 |
 | |
 | |
 | |
 | Wu, Jinghua, Li, Huan, Mathur, Ryan, Bouvier, Audrey, Powell, Wayne, Yonezu, Kotaro, Zhu, Dapeng (2023) Compositional variation and Sn isotope fractionation of cassiterite during magmatic-hydrothermal processes. Earth and Planetary Science Letters, 613. 118186 doi:10.1016/j.epsl.2023.118186 |
 | Xu, Jing, Ciobanu, Cristiana L., Cook, Nigel J., Zheng, Youye, Sun, Xiang, Wade, Benjamin P. (2016) Skarn formation and trace elements in garnet and associated minerals from Zhibula copper deposit, Gangdese Belt, southern Tibet. Lithos, 262. 213-231 doi:10.1016/j.lithos.2016.07.010 |
 | |
 | |
 | Yang, Ming, Romer, Rolf L., Yang, Yue-Heng, Wu, Shi-Tou, Wang, Hao, Tu, Jia-Run, Zhou, Hong-Ying, Xie, Lie-Wen, Huang, Chao, Xu, Lei, Yang, Jin-Hui, Wu, Fu-Yuan (2022) U-Pb isotopic dating of cassiterite: Development of reference materials and in situ applications by LA-SF-ICP-MS. Chemical Geology, 593. 120754 doi:10.1016/j.chemgeo.2022.120754 |
| Yin (1998) Earth Sci. Evolution and characteristics of the Central Orogenic Belt 05, 3 |
 | Yuan, Shunda, Peng, Jiantang, Hu, Ruizhong, Li, Huimin, Shen, Nengping, Zhang, Dongliang (2008) A precise U–Pb age on cassiterite from the Xianghualing tin-polymetallic deposit (Hunan, South China) Mineralium Deposita, 43 (4) 375-382 doi:10.1007/s00126-007-0166-y |
 | |
| Zhang (2003) Geol. Bull. China Early Paleozoic tectono-thermal event of the Jinshuikou Group on the southern margin of Qaidam: Zircon U–Pb SHRIMP age evidence 6, 397 |
| Not Yet Imported: - journal-article : 10.18654/1000-0569/2021.07.04
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
| Zhang (2018) J. Jilin Univ. (Earth Sci. Ed.) Detrital zircon U–Pb geochronology and Hf isotope of phyllite of Langyashan Formation in Hongshuihe iron ore district of Eastern Kunlun and their geological significance 48, 1085 |
 | |
 | Zhang, Shitao, Chen, Huayong, Shu, Qihai, Zhang, Yu, Chu, Gaobin, Cheng, Jiamin, Tian, Jing (2019) Unveiling growth histories of multi-generational garnet in a single skarn deposit via newly-developed LA-ICP-MS U Pb dating of grandite. Gondwana Research, 73. 65-76 doi:10.1016/j.gr.2019.04.003 |
 | Zhang, Xingkai, Jiang, Shao-Yong, Su, Hui-Min, Wang, Wei, Xia, Qinglin, Liu, Yunpeng, Li, Shien (2024) New Discovery of the Jinshui Tin Deposit in the Middle Section of the East Kunlun Orogenic Belt, Northwestern China: Mineralization Age and Exploration Significance. Journal of Earth Science, 35 (4) 1373-1377 doi:10.1007/s12583-024-1999-3 |
| Zhang (2010) Geol. Bull. China LA-ICP-MS zircon U-Pb age of quartz diorite at the Kekesha area of Dulan County, eastern section of the East Kunlun orogenic belt, China and its significance 29, 79 |
 | |
 | Zhao, Panlao, Chu, Xu, Williams-Jones, Anthony E., Mao, Jingwen, Yuan, Shunda (2022) The role of phyllosilicate partial melting in segregating tungsten and tin deposits in W-Sn metallogenic provinces. Geology, 50 (1) 121-125 doi:10.1130/g49248.1 |
 | |
 | |
 | Zhu, Da-Peng, Li, Huan, Algeo, Thomas J., Jiang, Wei-Cheng, Wang, Chong (2021) The prograde-to-retrograde evolution of the Huangshaping skarn deposit (Nanling Range, South China) Mineralium Deposita, 56 (6) 1087-1110 doi:10.1007/s00126-021-01042-7 |
These are possibly similar items as determined by title/reference text matching only.