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Whiteite-(MnMnMn)

A valid IMA mineral species
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01017220016350198594872.jpg
Whiteite-(MnMnMn)

Foote Lithium Co. Mine, Cleveland County, North Carolina, USA
02997280016394015839112.jpg
Whiteite-(MnMnMn)

Chandlers Mill Quarry, Newport, Sullivan County, New Hampshire, USA
01836370016970290193849.jpg
Whiteite-(MnMnMn)

Foote Lithium Co. Mine, Cleveland County, North Carolina, USA
09621610016350198469021.jpg
Whiteite-(MnMnMn)

Foote Lithium Co. Mine, Cleveland County, North Carolina, USA
07327120016393455318830.jpg
Whiteite-(MnMnMn)

Chandlers Mill Quarry, Newport, Sullivan County, New Hampshire, USA
01978660016968828003698.jpg
Whiteite-(MnMnMn)

Foote Lithium Co. Mine, Cleveland County, North Carolina, USA
01017220016350198594872.jpg
Whiteite-(MnMnMn)

Foote Lithium Co. Mine, Cleveland County, North Carolina, USA
02997280016394015839112.jpg
Whiteite-(MnMnMn)

Chandlers Mill Quarry, Newport, Sullivan County, New Hampshire, USA
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About Whiteite-(MnMnMn)Hide

Formula:
Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O
Colour:
colourless to very pale brown
Lustre:
Vitreous
Specific Gravity:
2.82 (Calculated)
Crystal System:
Monoclinic
Name:
Named for the chemical composition, in accordance with whiteite-group nomenclature. The suffix indicates sequentially the dominant atom in the X, M1, and M2 structural positions. The root name is for John Sampson White, Jr., associate curator of minerals, Smithsonian institution; founder, editor and publisher (1970-1982) of the Mineralogical Record.
The fully manganian whiteite.


Unique IdentifiersHide

Mindat ID:
55599
Long-form identifier:
mindat:1:1:55599:5
GUID
(UUID V4):
d1e3b886-1578-4d0b-804e-fd59575780e0

IMA Classification of Whiteite-(MnMnMn)Hide

IMA status:
Approved
Approval history:
IMA No. 2021-049

Classification of Whiteite-(MnMnMn)Hide

Strunz-mindat (2023):
8.DH.

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
Wt-MnMnMnIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Pronunciation of Whiteite-(MnMnMn)Hide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of Whiteite-(MnMnMn)Hide

Lustre:
Vitreous
Colour:
colourless to very pale brown
Streak:
white
Cleavage:
Poor/Indistinct
poor cleavage on {001}
Density:
2.82 g/cm3 (Calculated)

Optical Data of Whiteite-(MnMnMn)Hide

Type:
Biaxial (-)
RI values:
nα = 1.599(2) nβ = 1.605(2) nγ = 1.609(2)
2V:
Calculated: 78.2°
Max Birefringence:
δ = 0.010
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Pleochroism:
Non-pleochroic

Chemistry of Whiteite-(MnMnMn)Hide

Mindat Formula:
Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O
Elements listed:
Al, H, Mn, O, P - search for minerals with similar chemistry

Crystallography of Whiteite-(MnMnMn)Hide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P2/b
Setting:
P2/a
Cell Parameters:
a = 15.024(3) Å, b = 6.947(1) Å, c = 9.999(2) Å
β = 110.71(3)°
Ratio:
a:b:c = 2.163 : 1 : 1.439
Unit Cell V:
976.18 ų (Calculated from Unit Cell)
Z:
2

Epitaxial Relationships of Whiteite-(MnMnMn)Hide

Epitaxial Minerals:
Whiteite-(CaMnMn){Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2O

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.40 Å(49)
4.92 Å(66)
4.70 Å(37)
3.513 Å(42)
2.801 Å(100)
1.950 Å(26)
1.884 Å(26)
1.568 Å(28)

Type Occurrence of Whiteite-(MnMnMn)Hide

Type Locality:
ⓘ Foote Lithium Co. Mine, Cleveland County, North Carolina, USA
General Appearance of Type Material:
sugary aggregates of blade-like crystals up to 0.1 mm long
Place of Conservation of Type Material:
mineralogical collections of the Natural History Museum of Los Angeles County, Los Angeles, CA 90007, USA, catalogue nos. 74374, 76149, 76150, and 76151 (cotypes)
Geological Setting of Type Material:
partially oxidized pegmatite minerals
Associated Minerals at Type Locality:
EosphoriteHureauliteFairfielditeMangangordoniteWhiteite-(CaMnMn)
Jasonsmithite

Synonyms of Whiteite-(MnMnMn)Hide

Relationship of Whiteite-(MnMnMn) to other SpeciesHide

Member of:
Whiteite Subgroup > Jahnsite Group
Other Members of this group:
Rittmannite{(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Whiteite-(CaFeMg){Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
Whiteite-(CaMgMg)CaMg3Al2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Whiteite-(CaMnFe)CaMnFe2Al2(PO4)4(OH)2 · 8H2OMon. 2/m
Whiteite-(CaMnMg){Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m
Whiteite-(CaMnMn){Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Whiteite-(MnFeMg){(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
Whiteite-(MnMnMg)MnMnMg2Al2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b

Related Minerals - Strunz-mindat GroupingHide

8.DH.FerroberauniteFe2+Fe3+5(PO4)4(OH)5 · 6H2OMon. 2/m : B2/b
8.DH.Rowleyite[Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl]Iso.
8.DH.Ammoniotinsleyite(NH4)Al2(PO4)2(OH) · 2H2OMon. 2/m : P21/m
8.DH.Thebaite-(NH4)(NH4)3Al(C2O4)(PO3OH)2(H2O)Mon. 2/m : P21/b
8.DH.Dendoraite-(NH4)(NH4)2NaAl(C2O4)(PO3OH)2(H2O)2Mon. 2/m
8.DH.Whiteite-(CaMnFe)CaMnFe2Al2(PO4)4(OH)2 · 8H2OMon. 2/m
8.DH.HochleitneriteMn2Ti3(PO4)4O2(H2O)2 · 14H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.RegeriteKFe6(PO4)4(OH)7(H2O)6 · 4H2OMon. 2/m : P21/b
8.DH.05MinyuliteKAl2(PO4)2F · 4H2OOrth. mm2 : Pba2
8.DH.10LeucophosphiteKFe3+2(PO4)2(OH) · 2H2OMon. 2/m : P21/b
8.DH.10Spheniscidite(NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2OMon. 2/m
8.DH.10TinsleyiteKAl2(PO4)2(OH) · 2H2OMon.
8.DH.15Jahnsite-(CaMnFe){Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMnMg){Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMnMn){Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15KeckiteCaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2OMon. 2/m : P2/b
8.DH.15Rittmannite{(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Whiteite-(CaFeMg){Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
8.DH.15Whiteite-(CaMnMg){Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m
8.DH.15Whiteite-(MnFeMg){(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
8.DH.15Jahnsite-(MnMnMn){Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
8.DH.15Kaluginite(Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2OOrth.
8.DH.15Jahnsite-(CaFeFe){Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon.
8.DH.15Jahnsite-(NaFeMg)NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(NaMnMg){(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMgMg){Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O
8.DH.15Whiteite-(CaMnMn){Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Whiteite-(MnMnMg)MnMnMg2Al2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(MnMnMg)Mn2+Mn2+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaFeMg)CaFe2+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(MnMnFe)Mn2+Mn2+Fe2+2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Whiteite-(CaMgMg)CaMg3Al2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(MnMnZn)Mn2+Mn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(NaMnMn)NaMn2+(Mn2+Fe3+)Σ2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMnZn)CaMn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.20Lun'okite(Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20Manganosegelerite(Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20OveriteCaMgAl(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20SegeleriteCa2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2OOrth. mmm (2/m 2/m 2/m) : Pcca
8.DH.20WilhelmvierlingiteCaMnFe3+(PO4)2(OH) · 2H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20JuonniiteCaMgSc(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.25CalcioferriteCa2Fe3+2(PO4)3(OH) · 7H2OMon. 2/m : B2/b
8.DH.25KingsmountiteCa3MnFeAl4(PO4)6(OH)4 · 12H2OTric. 1 : P1
8.DH.25MontgomeryiteCa4MgAl4(PO4)6(OH)4 · 12H2OMon. 2 : B2
8.DH.25ZodaciteCa4Mn2+Fe3+4(PO4)6(OH)4 · 12H2OMon.
8.DH.25FanfaniiteCa4MnAl4(PO4)6(OH)4 · 12H2OMon. 2/m : B2/b
8.DH.30ArseniosideriteCa2Fe3+3(AsO4)3O2 · 3H2OMon. 2/m : B2/b
8.DH.30KolfaniteCa2Fe3+3O2(AsO4)3 · 2H2OMon.
8.DH.30MitridatiteCa2Fe3+3(PO4)3O2 · 3H2OMon. 2/m : B2/b
8.DH.30PararobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. 2/m : P21/b
8.DH.30RobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. m : Bb
8.DH.30Sailaufite(Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2OMon. m : Bm
8.DH.35MantienneiteKMg2Al2Ti(PO4)4(OH)3 · 15H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.35PaulkerriteK(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2OMon. m
8.DH.35Benyacarite(H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.40XanthoxeniteCa4Fe3+2(PO4)4(OH)2 · 3H2OTric. 1 : P1
8.DH.45MahnertiteNaCu3(AsO4)2Cl · 5H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mmm
8.DH.50AndyrobertsiteKCdCu5(AsO4)4(H2AsO4) · 2H2OMon. 2/m : P21/m
8.DH.50CalcioandyrobertsiteKCaCu5(AsO4)4(H2AsO4) · 2H2OMon. 2/m : P21/m
8.DH.55EnglishiteK3Na2Ca10Al15(PO4)21(OH)7 · 26H2OMon. 2/m
8.DH.60BouazzeriteBi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2OMon. 2/m
8.DH.65GalliskiiteCa4Al2(PO4)2F8 · 5H2OTric. 1 : P1
8.DH.70JoteiteCa2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2OTric. 1 : P1
8.DH.75KampeliteBa6Mg3Sc8(PO4)12(OH)6 · 7H2OOrth. mmm (2/m 2/m 2/m) : Pnma
8.DH.80KapundaiteNaCaFe4(PO4)4(OH)3 · 5H2OTric. 1 : P1
8.DH.85VaniniiteCa2Mn2+3Mn3+2O2(AsO4)4 · 2H2OMon. 2/m : P21/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Whiteite-(MnMnMn)Hide

References for Whiteite-(MnMnMn)Hide

Reference List:
Grey, I.E., Smith, J.B., Kampf, A.R., Mumme, W.G., Macrae, C.M., Riboldi-Tunnicliffe, A., Boer, S., Glenn, A.M. (2021): Whiteite-(MnMnMn), IMA 2021-049. CNMNC Newsletter 63; Mineralogical Magazine: 85, https://doi.org.10.1180/mgm.2021.74
Grey, Ian E., Smith, Jason B., Kampf, Anthony R., Mumme, W. Gus, MacRae, Colin M., Riboldi-Tunnicliffe, Alan, Boer, Stephanie, Glenn, Alexander M., Gable, Robert W. (2021) Whiteite-(MnMnMn), a new jahnsite-group mineral species from the Foote mine, North Carolina, USA, and chemical pressure effects in jahnsite-group minerals. Mineralogical Magazine, 85 (6) 862-867 doi:10.1180/mgm.2021.75

Localities for Whiteite-(MnMnMn)Hide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA
 
  • New Hampshire
    • Sullivan County
      • Newport
Van King
  • North Carolina
    • Cleveland County
Mineralogical Magazine: 85, https://doi.org.10.1180/mgm.2021.74
Grey, I.E., Smith, J.B., Kampf, A.R., Mumme, W.G., Macrae, C.M., Riboldi-Tunnicliffe, A., Boer, S., Glenn, A.M. (2021): Whiteite-(MnMnMn), IMA 2021-049. CNMNC Newsletter 63
Quick NavTopAbout Whiteite-(MnMnMn)Unique IdentifiersIMA Classification Classification Mineral SymbolsPronunciation Physical Properties Optical Data Chemistry Crystallography Epitaxial Relationships X-Ray Powder DiffractionType Occurrence SynonymsRelationshipsStrunz-MindatOther InformationInternet Links References Localities Locality List
 
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