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Whiteite-(MnFeMg)

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About Whiteite-(MnFeMg)Hide

03160110014946339009843.jpg
John S. White
Formula:
{(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O
Colour:
Brown
Hardness:
4
Crystal System:
Monoclinic
Name:
Named after John Sampson White, Jr., associate curator of minerals, Smithsonian institution; founder, editor and publisher (1970-1982) of the Mineralogical Record.

Classification of Whiteite-(MnFeMg)Hide

Approved
Approval Year:
1978
8.DH.15

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
42.11.3.2

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
19.12.62

19 : Phosphates
12 : Phosphates of Mn

Physical Properties of Whiteite-(MnFeMg)Hide

Transparency:
Translucent
Colour:
Brown
Hardness:

Optical Data of Whiteite-(MnFeMg)Hide

Type:
Biaxial (+)
RI values:
nα = 1.580 nβ = 1.584 - 1.585 nγ = 1.590 - 1.591
Max Birefringence:
δ = 0.010 - 0.011
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
none

Chemical Properties of Whiteite-(MnFeMg)Hide

Formula:
{(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O
IMA Formula:
Mn2+Fe2+Mg2Al2(PO4)4(OH)2 · 8H2O

Crystallography of Whiteite-(MnFeMg)Hide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/a
Cell Parameters:
a = 14.99(2) Å, b = 6.96(1) Å, c = 10.14(1) Å
β = 113.19(6)°
Ratio:
a:b:c = 2.154 : 1 : 1.457
Unit Cell V:
972.44 ų (Calculated from Unit Cell)
Z:
2
Twinning:
Commonly twinned by reflection on {001}, giving a pseudo-orthorhombic outline.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.318 Å(100)
4.824 Å(50)
4.644 Å(40)
3.518 Å(35)
3.245 Å(35)
2.948 Å(45)
2.776 Å(90)

Type Occurrence of Whiteite-(MnFeMg)Hide

Synonyms of Whiteite-(MnFeMg)Hide

Other Language Names for Whiteite-(MnFeMg)Hide

Relationship of Whiteite-(MnFeMg) to other SpeciesHide

Other Members of this group:
Rittmannite{(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2OMon.
Whiteite-(CaFeMg){Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
Whiteite-(CaMgMg)CaMg3Al2(PO4)4(OH)2·8H2OMon. 2/m : P2/b
Whiteite-(CaMnMg){Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m
Whiteite-(CaMnMn){Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
Whiteite-(MnMnMg)MnMnMg2Al2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b

Common AssociatesHide

Associated Minerals Based on Photo Data:
2 photos of Whiteite-(MnFeMg) associated with Hureaulite(Mn,Fe)5(PO4)2(HPO4)2 · 4H2O
1 photo of Whiteite-(MnFeMg) associated with PyriteFeS2

Related Minerals - Nickel-Strunz GroupingHide

8.DH.05MinyuliteKAl2(PO4)2(OH,F) · 4H2OOrth. mm2 : Pba2
8.DH.10LeucophosphiteKFe3+2(PO4)2(OH) · 2H2OMon. 2/m : P21/b
8.DH.10Spheniscidite(NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2OMon.
8.DH.10TinsleyiteKAl2(PO4)2(OH) · 2H2OMon.
8.DH.15Jahnsite-(CaMnFe){Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMnMg){Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMnMn){Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15KeckiteCaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2OMon. 2/m : P2/b
8.DH.15Rittmannite{(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2OMon.
8.DH.15Whiteite-(CaFeMg){Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
8.DH.15Whiteite-(CaMnMg){Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m
8.DH.15Jahnsite-(MnMnMn){Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon.
8.DH.15Kaluginite(Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2OOrth.
8.DH.15Jahnsite-(CaFeFe){Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon.
8.DH.15Jahnsite-(NaFeMg)NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(NaMnMg){(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMgMg){Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O
8.DH.20Manganosegelerite(Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20OveriteCaMgAl(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20SegeleriteCa2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2OOrth. mmm (2/m 2/m 2/m) : Pcca
8.DH.20WilhelmvierlingiteCaMnFe3+(PO4)2(OH) · 2H2OOrth.
8.DH.20JuonniiteCaMgSc(PO4)2(OH) · 4H2OOrth.
8.DH.25CalcioferriteCa2Fe3+2(PO4)3(OH) · 7H2OMon. 2/m : B2/b
8.DH.25KingsmountiteCa3MnFeAl4(PO4)6(OH)4·12H2OMon. 2 : B2
8.DH.25MontgomeryiteCa4MgAl4(PO4)6(OH)4 · 12H2OMon. 2 : B2
8.DH.25ZodaciteCa4Mn2+Fe3+4(PO4)6(OH)4 · 12H2OMon.
8.DH.30ArseniosideriteCa2Fe3+3(AsO4)3O2 · 3H2OMon. 2/m : B2/b
8.DH.30KolfaniteCa2Fe3+3O2(AsO4)3 · 2H2OMon.
8.DH.30MitridatiteCa2Fe3+3(PO4)3O2 · 3H2OMon. 2/m : B2/b
8.DH.30PararobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. 2/m : P21/b
8.DH.30RobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. m : Bb
8.DH.30Sailaufite(Ca,Na,☐)2Mn3+3(AsO4)2(CO3)O2 · 3H2OMon.
8.DH.35MantienneiteKMg2Al2Ti(PO4)4(OH)3 · 15H2OOrth.
8.DH.35PaulkerriteK(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.35Benyacarite(H2O,K)2(Mn2+,Fe2+)2(Fe3+,Ti)2Ti(PO4)4(O,F)2 · 14H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.40XanthoxeniteCa4Fe3+2(PO4)4(OH)2 · 3H2OTric. 1 : P1
8.DH.45MahnertiteNaCu3(AsO4)2Cl · 5H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mmm
8.DH.50AndyrobertsiteKCdCu5(AsO4)4(H2AsO4) · 2H2OMon.
8.DH.50CalcioandyrobertsiteKCaCu5(AsO4)4(H2AsO4) · 2H2OMon. 2/m : P21/m
8.DH.55EnglishiteK3Na2Ca10Al15(PO4)21(OH)7 · 26H2OMon. 2/m
8.DH.60BouazzeriteBi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2OMon. 2/m

Related Minerals - Dana Grouping (8th Ed.)Hide

42.11.3.1Whiteite-(CaFeMg){Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
42.11.3.3Whiteite-(CaMnMg){Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m
42.11.3.4Rittmannite{(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2OMon.

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

19.12.1MetaswitzeriteMn2+3(PO4)2 · 4H2OMon. 2/m : P2/b
19.12.2BermaniteMn2+Mn3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P2/b
19.12.3NatrophiliteNaMn2+PO4Orth. mmm (2/m 2/m 2/m) : Pmna
19.12.4SidorenkiteNa3Mn2+(CO3)(PO4)Mon.
19.12.5Niahite(NH4)(Mn2+,Mg)(PO4) · H2OOrth. mm2 : Pmn21
19.12.6RobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. m : Bb
19.12.7PararobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. 2/m : P21/b
19.12.8SinkankasiteMn2+Al(PO3OH)2(OH) · 6H2OTric.
19.12.9MangangordoniteMn2+Al2(PO4)2(OH)2 · 8H2OTric.
19.12.10Heterosite(Fe3+,Mn3+)PO4Orth. mmm (2/m 2/m 2/m) : Pmna
19.12.11PurpuriteMn3+(PO4)Orth. mmm (2/m 2/m 2/m) : Pmna
19.12.12Wolfeite(Fe2+,Mn2+)2(PO4)(OH)Mon. 2/m : P21/b
19.12.13Triploidite(Mn2+,Fe2+)2(PO4)(OH)Mon. 2/m : P2/b
19.12.14LipscombiteFe2+Fe3+2(PO4)2(OH)2Tet.
19.12.15FrondeliteMn2+Fe3+4(PO4)3(OH)5Orth. 2 2 2 : C2 2 21
19.12.16RockbridgeiteFe2+Fe3+4(PO4)3(OH)5Orth. mmm (2/m 2/m 2/m)
19.12.17Kryzhanovskite(Fe3+,Mn2+)3(PO4)2(OH,H2O)3Orth.
19.12.18LandesiteMn2+3-xFe3+x(PO4)2(OH)x · (3-x)H2OOrth.
19.12.19Phosphoferrite(Fe2+,Mn2+)3(PO4)2 · 3H2OOrth. mmm (2/m 2/m 2/m) : Pmna
19.12.20Reddingite(Mn2+,Fe2+)3(PO4)2 · 3H2OOrth. mmm (2/m 2/m 2/m) : Pmna
19.12.21EarlshannoniteMn2+Fe3+2(PO4)2(OH)2 · 4H2OMon.
19.12.22Hureaulite(Mn,Fe)5(PO4)2(HPO4)2 · 4H2OMon. 2/m : B2/b
19.12.23SwitzeriteMn2+3(PO4)2 · 7H2OMon.
19.12.24LaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
19.12.25PseudolaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OMon. 2/m : P21/b
19.12.26StrunziteMn2+Fe3+2(PO4)2(OH)2 · 6H2OTric. 1 : P1
19.12.27StewartiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
19.12.28Alluaudite(Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3Mon.
19.12.29Ferroalluaudite(Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3Mon. 2/m : B2/b
19.12.30Fillowite{Mn2+}{Na8}{Ca4Na4}{(Mn2+,Fe2+)43}(PO4)36Trig. 3 : R3
19.12.31JohnsomervilleiteNa10Ca6Mg18Fe25(PO4)36Trig.
19.12.32WicksiteNaCa2(Fe2+,Mn2+)4MgFe3+(PO4)6 · 2H2OOrth. mmm (2/m 2/m 2/m)
19.12.33Dickinsonite-(KMnNa){KNa}{Mn2+◻}{Ca}{Na3}{Mn2+13}{Al}(PO4)12(OH)2Mon. 2/m : B2/b
19.12.34Sarcopside(Fe2+,Mn2+,Mg)3(PO4)2Mon. 2/m : P21/b
19.12.35LudlamiteFe2+3(PO4)2 · 4H2OMon. 2/m : P21/b
19.12.36GraftoniteFe2+Fe2+2(PO4)2Mon. 2/m : P21/b
19.12.37WilhelmvierlingiteCaMnFe3+(PO4)2(OH) · 2H2OOrth.
19.12.38FairfielditeCa2Mn2+(PO4)2 · 2H2OTric. 1 : P1
19.12.39BeusiteMn2+Mn2+2 (PO4)2Mon.
19.12.40MesseliteCa2Fe2+(PO4)2 · 2H2OTric. 1 : P1
19.12.41Jahnsite-(CaMnFe){Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
19.12.42Jahnsite-(CaMnMn){Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
19.12.43Jahnsite-(CaMnMg){Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
19.12.44KeckiteCaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2OMon. 2/m : P2/b
19.12.45StanfielditeCa4Mg5(PO4)6Mon.
19.12.46Laubmannite(Fe2+,Mn2+,Ca)3Fe3+6(PO4)4(OH)12
19.12.47ZodaciteCa4Mn2+Fe3+4(PO4)6(OH)4 · 12H2OMon.
19.12.48HagendorfiteNaCaMn2+Fe2+2(PO4)3Mon. 2/m : B2/b
19.12.49Maghagendorfite(□,Na,)(Na,Ca,Fe2+)Mn(Mg,Fe2+,Fe3+)3(PO4)3Mon.
19.12.50VaruliteNaCaMn2+Mn2+2(PO4)3Mon. 2/m : B2/b
19.12.51GriphiteNa4Li2Ca6(Mn2+,Fe2+,Mg)19Al8(PO4)24(F,OH)8Iso. m3 (2/m 3) : Pa3
19.12.52Attakolite(Ca,Sr)Mn(Al,Fe)4(HPO4,PO4)3(SiO4,PO4)(OH)4Mon. 2/m : B2/m
19.12.53Arrojadite-(KFe){KNa}{Fe2+◻}{Ca}{Na2◻}{Fe2+13}{Al}(PO4)11(HPO4)(OH)2Mon.
19.12.54Lun'okite(Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
19.12.55EosphoriteMn2+Al(PO4)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m) : Cmca
19.12.56Ernstite(Mn2+,Fe3+)Al(PO4)(OH,O)2 · H2OMon.
19.12.57ChildreniteFe2+Al(PO4)(OH)2 · H2OOrth. mm2 : Ccc2
19.12.58BobfergusoniteNa2Mn5FeAl(PO4)6Mon. 2/m : P2/b
19.12.59QingheiiteNaMn3+Mg(Al,Fe3+)(PO4)3Mon. 2/m : P21/b
19.12.60Whiteite-(CaFeMg){Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
19.12.61Whiteite-(CaMnMg){Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m
19.12.63Rittmannite{(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2OMon.
19.12.64ZanazziiteCa2Mg5Be4(PO4)6(OH)4 · 6H2OMon. 2/m : B2/b
19.12.65Samuelsonite(Ca,Ba)Ca8Fe2+2Mn2+2Al2(PO4)10(OH)2Mon. 2/m : B2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Whiteite-(MnFeMg)Hide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Moore, Paul B. & J. Ito (1978), I. Whiteite, a new species, and a proposed nomenclature for the jahnsite-whiteite complex series. II. New data on xanthoxenite. III. Salmonsite discredited: Mineralogical Magazine: 42: 309-323.
American Mineralogist (1979): 64: 465-466.
Canadian Mineralogist (1989): 27: 699.

Internet Links for Whiteite-(MnFeMg)Hide

Localities for Whiteite-(MnFeMg)Hide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Brazil
 
  • Minas Gerais
    • Conselheiro Pena
Sergio Varvello collection
    • Galiléia
      • Sapucaia do Norte
Sergio Varvello collection
    • Itinga
      • Taquaral
Mineralogical Magazine 1978 42 : 309-323.
USA
 
  • New Hampshire
    • Grafton Co.
      • Groton
Whitmore & Lawrence, 2004. The Pegmatite Mines Known As Palermo, p.95.; NIZAMOFF, James W., SIMMONS, William B., and FALSTER, Alexander U. (2004) PHOSPHATE MINERALOGY AND PARAGENESIS OF THE PALERMO #2 PEGMATITE, NORTH GROTON, NEW HAMPSHIRE Geological Society of America Abstracts with Programs, Vol. 36, No. 5, p. 115
Journal of Pegmatology vol. 1, no. 1 ; Geological Society of America Abstracts with Programs, Vol. 36, No. 5, p. 115; NIZAMOFF, J. W. (2004, November). Phosphate mineralogy and paragenesis of the Palermo# 2 pegmatite, North Groton, New Hampshire. In 2004 Denver Annual Meeting.
  • North Carolina
    • Cleveland Co.
      • Kings Mountain Mining District
Rocks & Min.:60:65 & 76-83.
 
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