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Mantienneite

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About MantienneiteHide

00262650014948356163200.jpg
Joseph Mantienne
Formula:
KMg2Al2Ti(PO4)4(OH)3 · 15H2O
Colour:
Caramel brown to brownish honey brown
Lustre:
Vitreous
Hardness:
3
Crystal System:
Orthorhombic
Name:
Named in honour of the French mineralogist Dr. Joseph Mantienne (b. 1929), Bureau de Recherches Géologiques et Miniéres (BRGM), Orléans, France.
A vacancy-dominant end-member (possible new mineral) is discussed by Sejkora et al. (2006), based on analytical data of Fransolet et al. (1984).

Compare also benyacarite and paulkerrite.


Classification of MantienneiteHide

Approved
8.DH.35

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
42.11.21.2

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
19.8.23

19 : Phosphates
8 : Phosphates of Al and other metals

Physical Properties of MantienneiteHide

Vitreous
Colour:
Caramel brown to brownish honey brown
Hardness:
Cleavage:
Perfect
{001}

Optical Data of MantienneiteHide

Type:
Biaxial (-)
RI values:
nα = 1.564 nγ = 1.598
2V:
Measured: 50° to 60°
Max Birefringence:
δ = 0.034
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r > v strong

Chemical Properties of MantienneiteHide

Formula:
KMg2Al2Ti(PO4)4(OH)3 · 15H2O

Crystallography of MantienneiteHide

Crystal System:
Orthorhombic
Cell Parameters:
a = 10.4 Å, b = 20.33 Å, c = 12.31 Å
Ratio:
a:b:c = 0.512 : 1 : 0.606
Unit Cell V:
2,602.73 ų (Calculated from Unit Cell)

Type Occurrence of MantienneiteHide

General Appearance of Type Material:
Radial fibrous spherules to 1 mm
Place of Conservation of Type Material:
National School of Mines, Paris, France
Geological Setting of Type Material:
Forming the matrix of sandy layers in lacustric shales
Associated Minerals at Type Locality:

Synonyms of MantienneiteHide

Other Language Names for MantienneiteHide

Related Minerals - Nickel-Strunz GroupingHide

8.DH.05MinyuliteKAl2(PO4)2(OH,F) · 4H2OOrth. mm2 : Pba2
8.DH.10LeucophosphiteKFe3+2(PO4)2(OH) · 2H2OMon. 2/m : P21/b
8.DH.10Spheniscidite(NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2OMon.
8.DH.10TinsleyiteKAl2(PO4)2(OH) · 2H2OMon.
8.DH.15Jahnsite-(CaMnFe){Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMnMg){Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMnMn){Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15KeckiteCaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2OMon. 2/m : P2/b
8.DH.15Rittmannite{(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2OMon.
8.DH.15Whiteite-(CaFeMg){Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
8.DH.15Whiteite-(CaMnMg){Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m
8.DH.15Whiteite-(MnFeMg){(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2OMon. 2/m : P21/b
8.DH.15Jahnsite-(MnMnMn){Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon.
8.DH.15Kaluginite(Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2OOrth.
8.DH.15Jahnsite-(CaFeFe){Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon.
8.DH.15Jahnsite-(NaFeMg)NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(NaMnMg){(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2OMon. 2/m : P2/b
8.DH.15Jahnsite-(CaMgMg){Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O
8.DH.20Manganosegelerite(Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20OveriteCaMgAl(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.20SegeleriteCa2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2OOrth. mmm (2/m 2/m 2/m) : Pcca
8.DH.20WilhelmvierlingiteCaMnFe3+(PO4)2(OH) · 2H2OOrth.
8.DH.20JuonniiteCaMgSc(PO4)2(OH) · 4H2OOrth.
8.DH.25CalcioferriteCa2Fe3+2(PO4)3(OH) · 7H2OMon. 2/m : B2/b
8.DH.25KingsmountiteCa3MnFeAl4(PO4)6(OH)4 · 12H2OTric. 1 : P1
8.DH.25MontgomeryiteCa4MgAl4(PO4)6(OH)4 · 12H2OMon. 2 : B2
8.DH.25ZodaciteCa4Mn2+Fe3+4(PO4)6(OH)4 · 12H2OMon.
8.DH.30ArseniosideriteCa2Fe3+3(AsO4)3O2 · 3H2OMon. 2/m : B2/b
8.DH.30KolfaniteCa2Fe3+3O2(AsO4)3 · 2H2OMon.
8.DH.30MitridatiteCa2Fe3+3(PO4)3O2 · 3H2OMon. 2/m : B2/b
8.DH.30PararobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. 2/m : P21/b
8.DH.30RobertsiteCa2Mn3+3(PO4)3O2 · 3H2OMon. m : Bb
8.DH.30Sailaufite(Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2OMon.
8.DH.35PaulkerriteK(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.35Benyacarite(H2O,K)2(Mn2+,Fe2+)2(Fe3+,Ti)2Ti(PO4)4(O,F)2 · 14H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DH.40XanthoxeniteCa4Fe3+2(PO4)4(OH)2 · 3H2OTric. 1 : P1
8.DH.45MahnertiteNaCu3(AsO4)2Cl · 5H2OTet. 4/mmm (4/m 2/m 2/m) : I4/mmm
8.DH.50AndyrobertsiteKCdCu5(AsO4)4(H2AsO4) · 2H2OMon.
8.DH.50CalcioandyrobertsiteKCaCu5(AsO4)4(H2AsO4) · 2H2OMon. 2/m : P21/m
8.DH.55EnglishiteK3Na2Ca10Al15(PO4)21(OH)7 · 26H2OMon. 2/m
8.DH.60BouazzeriteBi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2OMon. 2/m

Related Minerals - Dana Grouping (8th Ed.)Hide

42.11.21.1PaulkerriteK(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2OOrth. mmm (2/m 2/m 2/m) : Pbca
42.11.21.4Benyacarite(H2O,K)2(Mn2+,Fe2+)2(Fe3+,Ti)2Ti(PO4)4(O,F)2 · 14H2OOrth. mmm (2/m 2/m 2/m) : Pbca

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

19.8.1MontebrasiteLiAl(PO4)(OH)Tric. 1 : P1
19.8.2BrazilianiteNaAl3(PO4)2(OH)4Mon. 2/m : P2/b
19.8.3WarditeNaAl3(PO4)2(OH)4 · 2H2OTet. 4 2 2 : P41 21 2
19.8.4TancoiteLiNa2Al(PO4)(PO3OH)(OH)Orth. mmm (2/m 2/m 2/m) : Pbca
19.8.5Bertossaite(Li,Na)2(Ca,Fe2+,Mn2+)Al4(PO4)4(OH,F)4Orth.
19.8.6TinsleyiteKAl2(PO4)2(OH) · 2H2OMon.
19.8.7Taranakite(K,NH4)Al3(PO4)3(OH) · 9H2OTrig. 3m (3 2/m) : R3c
19.8.8FrancoanelliteK3Al5(PO3OH)6(PO4)2 · 12H2OTrig.
19.8.9GordoniteMgAl2(PO4)2(OH)2 · 8H2OTric. 1 : P1
19.8.10AldermaniteMg5Al12(PO4)8(OH)22 · 32H2OOrth.
19.8.11OveriteCaMgAl(PO4)2(OH) · 4H2OOrth. mmm (2/m 2/m 2/m) : Pbca
19.8.12MontgomeryiteCa4MgAl4(PO4)6(OH)4 · 12H2OMon. 2 : B2
19.8.14FoggiteCaAl(PO4)(OH)2 · H2OOrth. mmm (2/m 2/m 2/m)
19.8.15GatumbaiteCaAl2(PO4)2(OH)2 · H2OMon. 2/m : P2/m
19.8.16CrandalliteCaAl3(PO4)(PO3OH)(OH)6Trig. 3m (3 2/m) : R3m
19.8.17Matulaite(Fe3+,Al)Al7(PO4)4(PO3OH)2(OH)8(H2O)8 · 8H2OMon.
19.8.19LehiiteCaAl3(PO4)(PO3OH)(OH)6
19.8.20Millisite(Na,K)CaAl6(PO4)4(OH)9 · 3H2OTet.
19.8.21EnglishiteK3Na2Ca10Al15(PO4)21(OH)7 · 26H2OMon. 2/m
19.8.22KleemaniteZnAl2(PO4)2(OH)2 · 3H2OMon.
19.8.24PaulkerriteK(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2OOrth. mmm (2/m 2/m 2/m) : Pbca

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for MantienneiteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Fransolet, A.-M., Oustriere, P., Fontan, F. & Pillard, F. (1984): La mantiennéite, une nouvelle espèce minérale du gisement de vivianite d'Anloua, Cameroun. Bulletin de la Société française de Minéralogie et de Cristallographie 107: 737-744
American Mineralogist (1985): 70: 1330.
Canadian Mineralogist (1997): 35: 707-712.
Sejkora, J., Škoda, R., Ondruš, P., Beran, P. & Susser, C. (2006): Mineralogy of phosphate accumulations in the Huber stock, Krásno ore district, Slavkovský les area, Czech Republic. Journal of the Czech Geological Society 51, 103-147.

Internet Links for MantienneiteHide

Localities for MantienneiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Cameroon (TL)
 
  • Adamawa Region
    • Vina
      • Martap
FRANSOLET, A.-M., OUSTRIERE, P., FONTAN, F. & PILLARD, F. (1984) La mantiennéite, une nouvelle espèce minérale du gisement de vivianite d'Anloua, Cameroun. Bulletin de Minéralogie 107, 737-744.
Germany
 
  • Bavaria
    • Upper Palatinate
      • Neustadt an der Waldnaab District
        • Waidhaus
Wittern: "Mineralfundorte in Deutschland", 2001; Dill, H. G., Weber, B., Gerdes, A., & Melcher, F. (2008). The Fe-Mn phosphate apliteSilbergrube'near Waidhaus, Germany: epithermal phosphate mineralization in the Hagendorf-Pleystein pegmatite province. Mineralogical Magazine, 72(5), 1119-1144.
Slovakia
 
  • Banská Bystrica Region
    • Lučenec District
      • Pinciná
Vavrová J., Biroň A., Galko I. 2006: Mantienneite - a new phosphate mineral from alginite deposit (Pinciná, Slovakia). Mineralogia Polonica, vol. 28, 232-234
 
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