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Stibiogoldfieldite

A valid IMA mineral species
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About StibiogoldfielditeHide

Formula:
(Cu4Cu2)(Cu4Cu+2)(Sb2Te2)S12S
Colour:
Dark gray
Lustre:
Metallic
Hardness:
3½ - 4
Specific Gravity:
5.055 (Calculated)
Crystal System:
Isometric
Name:
Named for antimony (Latin: stibium) and its relation to goldfieldite.
Related to goldfieldite by the substitution of 2Sb3+ for 2Te4+, compensated by the filling of the M2-site vacancies with 2Cu+. Chemically somewhat similar to benleonardite.

An Ag-Bi-(S,Se) phase is an additional associate, at both holo- and cotype localities.


Unique IdentifiersHide

Mindat ID:
55444
Long-form identifier:
mindat:1:1:55444:6
GUID
(UUID V4):
c069bcd0-af60-4903-b512-bd081f6e1c24

IMA Classification of StibiogoldfielditeHide

Approved
IMA Formula:
Cu6Cu6(Sb2Te2)S13
First published:
2022

Classification of StibiogoldfielditeHide

2.GB.

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
SbgfIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of StibiogoldfielditeHide

Metallic
Transparency:
Opaque
Colour:
Dark gray
Streak:
Gray
Hardness:
3½ - 4 on Mohs scale
Hardness Data:
Estimated
Comment:
Estimated by analogy to other tetrahedrite group members.
Tenacity:
Brittle
Cleavage:
Poor/Indistinct
Fracture:
Conchoidal
Density:
5.055 g/cm3 (Calculated)

Optical Data of StibiogoldfielditeHide

Reflectivity:
WavelengthR
400nm31.6%
420nm31.6%
440nm31.6%
460nm31.3%
470nm31.1%
480nm31.1%
500nm31.1%
520nm31.0%
540nm30.9%
546nm30.9%
560nm30.9%
580nm30.9%
589nm30.8%
600nm30.9%
620nm30.9%
640nm31.0%
650nm31.0%
660nm31.0%
680nm31.0%
700nm31.0%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 31.6%.
Colour in reflected light:
Grey (with indistinct brownish hue)
Internal Reflections:
None

Chemistry of StibiogoldfielditeHide

Mindat Formula:
(Cu4Cu2)(Cu4Cu+2)(Sb2Te2)S12S

Chemical AnalysisHide

Empirical formulas:
Sample IDEmpirical Formula
1(Cu11.30Ag0.03)Σ11.33(Sb0.80As0.57Bi0.06Te2.57)Σ4.00(S12.83Se0.20)Σ13.03

Crystallography of StibiogoldfielditeHide

Crystal System:
Isometric
Class (H-M):
4 3m - Hextetrahedral
Space Group:
I4 3m
Setting:
I4 3m
Cell Parameters:
a = 10.3466(17) Å
Unit Cell V:
1,107.63 ų (Calculated from Unit Cell)
Comment:
Cell parameters for holotype material.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.644 Å(19)
2.974 Å(100)
2.754 Å(8)
2.576 Å(19)
2.429 Å(7)
2.020 Å(10)
1.821 Å(32)
1.553 Å(13)

Type Occurrence of StibiogoldfielditeHide

General Appearance of Type Material:
Metallic anhedral grains up to 0.6 mm in size.
Place of Conservation of Type Material:
Mineralogical collections of (1) the Museo di Storia Naturale, Università di Pisa, Via Roma 79, Calci (PI), Italy, catalogue number 19926 (holotype), and (2) the Department of Mineralogy and Petrology, National Museum in Prague, Cirkusová 1740, 19300 Prague 9, Czech Republic, catalogue numbers P1P 78/2020 (holotype) and P1P 80/2020 (cotype).
Geological Setting of Type Material:
Epithermal precious metal ore deposits hosted in Oligocene-to-Miocene hydrothermally altered volcanic rocks.
Associated Minerals at Type Locality:

Synonyms of StibiogoldfielditeHide

Relationship of Stibiogoldfieldite to other SpeciesHide

Other Members of this group:
Arsenogoldfieldite(Cu4Cu2)(Cu4Cu+2)(As2Te2)S12SIso. 4 3m : I4 3m
Goldfieldite(Cu42)(Cu4Cu+2)Te4S12SIso. 4 3m : I4 3m

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Stibiogoldfieldite associated with GoldAu
1 photo of Stibiogoldfieldite associated with CalaveriteAuTe2

Related Minerals - Strunz-mindat GroupingHide

2.GB.Polybasite-TacTrig. 3m (3 2/m) : P3m1
2.GB.Argentotetrahedrite-(Hg)Ag6(Cu4Hg2)Sb4S12SIso. 4 3m : I4 3m
2.GB.Hakite-(Zn)Cu6(Cu4Zn2)Sb4Se12SeIso. 4 3m : I4 3m
2.GB.Hakite-(Cd)Cu6(Cu4Cd2)Sb4Se12SeIso. 4 3m : I4 3m
2.GB.Argentotetrahedrite-(Zn)Ag6(Cu4Zn2)Sb4S12SIso. 4 3m : I4 3m
2.GB.Pošepnýite(Cu+33)(Hg2+4Cu+2)Sb4Se12(Se0.50.5)Iso. 4 3m : I4 3m
2.GB.ArgentopearceiteAg16As2S11Trig. 3 2 : P3 2 1
2.GB.Zvěstovite-(Zn)Ag6(Ag4Zn2)As4S12SIso.
2.GB.Kenoargentotennantite-(Fe)[Ag6]4+(Cu4Fe2)As4S12Iso.
2.GB.Tennantite-(Hg)Cu6(Cu4Hg2)As4S12SIso. 4 3m : I4 3m
2.GB.Kenoargentotetrahedrite-(Zn)[Ag6]4+(Cu4Zn2)Sb4S12Iso. 4 3m : I4 3m
2.GB.Tennantite-(Cu)Cu6(Cu4Cu2)As4S12SIso. 4 3m : I4 3m
2.GB.Tennantite-(Ni)Cu6(Cu4Ni2)As4S12SIso. 4 3m : I4 3m
2.GB.Tetrahedrite-(Ni)Cu6(Cu4Ni2)Sb4S12SIso. 4 3m : I4 3m
2.GB.Stibioústalečite(Cu4Cu2)(Cu4Cu+2)(Sb2Te2)Se12SeIso. 4 3m : I4 3m
2.GB.Arsenogoldfieldite(Cu4Cu2)(Cu4Cu+2)(As2Te2)S12SIso. 4 3m : I4 3m
2.GB.Tennantite-(In)Cu6(Cu4(In3+Cu+))As4S12SIso. 4 3m : I4 3m
2.GB.Tennantite-(Cd)Cu6(Cu4Cd2)As4S12SIso. 4 3m : I4 3m
2.GB.Tetrahedrite-(Mn)Cu6(Cu4Mn2)Sb4S12SIso. 4 3m : I4 3m
2.GB.Argentopolybasite[Ag6Sb2S7][Ag9AgS4]Trig. 3 2 : P3 2 1
2.GB.XKenorozhdestvenskayaite-(Fe)[Ag6]4+(Ag4Fe2+2)Sb4S12Iso. 4 3m : I4 3m
2.GB.Argentotetrahedrite-(Cd)Ag6(Cu4Cd2)Sb4S12SIso. 4 3m : I4 3m
2.GB.Tennantite-(Mn)Cu6(Cu4Mn2)As4S12SIso. 4 3m : I4 3m
2.GB.Zvěstovite-(Fe)Ag6(Ag4Fe2+2)As4S12SIso. 4 3m : I4 3m
2.GB.Hakite-(Fe)Cu6(Cu4Fe2+2)Sb4Se12SeIso. 4 3m : I4 3m
2.GB.Tetrahedrite-(Cu)Cu6(Cu4Cu2+2)Sb4S12SIso. 4 3m : I4 3m
2.GB.Arsenoústalečite(Cu4Cu2)(Cu4Cu+2)(As2Te2)Se12SeIso. 4 3m : I4 3m
2.GB.Tetrahedrite-(Cd)Cu6(Cu4Cd2)Sb4S12SIso. 4 3m : I4 3m
2.GB.05Argentotennantite-(Zn)Ag6(Cu4Zn2)As4S12SIso. 4 3m : I4 3m
2.GB.05Freibergite Subgroup(Ag6,[Ag6]4+)(Cu4 C2+2)Sb4S12S0-1Iso. 4 3m : I4 3m
2.GB.05Giraudite-(Zn)Cu6(Cu4Zn2)As4Se12SeIso. 4 3m : I4 3m
2.GB.05Goldfieldite(Cu42)(Cu4Cu+2)Te4S12SIso. 4 3m : I4 3m
2.GB.05Hakite-(Hg)Cu6(Cu4Hg2)Sb4Se12SeIso. 4 3m : I4 3m
2.GB.05Tennantite SubgroupCu6(Cu4C2+2)As4S12SIso. 4 3m : I4 3m
2.GB.05Tetrahedrite SubgroupCu6(Cu4C2+2)Sb4S12SIso. 4 3m : I4 3m
2.GB.05Argentotetrahedrite-(Fe)Ag6(Cu4Fe2)Sb4S12SIso. 4 3m : I4 3m
2.GB.05Rozhdestvenskayaite-(Zn)Ag6(Ag4Zn2)Sb4S12SIso. 4 3m : I4 3m
2.GB.05UM1992-21-S:AgFeSbAg6(Ag4Fe2+2)Sb4S12SIso.
2.GB.05Tennantite-(Zn)Cu6(Cu4Zn2)As4S12SIso. 4 3m : I4 3m
2.GB.05Tetrahedrite-(Zn)Cu6(Cu4Zn2)Sb4S12SIso. 4 3m : F4 3m
2.GB.05Tennantite-(Fe)Cu6(Cu4Fe2+2)As4S12SIso. 4 3m : I4 3m
2.GB.05Tetrahedrite-(Fe)Cu6(Cu4Fe2+2)Sb4S12SIso. 4 3m : I4 3m
2.GB.05Kenoargentotetrahedrite-(Fe)[Ag6]4+(Cu4Fe2+2)Sb4S12Iso. 4 3m : I4 3m
2.GB.05Tetrahedrite-(Hg)Cu6(Cu4Hg2)Sb4S12SIso. 4 3m : I4 3m
2.GB.10SelenostephaniteAg5SbSe4Orth. 2 2 2 : P21 21 21
2.GB.10StephaniteAg5SbS4Orth. mm2 : Cmc21
2.GB.15Pearceite[Ag6As2S7][Ag9CuS4]Trig. 3m (3 2/m) : P3m1
2.GB.15Polybasite[Ag6Sb2S7][Ag9CuS4]Mon. 2/m : B2/m
2.GB.15UM2003-14-S:AgBiFeTeAg16FeBiTe3S8
2.GB.15Selenopolybasite[(Ag,Cu)6(Sb,As)2(S,Se)7][Ag9Cu(S,Se)2Se2]Trig. 3m (3 2/m) : P3m1
2.GB.15Cupropearceite[Cu6As2S7][Ag9CuS4]Trig. 3m (3 2/m) : P3m1
2.GB.15Cupropolybasite[Cu6Sb2S7][Ag9CuS4]Trig. 3m : P3 1m
2.GB.15UM1979-17-S:BiCuFe~Cu18Fe4BiS16
2.GB.20Galkhaite(Hg5Cu)CsAs4S12Iso. 4 3m : I4 3m
2.GB.20Vorontsovite(Hg5Cu)Σ6TlAs4S12Iso. 4 3m : I4 3m
2.GB.20Ferrovorontsovite(Fe5Cu)Σ6TlAs4S12Iso. 4 3m : I4 3m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for StibiogoldfielditeHide

References for StibiogoldfielditeHide

Localities for StibiogoldfielditeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Greece
 
  • Eastern Macedonia and Thrace
    • Evros
      • Alexandroupoli
P. Voudouris et al. (2022)
Russia
 
  • Kamchatka Krai
    • Koryak Okrug
      • Karaginsky District
        • Maletoyvayam ore field
Kasatkin et al. (2023)
USA (TL)
 
  • Nevada
    • Esmeralda County
      • Goldfield Mining District
        • Goldfield
Miyawaki et al. (2021) +1 other reference
 
矿物 and/or 产地  
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