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Hydrotalcite Supergroup

A group of related mineral species
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06814690014947071537806.jpg
Pyroaurite

Långban Mine, Långban Ore District, Filipstad, Värmland County, Sweden
01504060014947056145993.jpg
Omsite, etc.

Correc d'en Llinassos, Oms, Céret, Pyrénées-Orientales, Occitanie, France
02003090014977564734174.jpg
Hydrotalcite

Bazhenovsk deposit, Asbest, Sverdlovsk Oblast, Russia
05787790014947064678314.jpg
Pyroaurite

Långban Mine, Långban Ore District, Filipstad, Värmland County, Sweden
08508830014946585902330.jpg
Omsite, etc.

Correc d'en Llinassos, Oms, Céret, Pyrénées-Orientales, Occitanie, France
01979600014968713489320.jpg
Hydrotalcite

Bazhenovsk deposit, Asbest, Sverdlovsk Oblast, Russia
06814690014947071537806.jpg
Pyroaurite

Långban Mine, Långban Ore District, Filipstad, Värmland County, Sweden
01504060014947056145993.jpg
Omsite, etc.

Correc d'en Llinassos, Oms, Céret, Pyrénées-Orientales, Occitanie, France
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About Hydrotalcite SupergroupHide

A supergroup of minerals with natural layered double hydroxides (LDH). They are characterized structurally by layer-lattices based on a stacking of positively charged metal hydroxide layers along [0001], as in brucite, with interlayer anions (mostly carbonate and/or sulphate, which can be interchangeable) and water molecules.

The nomenclature was revised by Mills et al. (2012).

In inorganic chemistry, this family of compounds is called "layered double hydroxides" (LDH), "HTlc" (hydrotalcite-like compounds) or "anionic clays".


Unique IdentifiersHide

Mindat ID:
43290
Long-form identifier:
mindat:1:1:43290:4
GUID
(UUID V4):
f9339099-dcaf-4fa6-b3f1-e1757c1c4884

IMA Classification of Hydrotalcite SupergroupHide

IMA status notes:
IMA Approved Group Name

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014454CoalingitePastor-Rodriguez J, Taylor H F W (1971) Crystal structure of coalingite Mineralogical Magazine 38 286-2941971New Idria serpentinite, Coalinga, California, USA0293
0004272CualstibiteBonaccorsi E, Merlino S, Orlandi P (2007) Zincalstibite, a new mineral, and cualstibite: Crystal chemical and structural relationships American Mineralogist 92 198-2032007Apuan Alps, Tuscany, Italy0293
0014831HydrocalumiteSacerdoti M, Passaglia E (1988) Hydrocalumite from Latium, Italy: its crystal structure and relationship with related synthetic phases Neues Jahrbuch fur Mineralogie, Monatshefte 1988 462-4751988Montalto di Castro, Viterbo, Latium, Italy0293
0014832HydrocalumiteSacerdoti M, Passaglia E (1988) Hydrocalumite from Latium, Italy: its crystal structure and relationship with related synthetic phases Neues Jahrbuch fur Mineralogie, Monatshefte 1988 462-4751988Montalto di Castro, Viterbo, Latium, Italy0293
0014738HydrotalciteAllmann R, Jepsen H P (1969) Die struktur des hydrotalkits Neues Jahrbuch fur Mineralogie, Monatshefte 1969 544-5511969Vezna, Western Moravia0293
0000189IowaiteAllmann R, Donnay J D H (1969) About the structure of iowaite American Mineralogist 54 296-29919690293
0014506IowaiteBraithwaite R S W, Dunn P J, Pritchard R G, Paar W H (1994) Iowaite, a re-investigation Mineralogical Magazine 58 79-851994Palabora open pit mine, Phalaborwa, Transvaal0293
0014801MotukoreaiteRius J, Plana F (1986) Contribution to the superstructure resolution of the double layer mineral motukoreaite Neues Jahrbuch fur Mineralogie, Monatshefte 1986 263-2721986the Emile Baudot bank, western Mediterranean0293
0014447PyroauriteIngram L, Taylor H F W (1967) The crystal structures of sjoegrenite and pyroaurite Mineralogical Magazine 36 465-4791967Sweden0293
0005480ShigaiteCooper M A, Hawthorne F C (1996) The crystal structure of shigaite, [AlMn2(OH)6]3(SO4)2Na(H2O)6{H2O}6, a hydrotalcite-group mineral The Canadian Mineralogist 34 91-9719960293
0019806TakoviteMills S J, Whitfield P S, Kampf A R, Wilson S A, Dipple G M, Raudsepp M, Favreau G (2012) Contribution to the crystallography of hydrotalcites: the crystal structures of woodallite and takovite Journal of Geosciences 58 273-2792012Agoudal mine, Bou Azzer district, Tazenakht, Morocco0293
0010871WermlanditeRius J, Allmann R (1984) The superstructure of the double layer mineral wermlandite [Mg7(Al0.57,Fe3+0.43)2(OH)18]2+[(Ca0.6,Mg0.4)(SO4)2(H2O)12]2- Zeitschrift fur Kristallographie 168 133-1441984Langban, Warmland, Sweden0293
0004273ZincalstibiteBonaccorsi E, Merlino S, Orlandi P (2007) Zincalstibite, a new mineral, and cualstibite: Crystal chemical and structural relationships Alps, Tuscany, Italy American Mineralogist 92 198-2032007Lucchetti marble quarry, Fantiscritti marble basin, Carrara, Apuan0293
0019586ZincalstibiteMills S J, Christy A G, Kampf A R, Housley R M, Favreau G, Boulliard J C, Bourgoin V (2012) Zincalstibite-9R: the first nine-layer polytype with the layered double hydroxide structure-type Mineralogical Magazine 76 1337-13452012Monte Avanza mine, Udine Province, Italy0293
0014757KuzeliteAllmann R (1977) Refinement of the hybrid layer structure [Ca2Al(OH)6]+*[1/2SO4*3H2O]- Neues Jahrbuch fur Mineralogie, Monatshefte 1977 136-14419770293
0012351QuintiniteArakcheeva A V, Pushcharovsky D Y, Rastsvetaeva R K, Atencio D, Lubman G U (1996) Crystal structure and comparative crystal chemistry of Al2Mg4(OH)12(CO3)*3H2O, a new mineral from the hydrotalcite-manasseite group Note polytype 2H Crystallography Reports 41 972-9811996synthetic0293
0019807WoodalliteMills S J, Whitfield P S, Kampf A R, Wilson S A, Dipple G M, Raudsepp M, Favreau G (2012) Contribution to the crystallography of hydrotalcites: the crystal structures of woodallite and takovite Journal of Geosciences 58 273-2792012Mount Keith Nickel Mine, Western Australia, Australia0293
0002735ZaccagnaiteMerlino S, Orlandi P (2001) Carraraite and zaccagnaite, two new minerals from the Carrara marble quarries: their chemical compositions, physical properties and structural features American Mineralogist 86 1293-130120010293
0018810ZaccagnaiteLozano R P, Rossi C, La Iglesia A, Matesanz E (2012) Zaccagnaite-3R, a new Zn-Al hydrotalcite polytype from El Soplao cave (Cantabria, Spain) American Mineralogist 97 513-5232012El Soplao cave, Cantabria, Spain0293
0014907ZincowoodwarditeWitzke T, Raade G (2000) Zincowoodwardite, [Zn1-x Alx(OH)2][(SO4)x/2(H2O)n], a new mineral of the hydrotalcite group Neues Jahrbuch fur Mineralogie, Monatshefte 2000 455-4652000Hilarion mine, Kamariza, near Laurion, Greece0293
0014908ZincowoodwarditeWitzke T, Raade G (2000) Zincowoodwardite, [Zn1-x Alx(OH)2][(SO4)x/2(H2O)n], a new mineral of the hydrotalcite group Neues Jahrbuch fur Mineralogie, Monatshefte 2000 455-4652000Hilarion mine, Kamariza, near Laurion, Greece0293
0005826NikischeriteHuminicki D M C, Hawthorne F C (2003) The crystal structure of nikischerite, NaFeAl3(SO4)2(OH)18(H2O)12, a mineral of the shigaite group The Canadian Mineralogist 41 79-8220030293
CIF Raw Data - click here to close

Synonyms of Hydrotalcite SupergroupHide

Relationship of Hydrotalcite Supergroup to other SpeciesHide

Group Members:
Akopovaite  Al4Li2(OH)12(CO3)(H2O)3Mon. 2/m : B2/m
Amoraite Ca12Al6(OH)36(CO3)2(SO3) · 15H2O Tric. 1 : P1
Brugnatellite Mg6Fe3+(CO3)(OH)13 · 4H2OHex.
Carbocalumite Ca4Al2(OH)12(CO3) · 6H2OTrig. 3m (3 2/m) : R3c
Coalingite Mg10Fe3+2(OH)24[CO3] · 2H2OTrig. 3m (3 2/m) : R3m
Cualstibite Group M2R(OH)6[Sb5+(OH)6], where M = Zn, Ni, Cu and R = Al or Fe3+
  Cualstibite Cu2Al(OH)6[Sb5+(OH)6]Trig. 3 : P3
  Omsite Ni2Fe3+(OH)6[Sb(OH)6]Trig. 3 : P3
  Zincalstibite Zn2Al(OH)6[Sb5+(OH)6]Trig. 3 : P3
Dritsite Li2Al4(OH)12Cl2 · 3H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mcm
Fougèrite Group 
  Fougèrite Fe2+4Fe3+2(OH)12[CO3] · 3H2OTrig. 3m (3 2/m) : R3m
  Liudongshengite Zn4Cr2(OH)12(CO3) · 3H2OTrig. 3m (3 2/m) : R3m
  Mössbauerite Fe3+6O4(OH)8[CO3] · 3H2O Trig. 3
  Trébeurdenite Fe2+2Fe3+4O2(OH)10CO3 · 3H2OTrig. 3m (3 2/m) : R3m
Glaucocerinite Group 
  Carrboydite (Ni1-xAlx)(SO4)x/2(OH)2 · nH2OHex.
  Glaucocerinite (Zn1-xAlx)(OH)2(SO4)x/2 · nH2OHex.
  Hydrohonessite (Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2OHex.
  Mountkeithite [(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
  Zincaluminite Zn6Al6(SO4)2(OH)16 · 5H2O
Hydrocalumite Group 
  Hydrocalumite Ca4Al2(OH)12(Cl,CO3,OH)2 · 4H2OMon. 2 : P21
  Kuzelite Ca4Al2(OH)12[SO4] · 6H2OTrig.
  Mariakrite [Ca4Al2(OH)12(H2O)4][Fe2S4]Tric. 1 : P1
Hydrotalcite Group M6R3+2(OH)16Z · 4H2O, where M=Mg, Fe, Ni, R3+ = Al, Cr, Co or Fe, and Z=CO3, Cl
  Desautelsite Mg6Mn3+2(OH)16[CO3] · 4H2OTrig. 3m (3 2/m)
  Droninoite Ni6Fe3+2(OH)16Cl2 · 4H2OTrig. 3m (3 2/m) : R3m
  Hydrotalcite Mg6Al2(CO3)(OH)16 · 4H2OTrig. 3m (3 2/m) : R3m
  Hydrotalcite-3R Mg6Al2(CO3)(OH)16 · 4H2OTrig. 3m (3 2/m) : R3m
  Iowaite Mg6Fe3+2(OH)16Cl2 · 4H2OTrig. 3m (3 2/m) : R3m
  Kaznakhtite Ni6Co3+2(CO3)(OH)16 · 4H2OTrig. 3 : R3
  Meixnerite Mg6Al2(OH)16(OH)2 · 4H2OTrig. 3m (3 2/m) : R3m
  Pyroaurite Mg6Fe3+2(OH)16[CO3] · 4H2OTrig. 3m (3 2/m) : R3m
  Reevesite Ni6Fe3+2(OH)16(CO3) · 4H2OTrig. 3m (3 2/m) : R3m
  Stichtite Mg6Cr3+2(OH)16[CO3] · 4H2OTrig. 3m (3 2/m) : R3m
  Takovite Ni6Al2(OH)16[CO3] · 4H2OTrig. 3m (3 2/m) : R3m
  UM2002-02-COH:FeNi (Fe2+,Ni)6Fe3+2(CO3)(OH)16 · 4H2O
  Woodallite Mg6Cr2(OH)16Cl2 · 4H2OTrig. 3m (3 2/m) : R3m
Karchevskyite Mg18Al9(OH)54Sr2(CO3)9(H2O)6 (H3O)5Trig.
Mampsisite Ca4Al2(CO3)(OH)12 · 5H2OTric.
Muskoxite Mg7Fe4O13 · 10H2OTrig. 3m (3 2/m)
Poellmannite Ca6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
Quintinite Group 
  Caresite Fe2+4Al2(OH)12[CO3] · 3H2OTrig. 3 2 : P31 1 2
  Charmarite Mn2+4Al2(OH)12[CO3] · 3H2OHex.
  Chlormagaluminite Mg4Al2(OH)12Cl2 · 3H2OHex. 6/mmm (6/m 2/m 2/m) : P63/mcm
  Comblainite Ni4Co2(OH)12[CO3] · 3H2OTrig.
  Quintinite Mg4Al2(OH)12(CO3) · 3H2OHex. 6 2 2 : P63 2 2
  Zaccagnaite Zn4Al2(OH)12[CO3] · 3H2OHex.
UM1987-05-OH:AlCMg Mg4Al2(OH)12(CO3,SO4) · 3H2O
Wermlandite Group M7R3+2(OH)18[Ca(H2O)6][SO4]2 · 6H2O, where = Mg, Fe, Zn and R= Al or Fe
  Erssonite Mg7Fe3+2(OH)18[Ca(H2O)6](SO4)2 · 12H2OTrig. 3m (3 2/m) : P3c1
  Motukoreaite Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : R3m
  Natroglaucocerinite Zn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OHex.
  Nikischerite Fe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
  Shigaite Mn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
  Wermlandite Mg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : P3c1
Woodwardite Group 
  Honessite (Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2OTrig.
  Hydrowoodwardite (Cu1-xAlx)(OH)2[SO4]x/2 · nH2OTrig. 3m (3 2/m) : R3m
  Woodwardite Cu1-xAlx(OH)2(SO4)x/2 · nH2OTrig. 3m (3 2/m) : R3m
  Zincowoodwardite Zn1-xAlx(OH)2[SO4]x/2 · nH2OTrig.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Hydrotalcite Supergroup in petrologyHide

An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.

Internet Links for Hydrotalcite SupergroupHide

References for Hydrotalcite SupergroupHide

Quick NavTopAbout Hydrotalcite SupergroupUnique IdentifiersIMA Classification Crystal StructureSynonymsRelationshipsOther InformationHydrotalcite Supergroup in petrologyInternet Links References
 
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