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Glaucocerinite

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About GlaucoceriniteHide

Formula:
(Zn1-xAlx)(OH)2(SO4)x/2 · nH2O
(x < 0.5, n > 3x/2). May contain Cu replacing Zn (formula for type material is given as Znl3Al8Cu7(SO4)2O30.34H2O).
Colour:
Sky-blue, turquoise-blue, greenish, greyish, brownish
Lustre:
Waxy
Hardness:
1
Specific Gravity:
2.749
Crystal System:
Hexagonal
Name:
From the Greek γλαυκός for "sky-blue" and κήρινος for "wax-like," in allusion to its colour and appearance.
Compare also Woodwardite Group. Compare 'UM1985-07-OH:AlCuSZn' - corresponding to the alleged cotype specimen of glaucocerinite.


Classification of GlaucoceriniteHide

Approved, 'Grandfathered' (first described prior to 1959)
6/D.08-110
7.DD.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
31.4.8.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
4 : (AB)4(XO4)Zq·xH2O
25.5.10

25 : Sulphates
5 : Sulphates of Zn and Hg

Physical Properties of GlaucoceriniteHide

Colour:
Sky-blue, turquoise-blue, greenish, greyish, brownish
Comment:
Tints due to included impurities.
Hardness:
Density:
2.749 g/cm3 (Measured)    

Optical Data of GlaucoceriniteHide

Type:
Biaxial (-)
RI values:
nα = 1.540 nβ = 1.554 nγ = 1.562
2V:
Measured: 60° , Calculated: 72°
Birefringence:
High.
Max Birefringence:
δ = 0.022
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
weak

Chemical Properties of GlaucoceriniteHide

Formula:
(Zn1-xAlx)(OH)2(SO4)x/2 · nH2O

(x < 0.5, n > 3x/2). May contain Cu replacing Zn (formula for type material is given as Znl3Al8Cu7(SO4)2O30.34H2O).
IMA Formula:
(Zn1-xAlx)(SO4)x/2(OH)2 · nH2O (x < 0.5, n > 3x/2)

Crystallography of GlaucoceriniteHide

Crystal System:
Hexagonal
Morphology:
Occurs as veruginous masses with a radial-fibrous structure and concentric colour banding.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.9 Å(100)
5.45 Å(90)
3.63 Å(80)
2.62 Å(60)
2.46 Å(60)
2.231 Å(50)
1.981 Å(50)

Type Occurrence of GlaucoceriniteHide

Synonyms of GlaucoceriniteHide

Other Language Names for GlaucoceriniteHide

Relationship of Glaucocerinite to other SpeciesHide

Other Members of this group:
Carrboydite(Ni1-xAlx)(SO4)x/2(OH)2 · nH2OHex.
Hydrohonessite(Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2OHex.
Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Glaucocerinite associated with SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2O
2 photos of Glaucocerinite associated with AragoniteCaCO3
1 photo of Glaucocerinite associated with GalenaPbS

Related Minerals - Nickel-Strunz GroupingHide

7.DD.05FelsőbányaiteAl4(SO4)(OH)10 · 4H2OMon. 2 : P21
7.DD.10LangiteCu4(SO4)(OH)6 · 2H2OMon. m
7.DD.10PosnjakiteCu4(SO4)(OH)6 · H2OMon. m : Pm
7.DD.10WroewolfeiteCu4(SO4)(OH)6 · 2H2OMon. m : Pm
7.DD.15SpangoliteCu6Al(SO4)(OH)12Cl · 3H2OTrig. 3m : P3 1c
7.DD.20KtenasiteZnCu4(SO4)2(OH)6 · 6H2OMon.
7.DD.25ChristeliteCu2Zn3(SO4)2(OH)6 · 4H2OTric.
7.DD.30CampigliaiteMn2+Cu4(SO4)2(OH)6 · 4H2OMon.
7.DD.30DevillineCaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DD.30OrthoserpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OOrth. mm2 : Pca21
7.DD.30SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m : B2/b
7.DD.30NiedermayriteCdCu4(SO4)2(OH)6 · 4H2OMon. 2/m : P21/m
7.DD.30EdwardsiteCu3Cd2(SO4)2(OH)6·4H2O Mon. 2/m : P21/b
7.DD.35Carrboydite(Ni1-xAlx)(SO4)x/2(OH)2 · nH2OHex.
7.DD.35Honessite(Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35Hydrohonessite(Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35MotukoreaiteMg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : R3m
7.DD.35Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
7.DD.35ShigaiteMn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig.
7.DD.35WermlanditeMg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : P3c1
7.DD.35WoodwarditeCu1-xAlx(OH)2(SO4)x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O
7.DD.35Hydrowoodwardite(Cu1-xAlx)(OH)2[SO4]x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincowoodwarditeZn1-xAlx(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35NatroglaucoceriniteZn6Al3(OH)18[Na(H2O)6](SO4)2•6H2OHex.
7.DD.35NikischeriteFe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig.
7.DD.40Lawsonbauerite(Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.40Torreyite(Mg,Mn2+)72Mn2+2Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.45MooreiteMg92Mn2Zn4(SO4)2(OH)26 · 8H2OMon. 2/m : P2/b
7.DD.50NamuwiteZn4(SO4)(OH)6 · 4H2OTrig. 3 : P3
7.DD.55BechereriteZn7Cu(OH)13[(SiO(OH)3(SO4)]Trig. 3 : P3
7.DD.60Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2OMon. 2/m
7.DD.65VonbezingiteCa6Cu3(SO4)3(OH)12 · 2H2OMon. 2/m : P21/b
7.DD.70RedgilliteCu6(SO4)(OH)10 · H2OMon. 2/m : P21/b
7.DD.75ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21
7.DD.75Nickelalumite(Ni,Cu)Al4(SO4,(NO3)2)(OH)12 · 3H2OMon.
7.DD.75KyrgyzstaniteZnAl4(SO4)(OH)12·3H2OMon.
7.DD.80GuarinoiteZn6(SO4)(OH)10 · 5H2OHex.
7.DD.80Schulenbergite(Cu,Zn)7(SO4)2(OH)10 · 3H2OTrig.
7.DD.80ThérèsemagnaniteNaCo4(SO4)(OH)6Cl·6H2OHex.
7.DD.80UM1992-30-SO:CCuHZn(Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2OTrig. 3 : P3
7.DD.85MontetrisaiteCu6(SO4)(OH)10 · 2H2OOrth. mm2 : Cmc21

Related Minerals - Hey's Chemical Index of Minerals GroupingHide

25.5.1ZinkositeZnSO4Orth.
25.5.2GoslariteZnSO4 · 7H2OOrth. 2 2 2 : P21 21 21
25.5.3NamuwiteZn4(SO4)(OH)6 · 4H2OTrig. 3 : P3
25.5.4KtenasiteZnCu4(SO4)2(OH)6 · 6H2OMon.
25.5.5Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2OMon. 2/m
25.5.6Boyleite(Zn,Mg)SO4 · 4H2OMon. 2/m : P21/b
25.5.7SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m : B2/b
25.5.8OrthoserpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OOrth. mm2 : Pca21
25.5.9ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O
25.5.11GunningiteZnSO4 · H2OMon. 2/m : B2/b
25.5.12ChaidamuiteZnFe3+(SO4)2(OH) · 4H2OTric. 1 : P1
25.5.13Bianchite(Zn,Fe)SO4 · 6H2OMon. 2/m : P2/m
25.5.15Zincmelanterite(Zn,Cu,Fe)SO4 · 7H2OMon.
25.5.16Zincobotryogen(Zn,Mg,Mn2+)Fe3+(SO4)2(OH) · 7H2OMon. 2/m
25.5.17SchuetteiteHg2+3(SO4)O2Trig. 3 2 : P31 2 1
25.5.18Gianellaite[(NHg2)2](SO4)(H2O)xIso. 4 3m : F4 3m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for GlaucoceriniteHide

Reference List:
Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author (Z-A)
Dittler and Koechlin (1932) Centralblatt für Mineralogie, Geologie und Paleontologie, Stuttgart: 13.
American Mineralogist (1932): 17: 495.
American Mineralogist (1934): 19: 556.
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 574.
Raade, G. , Elliott, C.J. and Din, V. K. (1985): New data on glaucocerinite. Mineralogical Magazine 49: 583-590
American Mineralogist (1987): 72: 1028.
Mills, S.J., Christy, A.G., Genin, J.-M.R., Kameda, T., Colombo, F. (2012): Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76, 1289-1336.

Internet Links for GlaucoceriniteHide

Localities for GlaucoceriniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (eg from pseudomorphs.)

All localities listed without proper references should be considered as questionable.
Austria
 
  • Salzburg
    • Zell am See District
R. Exel: Die Mineralien und Erzlagerstätten Österreichs (1993)
France
 
  • Auvergne-Rhône-Alpes
    • Savoie
      • Tarentaise valley
        • La Léchère (Notre Dame de Briançon)
De Ascencao Guedes R. (2001), Le Penay: un filon de galène argentifère (La Léchère, Savoie), Le Cahier des Micromonteurs, n°2, pp: 13-20
Germany
 
  • Lower Saxony
    • Goslar
      • Goslar
        • Astfeld
No reference listed
  • North Rhine-Westphalia
    • Arnsberg
      • Märkischer Kreis
        • Iserlohn
          • Letmathe
Bender, D. and Krimmelbein, W. (1994) Aktuelle Übersicht: Mineralien der Zinkhütte Genna/Sauerland. Stand Juni 1994. Mineralien-Welt, 4/94, 10.
    • Cologne
      • Aachen
        • Stolberg
Blaß, G. & Graf, H. W. (1995): Neufunde von Schlackenhalden in der nördlichen Eifel (II). Mineralien-Welt, 6 (3), 28-31.
Blaß, G. & Graf, H.W. (1993): Neue Funde. Mineralien-Welt, 4 (2), 57-60.
  • Rhineland-Palatinate
    • Rhein-Lahn-Kreis
Wittern: "Mineralfundorte in Deutschland", 2001
        • Frücht
Der Aufschluss Vol.55, March/April 2004
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Lavrion District Mines
          • Agios Konstantinos [St Constantine] (Kamariza)
LAPIS 24 (7/8) 1999; Wendel, W. and Markl, G. (1999) Lavrion: Mineralogische Klassiker und Raritäten für Sammler. LAPIS 24 (7/8):34-52
            • Kamariza Mines (Kamareza Mines)
Lapis, 24, 7/8 (1999)
              • Hilarion area
Lapis, 24, 7/8 (1999)
No reference listed
Centralbl.Min.,Abt. A (1932) p. 13-17
          • Sounion area
            • Sounion Mines
W. Krause, H.-J. Bernhardt, R. S. W. Braithwaite, U. Kolitsch and R. Pritchard (2006): Kapellasite, Cu3Zn(OH)6Cl2, a new mineral from Lavrion, Greece. Mineralogical Magazine 70, 331-342.
Italy
 
  • Friuli-Venezia Giulia
    • Udine Province
      • Degano Valley
Bortolozzi, G.M., Bracco, R., De Tuoni, F., Vidus, L., Bittarello, E., Marengo, A., Ciriotti, M.E., Zorzi, F. (2018) Antiche miniere e affioramenti metalliferi a Comeglians (Val Degano, Friuli-Venezia Giulia): recenti ritrovamenti. Micro, 16, 1-2018, 2-36.
  • Trentino-Alto Adige
    • South Tirol
      • Chiusa (Klausen)
Mair, V. (1996): Die Kupferbergbaue von Stilfs, Eyrs und Klausen. Der Stoansucher 10 (1), 38-44.
    • Trento Province (Trentino)
      • Roncegno
-Bortolozzi G., Blass G., Boscardin M., Rocchetti I. and Ferretti P. (2013): La Miniera di Cinquevalli (Valsugana, Trentino-Alto Adige): aggiornamento sulle specie accertate negli ultimi anni. Studi Trent. Sci. Nat., 93, pagg. 149-165.
  • Tuscany
    • Livorno Province
      • Campigliese (Campiglia Mountains; Campiglia Ridge)
        • Campiglia Marittima
Biagioni, C., Orlandi, P., Cerri, M., Pistolesi, M., Rapaccini, S. & Santucci, A. (2013). Temperino e Lanzi. Le paragenesi secondarie dello skarn. Rivista Mineralogica Italiana, 1/2013, 40-55.
Norway
 
  • Aust-Agder
    • Froland
      • Bøylestad Kobberverk
Raade, G. and Sæbø, P. Chr. (1990) New Secondary Copper Minerals from Norway. In Interne notater Mineralogisk -Geologisk Museum Universitetet i Oslo, 1961 - 1990. Geologisk Museums Venner, 1991, p.145-148
  • Rogaland
    • Sauda
Selbekk R.S. (2010): Norges mineraler. En revidert utgave av Norges mineraler (Neumann 1985). Tapir-NGU-NHM.p 245
USA
 
  • Arizona
    • Cochise County
      • Turquoise Mining District (Courtland-Gleeson Mining District)
        • Courtland
          • Casey Hill
rolf luetcke
Grant, Raymond W., Bideaux, R.A., and Williams, S.A. (2006) Minerals Added to the Arizona List 1995-2005: 4. Frost, et al (2004).
 
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