| Adachiite | CaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH) |
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| Alfredstelznerite | Ca4(H2O)4[B4O4(OH)6]4(H2O)15 |
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| Arrheniusite-(Ce) | CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11 |
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| Axinite-(Fe) | Ca2Fe2+Al2BSi4O15OH |
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| Axinite-(Mg) | Ca2MgAl2BSi4O15OH |
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| Axinite-(Mn) | Ca2Mn2+Al2BSi4O15(OH) |
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| Borcarite | Ca4Mg(B4O6(OH)6)(CO3)2 |
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| Braitschite-(Ce) | (Ca,Na2)7(Ce,La)2B22O43 · 7H2O |
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| Brianroulstonite | Ca3[B5O6(OH)6](OH)Cl2 · 8H2O |
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| Buryatite | Ca3(Si,Fe3+,Al)(SO4)B(OH)4(OH,O)6 · 12H2O |
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| Byzantievite | Ba5(Ca,REE,Y)22(Ti,Nb)18(SiO4)4[(PO4),(SiO4)]4(BO3)9O22[(OH),F]43(H2O)1.5 |
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| Cahnite | Ca2[B(OH)4](AsO4) |
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| Calciborite | Ca(B2O4) |
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| Calcioveatchite | SrCaB11O16(OH)5 · 5H2O |
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| Capranicaite | KCaNaAl4B4Si2O18 |
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| Carboborite | Ca2Mg[B(OH)4]2(CO3)2 · 4H2O |
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| Charlesite | Ca6(Al,Si)2(SO4)2[B(OH)4](OH,O)12 · 26H2O |
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| Chelkarite | CaMgB2O4(Cl,OH)2 · 5H2O Or near, with Cl:OH = 3:1 |
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| Chiyokoite | Ca3Si(CO3)[B(OH)4]O (OH)5 · 12H2O |
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| Ciprianiite | Ca4[(Th,U),Ca]Σ2Al(Be0.5◻1.5)Σ2[B4Si4O22](OH)2 |
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| Clinokurchatovite | Ca(Mg,Fe2+,Mn2+)[B2O5] |
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| Colemanite | Ca[B3O4(OH)3] · H2O |
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| Danburite | CaB2Si2O8 |
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| Datolite | CaB(SiO4)(OH) |
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| Ekaterinite | Ca2(B4O7)(Cl,OH)2 · 2H2O |
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| Fabianite | CaB3O5OH |
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| Fedorovskite | Ca2Mg2B4O7(OH)6 |
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| Ferri-hellandite-(Ce) | (Ca3Ce)Ce2Fe3+◻2B4Si4O22(OH)2 |
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| Ferri-mottanaite-(Ce) | Ca4Ce2Fe3+(Be1.5◻0.5)[Si4B4O22]O2 |
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| Feruvite | CaFe32+(Al5Mg)(Si6O18)(BO3)3(OH)3(OH) |
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| Fluor-liddicoatite | Ca(Li2Al)Al6(Si6O18)(BO3)3(OH)3F |
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| Fluor-uvite | CaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3F |
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| Fontarnauite | (Na,K)2(Sr,Ca) (SO4)[B5O8(OH)] · 2H2O |
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| Frolovite | Ca[B(OH)4]2 |
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| Gaudefroyite | Ca4Mn3+2-3(BO3)3(CO3)(O,OH)3 |
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| Ginorite | Ca2B14O20(OH)6 · 5H2O |
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| Gowerite | Ca[B5O8(OH)][B(OH)3] · 3H2O |
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| Harkerite | Ca48Mg16[AlSi4O15(OH)]4(BO3)16(CO3)16 · 2(H2O,HCl) |
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| Heidornite | Na2Ca3B5O8(SO4)2Cl(OH)2 |
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| Hellandite-(Ce) | (Ca,REE)4Ce2Al◻2(B4Si4O22) (OH)2 |
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| Hellandite-(Y) | (Ca,REE)4Y2Al◻2(B4Si4O22) (OH)2 |
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| Henmilite | Ca2Cu[B(OH)4]2(OH)4 |
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| Hexahydroborite | Ca[B(OH)4]2 · 2H2O or CaB2O4 · 6H2O |
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| Hilgardite | Ca2B5O9Cl · H2O |
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| Homilite | Ca2(Fe2+,Mg)B2Si2O10 |
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| Hongheite | Ca19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9 |
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| Howlite | Ca2B5SiO9(OH)5 |
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| Hundholmenite-(Y) | (Y,REE,Ca,Na)15(Al,Fe3+)(CaxAs3+1-x)(Si,As5+)Si6B3(O,F)48 |
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| Hyalotekite | (Ba,Pb,K)4(Ca,Y)2(B,Be)2(Si,B)2Si8O28(F,Cl) |
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| Hydroboracite | CaMg[B3O4(OH)3]2 · 3H2O |
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