Koller, Jürgen, McElwee-White, Lisa, Abboud, Khalil A. (2007) An N-bridged tritungsten compound for the chemical vapor deposition of WN x thin films. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807049033
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | An N-bridged tritungsten compound for the chemical vapor deposition of WN x thin films | ||
| Journal | Acta Crystallographica Section E Structure Reports Online | ||
| Authors | Koller, Jürgen | Author | |
| McElwee-White, Lisa | Author | ||
| Abboud, Khalil A. | Author | ||
| Year | 2007 (November 1) | Volume | 63 |
| Issue | 11 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s1600536807049033Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 467030 | Long-form Identifier | mindat:1:5:467030:2 |
| GUID | 0 | ||
| Full Reference | Koller, Jürgen, McElwee-White, Lisa, Abboud, Khalil A. (2007) An N-bridged tritungsten compound for the chemical vapor deposition of WN x thin films. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807049033 | ||
| Plain Text | Koller, Jürgen, McElwee-White, Lisa, Abboud, Khalil A. (2007) An N-bridged tritungsten compound for the chemical vapor deposition of WN x thin films. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807049033 | ||
| In | (2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | In the title compound, octachlorido-1κ4 Cl,3κ4 Cl-di-μ2-nitrido-1:2κ2 N:N;2:3κ2 N:N-tetrapyridine-1κN,2κ2 N,3κN-bis(trimethylsilylimido-2κN)tritungsten(V) dichloromethane disolvate, [W3(C3H9NSi)2Cl8N2(C5H5N)4]·2CH2Cl2, the central W metal atom is located on a twofold rotation axis and is coordinated in a distorted octahedral environment by two trimethylsilylimido groups, two pyridine molecules and two μ-N atoms which bridge it to the two other W atoms. These terminal W centers also show a distorted octahedral coordination, the bridging N atom and the pyridine ligand being trans with respect to each other. Additionally, four Cl atoms are bound to each terminal W atom, in a square-planar geometry, completing the octahedral coordination. | ||
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