Armand, P., Granier, D., Lee, A. van der (2007) Rb3[PMo12O40], a compound containing Keggin anions. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807052506
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Rb3[PMo12O40], a compound containing Keggin anions | ||
| Journal | Acta Crystallographica Section E Structure Reports Online | ||
| Authors | Armand, P. | Author | |
| Granier, D. | Author | ||
| Lee, A. van der | Author | ||
| Year | 2007 (November 1) | Volume | 63 |
| Issue | 11 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s1600536807052506Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 467797 | Long-form Identifier | mindat:1:5:467797:4 |
| GUID | 0 | ||
| Full Reference | Armand, P., Granier, D., Lee, A. van der (2007) Rb3[PMo12O40], a compound containing Keggin anions. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807052506 | ||
| Plain Text | Armand, P., Granier, D., Lee, A. van der (2007) Rb3[PMo12O40], a compound containing Keggin anions. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807052506 | ||
| In | (2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | The cubic structure of trirubidium molybdophosphate, Rb3[PMo12O40], contains α-type Keggin [PMo12O40]3− anions and Rb+ counter-ions located in orthogonally intersecting channels. The P and Rb atoms are located on special positions with site symmetries \overline{4}3m and \overline{4}2.m, respectively. The three-dimensional arrangement is isostructural with that found in, for example, X 3[PMo12O40], with X = K, NH4 and H3O, or X 3[PW12O40] and X 4[SiW12O40], with X = Ag and Tl. The compound was crystallized using a typical high-temperature solid-state reaction with GaPO4 and X 3Mo3O10 (X = Rb or Li) as starting materials. | ||
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