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Kampf, Anthony R.; Möhn, Gerhard; Ma, Chi; Désor, Joy (2026) Hartkoppeite, a new mineral with a novel polyoxometalate sandwich cluster. American Mineralogist. doi:10.2138/am-2026-10210

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Reference TypeJournal (article/letter/editorial)
TitleHartkoppeite, a new mineral with a novel polyoxometalate sandwich cluster
JournalAmerican Mineralogist
AuthorsKampf, Anthony R.Author
Möhn, GerhardAuthor
Ma, ChiAuthor
Désor, JoyAuthor
Year2026 (April 8)
PublisherMineralogical Society of America
URL
DOIdoi:10.2138/am-2026-10210Search in ResearchGate
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Mindat Ref. ID19821917Long-form Identifiermindat:1:5:19821917:2
GUID0
Full ReferenceKampf, Anthony R.; Möhn, Gerhard; Ma, Chi; Désor, Joy (2026) Hartkoppeite, a new mineral with a novel polyoxometalate sandwich cluster. American Mineralogist. doi:10.2138/am-2026-10210
Plain TextKampf, Anthony R.; Möhn, Gerhard; Ma, Chi; Désor, Joy (2026) Hartkoppeite, a new mineral with a novel polyoxometalate sandwich cluster. American Mineralogist. doi:10.2138/am-2026-10210
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Abstract/NotesAbstract Hartkoppeite (IMA2025-056), Ca4Mn2+Mo6+6As5+4O32(OH)2(H2O)14·5H2O, is a newly approved mineral species from the Fuchs quarry, Hartkoppe, Sailauf, Bavaria, Germany. Hartkoppeite occurs as elongated and striated tabular crystals up to about 0.2 mm long. Tablets are flattened on {110}, elongated and striated parallel to [001], and exhibit the forms {110}, {1-10}, and {001}. The mineral is colorless and transparent with vitreous luster and white streak. The Mohs hardness is ∼2½. The mineral has brittle tenacity, stepped fracture, and three cleavages: {110} very good, {001} and {1-10} good. The measured density is 2.88(2) g·cm-3. The mineral is optically biaxial (+), α = 1.692(5), β = 1.693(5), γ = 1.718(5) (white light); 2Vmeas = 22(1)°; moderate r 2σI reflections) contains a novel polyoxometalate sandwich cluster of formula {Ca4Mn2+2(H2O)10[Mo6+6As5+4O32(OH)2]2}8-.

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MineralCitation Details
Hartkoppeite

Mineral Occurrences

LocalityMineral(s)
Fuchs Quarry, Hartkoppe, Sailauf, Aschaffenburg District, Lower Franconia, Bavaria, Germany Bertrandite, Calcite, Hartkoppeite, Native Arsenic, Pharmacolite, Rhyolite


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To cite: Ralph, J., Von Bargen, D., Martynov, P., Zhang, J., Que, X., Prabhu, A., Morrison, S. M., Li, W., Chen, W., & Ma, X. (2025). Mindat.org: The open access mineralogy database to accelerate data-intensive geoscience research. American Mineralogist, 110(6), 833–844. doi:10.2138/am-2024-9486.
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