 | | Journal (article/letter/editorial) | | H2O–NaCl at 700 to 900 °C and 0.7 to 2.0 GPa Angelo Antignano 1, Craig E. Manning ⁎ Department of Earth and...conditions in the earlier study. Compared to fluorite, calcite and anhydrite, fluorapatite solubility is significantly...is similar to anhydrite and much greater than calcite and fluorite. The NaCl enhancement of solubility...Ca A. Antignano, C.E. Manning / Chemical Geology 251 (2008) 112–119 salts such as calcite, fluorite...partly dissolved starting fluorapatite. 114 A. Antignano, C.E. Manning / Chemical Geology 251 (2008) 112–119 |  | Mair, Philipp, Tropper, Peter, Harlov, Daniel E., Manning, Craig E. (2017) The solubility of apatite in H2O, KCl-H2O, NaCl-H2O at 800 °C and 1.0 GPa: Implications for REE mobility in high-grade saline brines. Chemical Geology, 470. 180-192 doi:10.1016/j.chemgeo.2017.09.015 | Journal (article/letter/editorial) | | 5144 ppm at XNaCl = 0.50. Compared to fluorite, calcite and anhydrite, apatite solubility is significantly...solutions (Pan and Fleet, 1996; Schmidt et al., 2007; Antignano and Manning, 2008; Pourtier et al., 2010; Newton...of various compositions at high P and T (e.g., Antignano and Manning, 2008). It is therefore essential...P-T conditions, done by Ayers et al. (1991) and Antignano and Manning (2008) using natural Durango fluorapatite...contrast with that of other Ca compounds US such as calcite (CaCO3), fluorite (CaF2), and anhydrite (CaSO4) |  | | Journal (article/letter/editorial) | | mobility of nominally insoluble elements Angelo Antignano 1, Craig E. Manning ⁎ Department of Earth and...addresses: angelo.antignano@exxonmobil.com (A. Antignano), manning@ess.ucla.edu (C.E. Manning). 1 Current...and temperature (T) (Schuiling and 284 A. Antignano, C.E. Manning / Chemical Geology 255 (2008) 283–293...Manning (2005). Methods were similar to those of Antignano and Manning (2008). Briefly, small single-crystal...(Manning, 1994; Manning and Boettcher, 1994; Antignano and Manning, 2008). Run conditions of 0.7–2.0 |  | Sengupta, P., Bhui, U. K., Braun, I., Dutta, U., Mukhopadhyay, D. (2009) Chemical substitutions, paragenetic relations, and physical conditions of formation of hogbomite in the Sittampundi layered anorthosite complex, South India. American Mineralogist, 94 (11) 1520-1534 doi:10.2138/am.2009.3121 | Journal (article/letter/editorial) | | associated oxide phases (spinel, corundum, högbomite), calcite, and silicates (amphibole, chlorite, anorthite...anorthite grains (Fig. 2g). Locally, grains of calcite and pyrite are found in the clusters of clinozoisite...contain islands of corroded amphibole (Fig. 2j). Calcite is found at a few places near the chlorite. The...wt%) and Cr2O3 (0.21 wt%) (Table 4). The quartz, calcite, and pyrite have virtually end-member compositions...(Mag). (g) Development of clinozoisite (Czo) and calcite (Cal) in anorthite (An) grains. Crossed polarizers |  | | Journal (article/letter/editorial) | | and T, unlike some mineral-fluid systems such as calcite and rutile (e.g., Caciagli and Manning, 2003; Tropper...of fluorite, calcite, anhydrite, and apatite at 800 °C and 1 GPa. Data sources: calcite, Newton and Manning...anhydrite, Newton and Manning (2005); apatite, Antignano and Manning (2004). 304 P. Tropper, C.E. Manning...increases less strongly with XNaCl than anhydrite or calcite, but more strongly than apatite. The similar forms...solubility with XNaCl has also been observed for calcite (Newton and Manning, 2002), anhydrite (Newton and |  | | Journal (article/letter/editorial) | | aqueous fluids (e.g., Ayers and Watson 1991; Antignano and Manning 2008; Betkowski et al. 2016). Ayers...solubility and mobility varied with fluid composition. Antignano and Manning (2008) demonstrated a positive correlation...models for Ca-bearing minerals such as apatite, calcite, and fluorite predict dissolution into charged...charged species (Ayers and Watson 1991; Antignano and Manning 2008; Dolejš and Manning 2010). If the activities...past studies for the fluid volume, T, and P (Antignano and Manning 2008). Temperature was controlled |  | Tropper, P., Harlov, D., Krenn, E., Finger, F., Rhede, D., Bernhard, F. (2007) Zr-bearing minerals as indicators for the polymetamorphic evolution of the eastern, lower Austroalpine nappes (Stubenberg Granite contact aureole, Styria, Eastern Alps, Austria) Lithos, 95 (1) 72-86 doi:10.1016/j.lithos.2006.07.008 | Journal (article/letter/editorial) | | to the formation of the assemblage forsterite + calcite + titanian clinohumite ± phlogopite ± chlorite...zirconolite + apatite + calcite + chlorite ± magnetite ± pyrrhotite assemblage, (2) calcite + chlorite, (3) forsterite...titanian clinohumite + chlorite + calcite ± phlogopite and (4) calcite ± forsterite. Baddeleyite is always...model reaction baddeleyite + 2 geikielite + 3 calcite + CO2 = zirconolite + 2 dolomite. Zirconolite (Zirc...formation of the assemblage chlorite + dolomite + calcite + ilmenite ± zirconolite II ± geikielite + Fe-sulfides |  | | Journal (article/letter/editorial) | | Shmulovich et al. 2001), but enhance the solubility of calcite and anhydrite (Newton and Manning 2002, 2004)....Stalder et al. 2000; Shmulovich et al. 2001; Antignano and Manning 2003) can be used as a guide to show...albite + quartz is greater than albite alone (Antignano and Manning 2003). Solubility of albite in H2O...transformed metapelites from Val Savenca (Sesia Zone, Italy, sample VS-8). a Overview over a former plagioclase...grants EAR 9909583 and 0337170 to CEM. Angelo Antignano IV and Robert 748 Newton are thanked for their |  | Liu, Penglei, Massonne, Hans-Joachim, Jin, Zhenmin, Wu, Yao, Zhang, Junfeng (2017) Diopside, apatite, and rutile in an ultrahigh pressure impure marble from the Dabie Shan, eastern China: A record of eclogite-facies metasomatism during exhumation. Chemical Geology, 466. 123-139 doi:10.1016/j.chemgeo.2017.06.001 | Journal (article/letter/editorial) | | reaction rim of talc + calcite is much thinner than that of tremolite + calcite, indicating that the former...oriented parallel to the apatite c-axis (Fig. 2c, d). Calcite (≤ 0.3 mm) and rutile (≤ 0.2 mm; most grains ≤...dolomite (55–60 vol%), diopside (35–40 vol%), calcite (3–5 vol%), and accessory quartz, tremolite, talc...crossed polarized light. (b) Tremolite + calcite and talc + calcite reaction rims between diopside and dolomite...Ap-apatite, Arg-aragonite, Aug-augite, Bt-biotite, Cc-calcite, Coe-coesite, Cp-chalopyrite, Cpx-clinopyroxene |  | Lü, Zeng, Zhang, Lifei, Du, Jinxue, Yang, Xin, Tian, Zuolin, Xia, Bin (2012) Petrology of HP metamorphic veins in coesite-bearing eclogite from western Tianshan, China: Fluid processes and elemental mobility during exhumation in a cold subduction zone. Lithos, 136. 168-186 doi:10.1016/j.lithos.2011.10.011 | Journal (article/letter/editorial) | | minerals, such as the enclosure of magnesite (or calcite) in dolomite, rutile in titanite, and the occurrence...porphyroblastic garnet, surrounded by secondary calcite and chlorite (sample AT103-2). Planepolarized light...or is included in glaucophane and clinozoisite. Calcite, chlorite, greenish amphibole and pyrite are locally...fractured and locally replaced by chlorite and calcite. Note the curved outline of garnet indicated by...dolomite (sample H607-1). PPL. (f) BSE image showing calcite, glaucophane and omphacite in dolomite (sample |  | | Journal (article/letter/editorial) | | halogens (Pan and Fleet, 2002; Schmidt et al., 2007; Antignano and Manning, 2008a; Pourtier et al., 2010). In...rutile and apatite (Tropper and Manning, 2005; Antignano and Manning, 2008a,b; Manning et al., 2008), though...form to apatite, fluorite, calcite and anhydrite, as reported by Antignano and Manning (2008a), Tropper...and 1 GPa with that of the Durango fluorapatite (Antignano and Manning, 2008a). The much greater increase...incongruent dissolution to REE phosphate + solutes (Antignano and Manning, 2008a). In addition, the different |  | | Journal (article/letter/editorial) | | (e.g., Tropper and Manning 2005, 2007a, 2007b; Antignano and Manning 2008; Tropper et al. 2011). No evidence... unlike in some mineral-fluid systems such as calcite, rutile, and corundum (Caciagli and Manning 2003;...2007b) or fluorapatite in the system NaCl + H2O (Antignano and Manning 2008). Monazite solubility in H2O-KCl...to that seen for apatite, fluorite, calcite, anhydrite (Antignano and Manning 2008; Tropper and Manning...g., Pan and Fleet 1996; Schmidt et al. 2007; Antignano and Manning 2008; Newton and Manning 2010; Tropper |  | | Journal (article/letter/editorial) | | H2O-NaCl solutions. Investigated minerals include calcite (CaCO3), anhydrite (CaSO4), fluorite (CaF2) and...Manning, 2002, 2005; Tropper and Manning, 2007; Antignano and Manning, 2008). The dependence of solubility...observed. Preliminary data suggest that, at least for calcite, similar behavior is seen for ip t other salts...p te CaCO3 + 2NaClaq = CaCl2,aq + Na2CO3,aq calcite (Newton and Manning, 2002, 2010). This interpretation...Geochimica et Cosmochimica Acta 68, 3557-3567. Antignano, A., Manning, C.E., 2008. Fluorapatite solubility |  | | Journal (article/letter/editorial) | | + clinopyroxene1 + clinopyroxene2 + titanite + calcite ± hyalophane ± K-feldspar ± albite ± chlorite ±...darkgreen. Locally, these rocks are crosscut by calcite-bearing veins. At the border between these veins...clinozoisite (Czoi). A former vein is filled with calcite (Cc) (sample Mst 3). Cr-Al-Zn-Fe-rich spinel1...+ clinopyroxene1 + clinopyroxene2 + titanite + calcite ± hyalophane ± Kfeldspar ± albite ± chlorite ±...garnet rim. The surrounding matrix consists of calcite. (C) BSE image showing garnet on the bottom left |  | | Journal (article/letter/editorial) | | Bicocca, Piazza della Scienza 4, 20126 Milano, Italy 2 Department of Earth Sciences, University of Torino...Torino, Via Valperga Caluso 35, Torino 10125, Italy 1 Abstract This review combines fluid inclusion...often associated with carbonates (e.g., calcite, Mg-calcite, dolomite, hydrous carbonates), and/or minor...also observed (Table 1). Carbonates (mainly calcite, Mg-calcite, dolomite, magnesite) constitute common,...eclogitic 2.6 GPa near peak HP Omp fluid albite calcite anhydrite (Monviso) vein1 550 °C2 inclusions |  | | Journal (article/letter/editorial) | | GPa and 350–620 °C Craig E. Manning ⁎, Angelo Antignano 1, Heather A. Lin 2 Department of Earth and Space...Manning), angelo.antignano@exxonmobil.com (A. Antignano), heather_lin@golder.com (H.A. Lin). 1 Current...measurements used techniques similar to those of Antignano and Manning (2008a,b). For each experiment, a...Manning, 2003; Tropper and Manning, 2005, 2007; Antignano and Manning, 2008a,b). In the weight-loss experiments...systematically with dissolved Na-aluminosilicate (Antignano and Manning, 2008b; Manning et al., 2008). In |  | | Journal (article/letter/editorial) | | including the phosphates apatite and monazite (Antignano and Manning, 2008; Tropper et al., 2011), which...southwestern United States of America. Lithos 23, 19–52. Antignano, A., Manning, C.E., 2008. Fluorapatite solubility...melting in the Australalpine Ulten Zone, northern Italy. Mineral. Petrol. 58, 131–144. Holloway, J.R., 1976...Hercynian granitoid (Sila Massif, Calabria, southern Italy). Int. J. Earth Sci. 93, 400–413. Lira, R., Poklepovic...from the Gennargentu Igneous Complex (Sardinia, Italy). Mineral. Petrol. 85, 253–268. Newton, R.C., Manning |  | | Journal (article/letter/editorial) | | compositions of the samples (Table 1). Although apatite, calcite, tourmaline and zircon are also metasomatic product...model is the occurrence of an unusual microcline–calcite–biotite–apatite– sphene ± clinopyroxene ± hornblende...that carbonate-bearing brines would precipitate calcite at pressures ...apatite in saline solutions at elevated P and T (Antignano and Manning, 2004). If apatite were in the fluid...continental crust. Tectonophysics 296, 1–14. Antignano, A., Manning, C.S., 2004. Solubility of apatite |  | Huston, David L., Maas, Roland, Cross, Andrew, Hussey, Kelvin J., Mernagh, Terrence P., Fraser, Geoff, Champion, David C. (2016) The Nolans Bore rare-earth element-phosphorus-uranium mineral system: geology, origin and post-depositional modifications. Mineralium Deposita, 51 (6) 797-822 doi:10.1007/s00126-015-0631-y | Journal (article/letter/editorial) | | the ~1805 Ma Boothby Orthogneiss in the Aileron Province, Northern Territory, Australia. The fluorapatite...silicates, phosphates and (fluoro)carbonates, and (2) calcite-allanite with accessory REE-bearing phosphate and...subduction along the south margin of the Aileron Province at 1820–1750 Ma, producing a metasomatised, volatile-rich...pegmatites (Collins and Williams 1995). The Aileron Province is overlain by the Neoproterozoic to Paleozoic...mineral deposit in the Paleoproterozoic Aileron Province, which is located along the southern margin of |  | | Journal (article/letter/editorial) | | some solubility studies in our laboratory (e.g., Antignano and Manning, 2008a,b). Run conditions were 700...conditions. American Journal of Science 283, 283–297. Antignano, A., Manning, C.E., 2008a. Apatite solubility...7 to 2.0 GPa. Chemical Geology 251, 112–119. Antignano, A., Manning, C.E., 2008b. Rutile solubility in... N.C., Manning, C.E., 2003. The solubility of calcite in water at 5–16 kbar and 500–800 °C. Contributions |  | | Journal (article/letter/editorial) | | metamorphic rocks, in which inclusions of quartz, calcite, micas, feldspars, and accessory phases are commonly...calibrated using the ca. 1100 cm–1 Raman line of sparry calcite. For the heating and cooling experiments, we used...surface of the Casting Copper garnet wafers. The calcite standard was analyzed before and after each temperature...apatite may represent an alternative. For example, Antignano and Manning (2008) 748 ASHLEY ET AL: APATITE-IN-GARNET...Zeitschrift für Kristallographie, 229(5), 405–419. Antignano, A., and Manning, C.E. (2008) Fluorapatite solubility |  | Lucassen, Friedrich, Dulski, Peter, Abart, Rainer, Franz, Gerhard, Rhede, Dieter, Romer, Rolf L. (2010) Redistribution of HFSE elements during rutile replacement by titanite. Contributions to Mineralogy and Petrology, 160 (2) 279-295 doi:10.1007/s00410-009-0477-3 | Journal (article/letter/editorial) | | and variable, but generally small amounts of calcite, quartz, and epidote/zoisite and rare phengitic...weakly zoned as the matrix amphibole), titanite, calcite, plagioclase, and quartz. Textural relations demonstrate...inclusions of hornblende, plagioclase, and minor calcite in the different titanite types point to possible...lines. b m2 in Fig. 1d; dark areas are holes, calcite, and rutile relicts; LA spots were positioned in...same as of Al. hbl hornblende, pl plagioclase, cc calcite, rt rutile AFig. 2j). HFSE contents of titanite |  | Giuliani, A., Phillips, D., Fiorentini, M.L., Kendrick, M.A., Maas, R., Wing, B.A., Woodhead, J.D., Bui, T.H., Kamenetsky, V.S. (2013) Mantle oddities: A sulphate fluid preserved in a MARID xenolith from the Bultfontein kimberlite (Kimberley, South Africa) Earth and Planetary Science Letters, 376. 74-86 doi:10.1016/j.epsl.2013.06.028 | Journal (article/letter/editorial) | | frequently documented in MARID rocks, and include calcite, clinopyroxene (usually euhedral forms) and phlogopite;...μm) inclusions of celestine, sphene, apatite, calcite, emmonite (or Ca-rich strontianite [(Sr, Ca)CO3...Na, Sr and LREE), plus trace amounts of barite, calcite and emmonite. This mineral assemblage suggests...Manning, 2005), as well as other anions (e.g., P – Antignano and Manning, 2008) and cations that are largely...Spain. Earth Planet. Sci. Lett. 327–328, 50–60. Antignano, A., Manning, C.E., 2008. Fluorapatite solubility |  | Lucassen, F., Franz, G., Dulski, P., Romer, R.L., Rhede, D. (2011) Element and Sr isotope signatures of titanite as indicator of variable fluid composition in hydrated eclogite. Lithos, 121 (1) 12-24 doi:10.1016/j.lithos.2010.09.018 | Journal (article/letter/editorial) | | and variable, but generally small amounts of calcite, quartz, and epidote/zoisite and rare phengitic...compared with the matrix amphibole), titanite, calcite, plagioclase, and quartz. The contact between the...idioblastic hornblende (hbl), plagioclase, quartz, and calcite. A zoisite–biotite– plagioclase (Z) aggregate is...Lucassen et al. / Lithos 121 (2011) 12–24 and calcite inclusions are present. The single crystal titanite...1b). hbl = hornblende; rt = rutile relicts; cc = calcite. Circular black dots (arrow) are craters from laser |  | | Journal (article/letter/editorial) | | REE pattern consistent with Kd values between calcite and seawater, including a clear M-type tetrad-effect...plates and crystalline apatite can also form at a calcite-solution interface, without any organic additive...quartz veins in the BIF13 sample from Tom Price. Antignano and Manning (2008) have shown that the solubility...Great Oxidation Event? Nature 317, 1903-1906. Antignano A. and Manning C. E. (2008) Fluorapatite solubility...and the timing of Precambrian aragonite seas and calcite seas. Geology 31, 785-788. Heimann A., Johnson |
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Antignano, Livorno, Livorno Province, Tuscany, Italy