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Canfieldite

A valid IMA mineral species - grandfathered
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About CanfielditeHide

04056670015357659137358.jpg
Frederick A. Canfield
Formula:
Ag8SnS6
May contain some Ge replacing Sn, and some Te or Se replacing S.
Colour:
Steel gray with reddish tint
Lustre:
Metallic
Hardness:
Specific Gravity:
6.2 - 6.3
Crystal System:
Orthorhombic
Name:
Named in 1893 by Samuel Lewis Penfield in honor of Frederick Alexander Canfield [April 7, 1849 Randolph, New Jersey, USA - July 3, 1926), of Dover, New Jersey, USA. Canfield was a mining engineer and mineral collector. Canfield's family was long interested in running the Dickerson Suckasunny Mining Company, with iron mines in Morris County, New Jersey. Much of Canfield's professional mining work was in New Jersey and Bolivia. Canfield was also a third generation mineral collector having acquired his great uncles' mineral collection as well as his own father's collection.
Note that most "canfieldite" specimens from the type locality turn out on analysis to be Sn-bearing argyrodite. Caveat emptor.


Unique IdentifiersHide

Mindat ID:
882
Long-form identifier:
mindat:1:1:882:2
GUID
(UUID V4):
351e5eba-effa-42d8-be96-b2d7370bcd0f

IMA Classification of CanfielditeHide

Classification of CanfielditeHide

2.BA.70

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
B : Metal Sulfides, M: S > 1: 1 (mainly 2: 1)
A : With Cu, Ag, Au
2.5.6.2

2 : SULFIDES
5 : AmBnXp, with (m+n):p = 3:2
6.2.5

6 : Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and Sulphohalides
2 : Sulphogermanates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
CfiIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
CfThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of CanfielditeHide

Metallic
Transparency:
Opaque
Colour:
Steel gray with reddish tint
Comment:
Tarnishes black with blue to purple tint
Streak:
Greyish black
Hardness:
2½ on Mohs scale
Hardness:
VHN25=91 - 171 kg/mm2 - Vickers
Tenacity:
Brittle
Fracture:
Irregular/Uneven, Conchoidal
Density:
6.2 - 6.3 g/cm3 (Measured)    6.311 g/cm3 (Calculated)

Optical Data of CanfielditeHide

Anisotropism:
Generally isotropic, sometimes anomalous anisotropism
Reflectivity:
WavelengthR
400nm33.0%
440nm28.9%
480nm27.2%
520nm25.9%
560nm25.2%
600nm24.9%
640nm24.8%
680nm24.8%
700nm24.9%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 33.0%.
Colour in reflected light:
Gray-white with violet tint

Chemistry of CanfielditeHide

Mindat Formula:
Ag8SnS6

May contain some Ge replacing Sn, and some Te or Se replacing S.
Common Impurities:
Ge,Fe,Te

Crystallography of CanfielditeHide

Crystal System:
Orthorhombic
Class (H-M):
mm2 - Pyramidal
Cell Parameters:
a = 15.298(2) Å, b = 7.548(1) Å, c = 10.699(1) Å
Ratio:
a:b:c = 2.027 : 1 : 1.417
Unit Cell V:
1,235.41 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Crystals to 1cm with pseudo-octahedron and dodecahedron, botyroidal.
Twinning:
Commonly on {111}
Comment:
Space Group: P na21 or P nam (synthetic).

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0019044CanfielditeBindi L, Nestola F, Guastoni A, Zorzi F, Peruzzo L, Raber T (2012) Te-rich canfieldite, Ag8Sn(S,Te)6, from Lengenbach Quarry, Binntal, Canton Valais, Switzerland: Occurrence, description and crystal structure The Canadian Mineralogist 50 111-1182012Lengenbach Quarry, Binntal, Canton Valais, Switzerland0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.114 Å(100)
3.085 Å(90)
1.8960 Å(90)
2.727 Å(70)
1.9129 Å(70)
3.252 Å(55)
3.232 Å(55)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Geological Setting:
Late forming mineral in polymetallic veins.

Type Occurrence of CanfielditeHide

General Appearance of Type Material:
Crystals, to 1 cm
Place of Conservation of Type Material:
No defined type material.
Associated Minerals at Type Locality:
Reference:
Penfield, S.L. (1893) On canfieldite a new germanium mineral and on the chemical composition of argyrodite. American Journal of Science: 146: 107-113.

Other Language Names for CanfielditeHide

German:Canfieldit
Simplified Chinese:硫银锡矿
黑硫银锡矿
Spanish:Canfieldita

Varieties of CanfielditeHide

Tellurium-bearing CanfielditeCanfieldite with a large portion of the sulfur replaced by tellurium. E.g.: 9.4 weight% S, 18.9% Te in Pirquitas mine, Argentina; 9.5% S, 17.9% Te in Julio Verne mine, Argentina; 13.95% S, 8.69% Te in Revelstoke mine, Canada.

See also "tellurocanfieldite...
TellurocanfielditeOriginally approved but approval has subsequently been withdrawn because a subsequent single-crystal structural analysis has shown that Te is disordered over the three sulphur sites and thus the material is in fact Te-rich canfieldite.

Relationship of Canfieldite to other SpeciesHide

Other Members of this group:
AlburniteAg8GeTe2S4Iso.
ArgyroditeAg8GeS6Orth. mm2 : Pna21
Putzite(Cu4.7Ag3.3)GeS6Iso. 4 3m : F4 3m
SpryiteAg8(As3+0.5As5+0.5)S6Orth. mm2 : Pna21
Forms a series with:

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Canfieldite associated with SilverAg
3 photos of Canfieldite associated with StephaniteAg5SbS4
2 photos of Canfieldite associated with PyrargyriteAg3SbS3
1 photo of Canfieldite associated with Pearceite[Ag6As2S7][Ag9CuS4]

Related Minerals - Strunz-mindat GroupingHide

2.BA.Orileyite(Fe,Cu)2As
2.BA.AlburniteAg8GeTe2S4Iso.
2.BA.DzierżanowskiteCaCu2S2Trig. 3m (3 2/m) : P3m1
2.BA.MakotoiteAg12(Cu3Au)S8Trig. 3m (3 2/m) : R3c
2.BA.XuwenyuaniteAg9Fe3+Te2S4Iso. 4 3m : F4 3m
2.BA.05ChalcociteCu2SMon. 2/m : P21/b
2.BA.05DjurleiteCu31S16Mon. 2/m
2.BA.05GeeriteCu8S5Trig. 3
2.BA.05RoxbyiteCu9S5Tric. 1 : P1
2.BA.10AniliteCu7S4Orth. mmm (2/m 2/m 2/m) : Pnma
2.BA.10DigeniteCu9S5Trig. 3m (3 2/m) : R3m
2.BA.15BorniteCu5FeS4Orth. mmm (2/m 2/m 2/m) : Pbca
2.BA.20BellidoiteCu2SeTet. 4/m : P42/n
2.BA.20BerzelianiteCu2-xSe (x ≈ 0.12)Iso. m3m (4/m 3 2/m) : Fm3m
2.BA.25AthabascaiteCu5Se4Orth.
2.BA.25UmangiteCu3Se2Tet. 4 2m : P4 21m
2.BA.30RickarditeCu7Te5Orth. mmm (2/m 2/m 2/m) : Pmmn
2.BA.30WeissiteCu2-xTeHex. 6/mmm (6/m 2/m 2/m) : P6/mmm
2.BA.35AcanthiteAg2SMon. 2/m : P21/m
2.BA.35SpryiteAg8(As3+0.5As5+0.5)S6Orth. mm2 : Pna21
2.BA.40MckinstryiteAg5-xCu3+xS4Orth. mmm (2/m 2/m 2/m) : Pnma
2.BA.40StromeyeriteAgCuSOrth. mmm (2/m 2/m 2/m)
2.BA.40dUM2003-13-S:AgAuCuAg6AuCu2S5
2.BA.42HoneaiteAu3TlTe2 Orth. mmm (2/m 2/m 2/m) : Pbcm
2.BA.45JalpaiteAg3CuS2Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
2.BA.45KuriliteAg8Te3SeTrig. 3 : R3
2.BA.45SelenojalpaiteAg3CuSe2Tet. 4/mmm (4/m 2/m 2/m) : I41/amd
2.BA.47Spiridonovite(Cu1-xAgx)2TeTrig. 3m (3 2/m) : P3c1
2.BA.50EucairiteAgCuSeOrth.
2.BA.50WuyanzhiiteCu2STet. 4 2 2 : P43 21 2
2.BA.52ArgentiteAg2SIso.
2.BA.55AguilariteAg4SeSMon. 2/m
2.BA.55NaumanniteAg2SeOrth. 2 2 2 : P21 21 21
2.BA.60CervelleiteAg4TeSMon. 2/m
2.BA.60HessiteAg2TeMon. 2/m : P21/b
2.BA.60ChenguodaiteAg9Fe3+Te2S4Orth.
2.BA.65Henryite(Cu,Ag)3+xTe2 , with x ~ 0.40 Iso. m3m (4/m 3 2/m) : Fd3c
2.BA.65StütziteAg5-xTe3, x = 0.24-0.36Hex. 6 : P6
2.BA.70ArgyroditeAg8GeS6Orth. mm2 : Pna21
2.BA.70Putzite(Cu4.7Ag3.3)GeS6Iso. 4 3m : F4 3m
2.BA.75FischesseriteAg3AuSe2Iso. 4 3 2 : I41 3 2
2.BA.75Penzhinite(Ag,Cu)4Au(S,Se)4Hex. 6 2 2 : P63 2 2
2.BA.75PetrovskaiteAuAgSMon.
2.BA.75PetziteAg3AuTe2Iso. 4 3 2 : I41 3 2
2.BA.75UytenbogaardtiteAg3AuS2Trig. 3m (3 2/m) : R3c
2.BA.80Bezsmertnovite(Au,Ag)4Cu(Te,Pb)Orth.
2.BA.80BilibinskitePbCu2Au3Te2Iso.
2.BA.80Bogdanovite(Au,Te,Pb)3(Cu,Fe)Iso.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Industrial Uses:
Minor ore of tin and silver.

Internet Links for CanfielditeHide

References for CanfielditeHide

Reference List:

Localities for CanfielditeHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Argentina
 
  • Jujuy Province
    • Rinconada Department
      • Mina Pirquitas
Coira et al. (1995) +2 other references
Slater (2016)
          • San Miguel Open pit
Paar et al. (2000)
  • Salta Province
    • Los Andes department
      • San Antonio de los Cobres
        • Organullo mining district
Milka K. de Brodtkorb (2002)
Australia
 
  • Tasmania
    • Northern Midlands municipality
      • Rossarden mining district
Bottrill et al. (2008)
    • West Coast municipality
      • Zeehan mining district
        • North Dundas
STILLWELL +1 other reference
Austria
 
  • Salzburg
    • Tamsweg District
      • Muhr
        • Rotgülden
          • Lower Rotgülden lake
Horner et al. (1997)
  • Upper Austria
    • Schärding District
      • Sankt Florian am Inn
        • Allerding
Horninger (1936) +1 other reference
Bolivia
 
  • Oruro
    • Poopó Province
Torres et al. (2019)
  • Potosí
    • Antonio Quijarro Province
      • Uyuni Municipality
        • Carguaicollo Mine
Ahlfeld et al. (1964)
    • Chayanta Province
      • Colquechaca Municipality
Wilson (2001)
James A. Ferraiolo
    • Sud Chichas Province
      • Atocha Municipality
        • Chocaya-Animas mining district (Animas-Chocaya mining district)
Wilson (2001)
Mineralogical Society of America - ...
Wilson (2001)
Canada
 
  • British Columbia
Mineralogical Society of America - ...
      • Mount Cotterell
Peatfield (n.d.)
  • New Brunswick
    • Gloucester Co.
      • Beresford Parish
dnre-mrne.gnb.ca (2006)
China
 
  • Fujian
    • Nanping
      • Jianyang District
Mineralogical Society of America - ...
Anthony
  • Guangdong
    • Heyuan
      • Lianping Co.
Weining Zhou (1994)
    • Yunfu
      • Yuncheng District
Canhui Huang (1991) +1 other reference
  • Guangxi
    • Hechi
      • Nandan County
        • Dachang Sn-polymetallic ore field
Weining Zhou (1994)
    • Hezhou
      • Zhongshan Co.
        • Shanhu W-Sn ore field (Shanhu Mine)
Yunying Shu and Peiling Zhou (1990)
  • Hunan
    • Chenzhou
      • Guiyang Co.
Zhengqin Li (1991)
        • Huangshaping Pb-Zn-polymetallic ore field
Zhengqin Li (1991)
      • Linwu Co.
        • Xianghualing Sn-polymetallic ore field
Zhengqin Li (1991) +1 other reference
      • Yizhang Co.
        • Dongpo ore field
Weining Zhou (1994)
Yi Li and Youbin Liang (1991) +1 other reference
  • Inner Mongolia
    • Chifeng City (Ulanhad League; Chifeng Prefecture)
      • Bairin Left Banner (Balin Zuoqi)
Yongsheng Kuang et al. (2014) +3 other references
Shi et al. (2024)
      • Linxi County
Wang et al. (2022)
    • Hinggan League (Xing'an Prefecture)
      • Horqin Right Middle Banner (Ke'erqin Youyi Zhongqi)
Tianwei Guo and Zhongwen Han (1990) +1 other reference
    • Hulunbuir City (Hulunbei'er Prefecture)
      • New Barag Right Banner (Xin Barag Youqi)
Zhicheng Lu et al. (2002)
  • Jiangxi
    • Ganzhou
      • Dayu Co.
        • Xihuashan ore field
Weining Zhou (1994)
    • Shangrao
      • Wannian Co.
Leiming Xu et al. (1993)
    • Yingtan
      • Guixi Co.
        • Lengshuikeng Ag-Pb-Zn-Au deposit
Ran Lu et al. (2012)
  • Liaoning
    • Huludao
      • Jianchang County
Xuehui Xia et al. (2003)
Xuehui Xia et al. (2003)
  • Qinghai
    • Haixi Mongol and Tibetan Autonomous Prefecture
      • Dulan County
Chen et al. (2022)
  • Tibet
    • Nagchu Prefecture (Naqu Prefecture)
      • Seni District
Zhixing Feng et al. (2010) +1 other reference
Czech Republic
 
  • Central Bohemian Region
    • Kutná Hora District
      • Kutná Hora
Anthony et al. (1990)
Mineralogical Society of America - ...
  • Karlovy Vary Region
    • Cheb District
Steffen Möckel analysis
France
 
  • Auvergne-Rhône-Alpes
    • Cantal
      • Aurillac
        • Laroquebrou
          • Saint-Santin-Cantalès
      • Saint-Flour
        • Molèdes
R. Pierrot
  • Brittany
    • Finistère
      • Châteaulin
        • Poullaouen
          • Locmaria-Berrien
R.PIERROT et al. (1973)
Germany
 
  • Saxony
    • Mittelsachsen
      • Brand-Erbisdorf
Hofmann (1986)
Greece
 
  • South Aegean
    • Tinos
      • Tinos Island
Tombros (2008)
Greenland
 
  • Sermersooq
    • Arsuk Fjord
Petersen et al. (1993)
India
 
  • Haryana
    • Bhiwani District
Murao et al. (2008)
  • Rajasthan
    • Bhilwara District
Khan et al. (2021)
Indonesia
 
  • Banten Province
    • Cikotok Gold District
Marcoux et al. (1993) +2 other references
  • West Java Province
Yuningsih et al. (2014)
Japan
 
  • Aomori Prefecture
    • Minamitsugaru District
      • Ikarigaseki
Shimizu et al. (1998)
  • Gifu Prefecture
    • Hida City
      • Kamioka mine
MARIKO et al. (1996)
  • Hokkaidō Prefecture
    • Ishikari Subprefecture
      • Sapporo City
        • Minami-ku
Min. Jour. (Japan) +2 other references
  • Hyogo Prefecture
    • Asago City
      • Ikuno-cho-ono
Mineralogical Society of America - ... +1 other reference
    • Shisou City
Nakamura et al. (1973)
  • Kagoshima Prefecture
    • Ibusuki City
      • Iwato mine
Econ Geol (1989)
  • Shimane Prefecture
    • Masuda City
Soeda et al. (1984)
SOEDA et al. (1982)
  • Tochigi Prefecture
    • Nikko City
      • Ashio
Nakamura et al. (1973)
      • Kuriyamamura
Shimizu et al. (2007)
Peru
 
  • Ancash
    • Bolognesi Province
      • Huallanca District
        • Huanzala
Econ Geol (1985)
  • Lima
    • Oyón Province
      • Oyón District
EDS Analysis Frank Keutsch +1 other reference
Poland
 
  • Lower Silesian Voivodeship
    • Karkonosze County
      • Szklarska Poręba
        • Mount Spławna
Kozłowski et al. (2022)
Portugal
 
  • Castelo Branco
    • Covilhã
D. Wimmers (1985)
  • Vila Real
    • Sabrosa
Gaspar +1 other reference
Romania
 
  • Alba County
    • Bucium
      • Bucium
Cioacă et al. (2014)
    • Lupșa
      • Mușca
Cioacă et al. (2014)
    • Roșia Montană
Gheorghe C. POPESCU (2011)
  • Hunedoara County
    • Buceș
      • Stănija
Cook et al. (2003) +1 other reference
Russia
 
  • Buryatia
    • Muysky District
      • Muya
Chugaev et al. (2017)
  • Kamchatka Krai
    • Yelizovsky District
[Der Aufschluss 1995:4 p163-180] +1 other reference
  • Magadan Oblast
Mineralogical Society of America - ... +2 other references
    • Omsukchansky District
      • Ducat ore field
Savva et al. (2021)
      • Engteri ore cluster
Пальянова et al. (2016)
Palyanova et al. (2016) +1 other reference
R.G. Kravtsova et al. (2015) +1 other reference
Goryachev et al. (2014)
  • Primorsky Krai
    • Dalnegorsk Urban District
      • Dalnegorsk
Simanenko et al. (2015)
    • Krasnoarmeysky District
      • Arminsky ore district
        • Vostok
    • Pozharsky District
Dobrovol’skaya et al. (2008)
  • Sakha
    • Aldan
      • El'konskii Gorst
Novoselov et al. (2019) +1 other reference
    • Olekma area
      • Tabornoe gold deposit
Kondratieva et al. (2021)
    • Sarychev Range
Gamyanin G.N. et al. (2001) +1 other reference
    • Verkhoyansk District
L.A. Kondrat’eva +2 other references
    • Verkhoyansk Fold Belt
      • Verkhoyansk Silver Province
        • Deputatsky ore cluster
Pavlova et al. (2009)
Pavlova et al. (2009)
Pavlova et al. (2009)
Pavlova et al. (2009)
        • Southern Verkhoyansk District
Pavlova et al. (2009)
        • Western Verkhoyansk District
          • Mangazeisky ore cluster
Pavlova et al. (2009)
Nekrasov et al. (1988) +1 other reference
  • Zabaykalsky Krai
    • Olovyanninsky District
      • Kukulbeisky ore district
Mineralogical Society of America - ...
Slovakia
 
  • Prešov Region
    • Prešov District
      • Zlatá Baňa
Duda et. all.
Ďuďa R. (2001)
Spain
 
  • Andalusia
    • Almería
      • Cuevas del Almanzora
        • Las Herrerías
Navarro et al. (2009)
Switzerland
 
  • Valais
    • Goms
      • Binn
        • Fäld
Bindi et al. (2012) +1 other reference
USA
 
  • Arizona
    • Cochise County
Anthony et al. (1995)
Anthony et al. (1995)
  • Colorado
    • Lake County
      • Iron Hill
Eckel et al. (1997)
Eckel et al. (1997)
  • Montana
    • Silver Bow County
      • Butte Mining District (Summit Valley Mining District)
        • Walkerville
King (n.d.)
  • Nevada
    • Lander County
      • Lewis Mining District
Min.Rec.:20 (5)
      • McCoy Mining District
Castor et al. (2004) +1 other reference
    • Nye County
      • Hot Creek Range
Rocks & Minerals. Nov. 1999
In the collection of Brent Thorne. XRD ...
Uzbekistan
 
  • Navoiy
    • Central Kyzylkum Region
      • Bel'tau Mountains
Pekov (1998)
  • Tashkent Region
    • Ohangaron District
Evseev (1995)
Vietnam
 
  • Tuyên Quang Province
    • Na Hang District
B. Fojt & I. Kusinir (2001)
 
and/or  
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