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Oyonite

A valid IMA mineral species
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Formula:
Ag3Mn2Pb4Sb7As4S24
Colour:
Black
Lustre:
Metallic
Hardness:
3 - 3½
Specific Gravity:
5.237 (Calculated)
Crystal System:
Monoclinic
Name:
Named after the Oyon district in which the type locality is located.
Oyonite belongs to the Sb-rich members of the andorite homeotypic sub-series. Chemically similar to menchettiite, lasmanisite, and uchucchacuaite. Also compare ramdohrite and 'dürfeldtite'.

Also compare luboržákite.

A phase chemically similar to oyonite, but with the (Pb-poorer) "approximate composition MnPbAg2Sb4As2S12" is reported by Kasatkin et al. (2022).


Hide all sections | Show all sections

Unique IdentifiersHide

Mindat ID:
52807
Long-form identifier:
mindat:1:1:52807:0
GUID
(UUID V4):
013ab84c-628e-474d-8eb9-96a87e899e00

IMA Classification of OyoniteHide

Classification of OyoniteHide

2.JB.40a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
OyoIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of OyoniteHide

Metallic
Transparency:
Opaque
Colour:
Black
Streak:
black
Hardness:
3 - 3½ on Mohs scale
Hardness:
VHN100=137 kg/mm2 - Vickers
Tenacity:
Brittle
Density:
5.237 g/cm3 (Calculated)

Optical Data of OyoniteHide

Bireflectance:
Weakly to moderately
Reflectivity:
WavelengthR1R2
471.1nm33.9%40.2%
548.3nm32.5%38.9%
586.6nm31.6%38.0%
652.3nm29.8%36.5%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 40.2%.
R1 shown in black, R2 shown in red
Internal Reflections:
None
Pleochroism:
Weak
Comments:
Dark grey to a dark green

Chemistry of OyoniteHide

Mindat Formula:
Ag3Mn2Pb4Sb7As4S24

Crystallography of OyoniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 19.1806(18) Å, b = 12.7755(14) Å, c = 8.1789(10) Å
β = 90.471(1)°
Ratio:
a:b:c = 1.501 : 1 : 0.64
Unit Cell V:
2004.1 ų
Z:
2
Morphology:
Subhedral to anhedral crystals, up to 100 μm in length.
Comment:
Space group P21/n. Pseudo-orthorhombic.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.34 Å(40)
3.29 Å(100)
2.920 Å(40)
2.821 Å(70)
2.045 Å(50)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of OyoniteHide

General Appearance of Type Material:
Black metallic subhedral to anhedral crystals, up to 100 μm in length.
Place of Conservation of Type Material:
Mineralogical collections of the Museo di Storia Naturale,Sezione di Mineralogia e Litologia, Università di Firenze, Via La Pira 4, I-50121, Firenze, Italy, catalogue number 3283/I
Chemical Analysis of Type Material:
Cu0.76 %
Ag8.39 %
Mn3.02 %
Pb24.70 %
As9.54 %
Sb28.87 %
S24.30 %
Total:99.58 %
Geological Setting of Type Material:
Hydrothermal epigenetic deposit.
Associated Minerals at Type Locality:
Reference:
Bindi, L. Biagioni, C., Keutsch, F.N. (2018): Oyonite, Ag3Mn2Pb4Sb7As4S24, a New Member of the Lillianite Homologous Series from the Uchucchacua Base-Metal Deposit, Oyon District, Peru. Minerals 8, 192.

Synonyms of OyoniteHide

Relationship of Oyonite to other SpeciesHide

Other Members of this group:
AndreadiniiteCuHgAg7Pb7Sb24S48Mon. 2/m : P21/b
ArsenquatrandoriteAg17.6Pb12.8Sb38.1As11.5S96Mon. 2/m : P21/b
AschamalmitePb6-3xBi2+xS9Mon. 2/m : B2/m
Clino-oscarkempffiteAg15Pb6Sb21Bi18S72Mon. 2/m : P21/b
ErzwiesiteAg8Pb12Bi16S40Orth. mmm (2/m 2/m 2/m) : Cmcm
EskimoiteAg7Pb10Bi15S36Mon.
FizélyiteAg5Pb14Sb21S48 Mon. 2/m
GustaviteAgPbBi3S6Orth. mmm (2/m 2/m 2/m)
HeyrovskýitePb6Bi2S9Orth. mmm (2/m 2/m 2/m) : Cccm
HolubiteAg3Pb6(Sb8Bi3)S24Mon. 2/m
JasrouxiteAg16Pb4(Sb24As16)S72Tric. 1 : P1
LasmanisiteAg12Pb13Mn11Sb44S96Orth. 2 2 2 : P21 21 21
LillianitePb3-2xAgxBi2+xS6Orth. mmm (2/m 2/m 2/m)
MenchettiiteAgPb2.40Mn1.60Sb3As2S12Mon. 2/m : P21/b
OscarkempffiteAg10Pb4(Sb17Bi9)S48Orth. mm2
OurayiteAg3Pb4Bi5S13Orth.
QuatrandoriteAgPbSb3S6Mon. 2/m : P21/b
RamdohritePb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24Mon. 2/m
RoshchiniteAg19Pb10Sb51S96Orth. mmm (2/m 2/m 2/m) : Pnma
SchirmeritePbAgBi3S6 - Pb3Ag1.5Bi3.5S9Orth.
SenandoriteAgPbSb3S6Orth. mm2 : Pmn21
StaročeskéiteAg0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6Orth. mmm (2/m 2/m 2/m) : Cmcm
TerrywallaceiteAgPb(Sb,Bi)3S6 Mon. 2/m : P21/b
TreasuriteAg7Pb6Bi15S32Mon.
UchucchacuaiteAgMnPb3Sb5S12Orth. mmm (2/m 2/m 2/m) : Pmmm
UstarasitePb(Bi,Sb)6S10 (?)
VikingiteAg5Pb8Bi13S30Mon. 2/m : B2/m
XilingolitePb3Bi2S6Mon.

Related Minerals - Strunz-mindat GroupingHide

2.JB.SenandoriteAgPbSb3S6Orth. mm2 : Pmn21
2.JB.OscarkempffiteAg10Pb4(Sb17Bi9)S48Orth. mm2
2.JB.ChukotkaiteAgPb7Sb5S15Mon. 2/m : P21/b
2.JB.ArsenquatrandoriteAg17.6Pb12.8Sb38.1As11.5S96Mon. 2/m : P21/b
2.JB.Clino-oscarkempffiteAg15Pb6Sb21Bi18S72Mon. 2/m : P21/b
2.JB.AndreadiniiteCuHgAg7Pb7Sb24S48Mon. 2/m : P21/b
2.JB.GinelfiteAg2(Ag0.5Fe)TlPb23.5(Sb,As)33.5S76Tric. 1 : P1
2.JB.LazerckeriteAg3.75Pb4.50(Sb7.75Bi4)S24Mon. 2/m
2.JB.LasmanisiteAg12Pb13Mn11Sb44S96Orth. 2 2 2 : P21 21 21
2.JB.MontpelvouxiteAgPb16Sb27As18S84Tric. 1 : P1
2.JB.SelenojunoiteCu2Pb3Bi8Se16Mon. 2/m : B2/m
2.JB.05DiaphoriteAg3Pb2Sb3S8Mon. 2/m : P21/b
2.JB.10CosalitePb2Bi2S5Orth. mmm (2/m 2/m 2/m)
2.JB.15FreieslebeniteAgPbSbS3Mon. 2/m : P21/b
2.JB.15MarriteAgPbAsS3Mon. 2/m : P21/b
2.JB.20CannizzaritePb48Bi56S132Mon. 2/m : P21/m
2.JB.20WittitePb9Bi12(S,Se)27Mon.
2.JB.25aJunoiteCu2Pb3Bi8(S,Se)16Mon. 2/m : B2/m
2.JB.25iNeyiteAg2Cu6Pb25Bi26S68Mon. 2/m : B2/m
2.JB.25cNordströmiteCuPb3Bi7(Se4S10)Mon. 2/m : P21/m
2.JB.25gNuffielditeCu1.4Pb2.4Bi2.4Sb0.2S7Orth. mmm (2/m 2/m 2/m)
2.JB.25dProuditeCuPb7.5Bi9.33(S,Se)22Mon. 2/m : B2/m
2.JB.25hWeibullitePb5Bi8Se7S11Orth. mmm (2/m 2/m 2/m) : Pnma
2.JB.25bFelbertaliteCu2Pb6Bi8S19Mon. 2/m : B2/m
2.JB.25jRouxeliteCu2HgPb23Sb27S65.5Mon. 2/m : B2/m
2.JB.25fÁngelaiteCu2AgPbBiS4Orth. mmm (2/m 2/m 2/m) : Pnma
2.JB.25iCuproneyiteCu7Pb27Bi25S68Mon. 2/m : B2/m
2.JB.30aGeocronitePb14Sb6S23Mon. 2/m : P21/m
2.JB.30aJordanitePb14As6S23Mon. 2/m : P21/m
2.JB.30bKirkiitePb10Bi3As3S19Mon. 2/m : P21/m
2.JB.30cTsugaruitePb28As15S50ClOrth. mm2 : Pnn2
2.JB.30aMarcobaldiitePb12(Sb3As2Bi)Σ6S21Tric. 1 : P1
2.JB.30aArsenmarcobaldiitePb12(As3.2Sb2.8)Σ6S21Tric. 1 : P1
2.JB.35cPillaitePb9Sb10S23ClO0.5Mon. 2/m : B2/m
2.JB.35aZinkenitePb9Sb22S42Hex. 6 : P63
2.JB.35bScainiitePb14Sb30S54O5Mon. 2/m : B2/m
2.JB.35dPellouxite(Cu,Ag)Pb10Sb12S27O(Cl,S)0.6Mon. 2/m : B2/m
2.JB.35fTubuliteAg2Pb22Sb20S53 Mon. m : Pb
2.JB.35eChovanitePb15-2xSb14+2xS36Ox (x ~ 0.2)Mon. 2/m : B2/m
2.JB.40bAschamalmitePb6-3xBi2+xS9Mon. 2/m : B2/m
2.JB.40aBursaitePb5Bi4S11 (?)Orth.
2.JB.40bEskimoiteAg7Pb10Bi15S36Mon.
2.JB.40aFizélyiteAg5Pb14Sb21S48 Mon. 2/m
2.JB.40aGustaviteAgPbBi3S6Orth. mmm (2/m 2/m 2/m)
2.JB.40aLillianitePb3-2xAgxBi2+xS6Orth. mmm (2/m 2/m 2/m)
2.JB.40cOurayiteAg3Pb4Bi5S13Orth.
2.JB.40aRamdohritePb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24Mon. 2/m
2.JB.40aRoshchiniteAg19Pb10Sb51S96Orth. mmm (2/m 2/m 2/m) : Pnma
2.JB.40dSchirmeritePbAgBi3S6 - Pb3Ag1.5Bi3.5S9Orth.
2.JB.40aTreasuriteAg7Pb6Bi15S32Mon.
2.JB.40aUchucchacuaiteAgMnPb3Sb5S12Orth. mmm (2/m 2/m 2/m) : Pmmm
2.JB.40eUstarasitePb(Bi,Sb)6S10 (?)
2.JB.40aVikingiteAg5Pb8Bi13S30Mon. 2/m : B2/m
2.JB.40aXilingolitePb3Bi2S6Mon.
2.JB.40bHeyrovskýitePb6Bi2S9Orth. mmm (2/m 2/m 2/m) : Cccm
2.JB.40UM1988-05-S:AgBiCuHgPb(Hg,Ag,Cu,Pb)5Pb5Bi11S27
2.JB.40UM1988-06-S:AgBiCuHgPb(Pb,Hg)12(Cu,Ag)3(Bi,Sb)10(S,Te)27
2.JB.40aQuatrandoriteAgPbSb3S6Mon. 2/m : P21/b
2.JB.40aMenchettiiteAgPb2.40Mn1.60Sb3As2S12Mon. 2/m : P21/b
2.JB.40aTerrywallaceiteAgPb(Sb,Bi)3S6 Mon. 2/m : P21/b
2.JB.40aJasrouxiteAg16Pb4(Sb24As16)S72Tric. 1 : P1
2.JB.40aErzwiesiteAg8Pb12Bi16S40Orth. mmm (2/m 2/m 2/m) : Cmcm
2.JB.40aStaročeskéiteAg0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6Orth. mmm (2/m 2/m 2/m) : Cmcm
2.JB.40aHolubiteAg3Pb6(Sb8Bi3)S24Mon. 2/m
2.JB.40bBaiamareiteAg4Pb12Fe4Sb20S48Mon. 2/m
2.JB.55GratonitePb9As4S15Trig. 3m : R3m
2.JB.60MarrucciiteHg3Pb16Sb18S46Mon. 2/m : B2/m
2.JB.65VurroitePb20Sn2(Bi,As)22S54Cl6Mon. 2/m : B2/b
2.JB.65TazieffitePb20Cd2(As,Bi)22S50Cl10Mon. 2/m : B2/b
2.JB.70DaliranitePbHgAs2S5Mon.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for OyoniteHide

References for OyoniteHide

Localities for OyoniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Peru (TL)
 
  • Lima
    • Oyón Province
      • Oyón District
Bindi et al. (2018)
Russia
 
  • Sverdlovsk Oblast
    • Serovsky District
      • Turya river
        • Tur'insk
Kasatkin et al. (2020)
 
and/or  
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