| Reference Type | Journal (article/letter/editorial) |
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| Title | On the atomic volume relations in certain isomorphous series |
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| Journal | Mineralogical Magazine and Journal of the Mineralogical Society |
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| Authors | Hallimond, A. F. | Author |
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| Year | 1927 (September) | Volume | 21 |
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| Issue | 118 |
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| Publisher | Mineralogical Society |
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| Download URL | https://rruff.info/doclib/MinMag/Volume_21/21-118-277.pdf+ |
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| DOI | doi:10.1180/minmag.1927.021.118.01 |
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| Generate Citation Formats |
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| Mindat Ref. ID | 7042 | Long-form Identifier | mindat:1:5:7042:7 |
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| GUID | 0 |
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| Full Reference | Hallimond, A. F. (1927) On the atomic volume relations in certain isomorphous series. Mineralogical Magazine and Journal of the Mineralogical Society, 21 (118) 277-284 doi:10.1180/minmag.1927.021.118.01 |
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| Plain Text | Hallimond, A. F. (1927) On the atomic volume relations in certain isomorphous series. Mineralogical Magazine and Journal of the Mineralogical Society, 21 (118) 277-284 doi:10.1180/minmag.1927.021.118.01 |
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| In | (1926) Mineralogical Magazine Vol. 21 (118) Mineralogical Society |
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| Abstract/Notes | Considerable interest attaches to the estimation of the volume occupied by the several atoms in a crystalline compound. For the complete molecule a volume can at once be calculated from the density and the chemical composition, but the further subdivision of this space into domains belonging to the constituent atoms or groups can only be made by methods that are limited and frequently very indirect. In general, the volume is not additive, and. it seems clear that the same atom may occupy very different volumes in its different compounds; indeed, it is only within the limits of a truly isomorphous series that the volume can be treated as an additive property. But even in this case it is not possible directly to calculate volumes for the constituents of the molecule if the chemical formulae are of the same type throughout; when, however, the formulae differ in type a solution may be possible. |
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