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Zhang, Li-Fang (2007) Diaqua[N,N′-(o-phenylene)bis(pyridine-2-carboxamidato)-κ 4 N]manganese(III) perchlorate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807050453

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Reference TypeJournal (article/letter/editorial)
TitleDiaqua[N,N′-(o-phenylene)bis(pyridine-2-carboxamidato)-κ 4 N]manganese(III) perchlorate
JournalActa Crystallographica Section E Structure Reports Online
AuthorsZhang, Li-FangAuthor
Year2007 (November 1)Volume63
Issue11
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s1600536807050453Search in ResearchGate
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Mindat Ref. ID467337Long-form Identifiermindat:1:5:467337:2
GUID0
Full ReferenceZhang, Li-Fang (2007) Diaqua[N,N′-(o-phenylene)bis(pyridine-2-carboxamidato)-κ 4 N]manganese(III) perchlorate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807050453
Plain TextZhang, Li-Fang (2007) Diaqua[N,N′-(o-phenylene)bis(pyridine-2-carboxamidato)-κ 4 N]manganese(III) perchlorate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807050453
In(2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr)
Abstract/NotesIn the MnIII complex of the title compound, [MnIII(C18H12N4O2)(H2O)2]ClO4, the MnIII atom is coordinated by four N atoms from the bpb2− [1,2-bis(pyridine-2-carboxamido)benzene] ligand located in the equatorial plane and two O atoms of water molecules at axial positions, yielding a distorted MnN4O2 octahedral coordination geometry. The bpb2− ligand is nearly planar, with a maximum deviation of 0.2311 (3) Å from the mean plane. The MnIII complex cation and the perchlorate anion, both of which are located on twofold rotation axes, are connected by O—H...O and C—H...O hydrogen bonds into a three-dimensional supramolecular network structure.


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