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Butcher, Ray J., Pourian, Mohamad, Jasinski, Jerry P. (2007) [2,2′-(2,6,9,13-Tetraazatetradeca-1,13-diene-1,14-diyl)diphenolato]iron(III) chloride. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807049999

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Reference TypeJournal (article/letter/editorial)
Title[2,2′-(2,6,9,13-Tetraazatetradeca-1,13-diene-1,14-diyl)diphenolato]iron(III) chloride
JournalActa Crystallographica Section E Structure Reports Online
AuthorsButcher, Ray J.Author
Pourian, MohamadAuthor
Jasinski, Jerry P.Author
Year2007 (November 1)Volume63
Issue11
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s1600536807049999Search in ResearchGate
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Mindat Ref. ID467240Long-form Identifiermindat:1:5:467240:5
GUID0
Full ReferenceButcher, Ray J., Pourian, Mohamad, Jasinski, Jerry P. (2007) [2,2′-(2,6,9,13-Tetraazatetradeca-1,13-diene-1,14-diyl)diphenolato]iron(III) chloride. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807049999
Plain TextButcher, Ray J., Pourian, Mohamad, Jasinski, Jerry P. (2007) [2,2′-(2,6,9,13-Tetraazatetradeca-1,13-diene-1,14-diyl)diphenolato]iron(III) chloride. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807049999
In(2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr)
Abstract/NotesThe structure of the title compound, [Fe(C22H28N4O2)]Cl {also known as [N,N′-bis[3-(salicylideneamino)propyl]ethane-1,2-diamine]iron(III) chloride}, has crystallographic symmetry with both the Fe and Cl atoms lying on twofold axes. The structure adopts a conformation where the phenolate O atoms are trans. The geometry about the Fe center is distorted octahedral due to the restrictions imposed by the bite angles of the chelate rings. The structure displays N—H...Cl hydrogen bonding.


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