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Butcher, Ray J., Jasinski, Jerry P., Mayekar, Anil N., Narayana, B., Yathirajan, H. S. (2007) (2Z)-2-Bromo-3-[3,5-dibromo-4-(ethylamino)phenyl]-1-(2,4-dichlorophenyl)prop-2-en-1-one. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s160053680704946x

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Reference TypeJournal (article/letter/editorial)
Title(2Z)-2-Bromo-3-[3,5-dibromo-4-(ethylamino)phenyl]-1-(2,4-dichlorophenyl)prop-2-en-1-one
JournalActa Crystallographica Section E Structure Reports Online
AuthorsButcher, Ray J.Author
Jasinski, Jerry P.Author
Mayekar, Anil N.Author
Narayana, B.Author
Yathirajan, H. S.Author
Year2007 (November 1)Volume63
Issue11
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s160053680704946xSearch in ResearchGate
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Mindat Ref. ID467124Long-form Identifiermindat:1:5:467124:8
GUID0
Full ReferenceButcher, Ray J., Jasinski, Jerry P., Mayekar, Anil N., Narayana, B., Yathirajan, H. S. (2007) (2Z)-2-Bromo-3-[3,5-dibromo-4-(ethylamino)phenyl]-1-(2,4-dichlorophenyl)prop-2-en-1-one. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s160053680704946x
Plain TextButcher, Ray J., Jasinski, Jerry P., Mayekar, Anil N., Narayana, B., Yathirajan, H. S. (2007) (2Z)-2-Bromo-3-[3,5-dibromo-4-(ethylamino)phenyl]-1-(2,4-dichlorophenyl)prop-2-en-1-one. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s160053680704946x
In(2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr)
Abstract/NotesIn the title compound, C17H12Br3Cl2NO, the mean planes of the 3,5-dibromo-4-phenyl and 2,4-dichlorophenyl groups make a dihedral angle of 72.4 (2)°. The dihedral angles between the 2-bromoprop-2-en-1-one group and the two phenyl ring groups (3,5-dibromo-4-phenyl and 2,4-dichlorophenyl) are 71.1 (1) and 10.9 (4)°, respectively. The crystal packing is stabilized by intermolecular N—H...O hydrogen-bond interactions between the ethylamino H atom and the propyl ketone O atom, with the 3,5-dibromo-4-phenyl rings linked in chains in an alternate inverted pattern parallel and oblique to the ac face and diagonally along the a axis of the unit cell. An intramolecular hydrogen bond between the ethyl amino H atom and the 5-Br atom from the 3,5-dibromo-4-phenyl group helps stabilize the molecular conformation.


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