Erben, Milan, Císařová, Ivana, Dušek, Michal, Vinklárek, Jaromír, Picka, Michal (2007) Dibromido(η5,η5-propane-2,2-diyldicyclopentadienyl)titanium(IV) Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807048921
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Dibromido(η5,η5-propane-2,2-diyldicyclopentadienyl)titanium(IV) | ||
| Journal | Acta Crystallographica Section E Structure Reports Online | ||
| Authors | Erben, Milan | Author | |
| Císařová, Ivana | Author | ||
| Dušek, Michal | Author | ||
| Vinklárek, Jaromír | Author | ||
| Picka, Michal | Author | ||
| Year | 2007 (November 1) | Volume | 63 |
| Issue | 11 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s1600536807048921Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 467006 | Long-form Identifier | mindat:1:5:467006:7 |
| GUID | 0 | ||
| Full Reference | Erben, Milan, Císařová, Ivana, Dušek, Michal, Vinklárek, Jaromír, Picka, Michal (2007) Dibromido(η5,η5-propane-2,2-diyldicyclopentadienyl)titanium(IV) Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807048921 | ||
| Plain Text | Erben, Milan, Císařová, Ivana, Dušek, Michal, Vinklárek, Jaromír, Picka, Michal (2007) Dibromido(η5,η5-propane-2,2-diyldicyclopentadienyl)titanium(IV) Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807048921 | ||
| In | (2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | In the molecule of the title compound, [TiBr2(C13H14)], the TiIV centre is in a distorted tetrahedral environment involving two η5-bonded cyclopentadienyl rings of a propane-2,2-diyldicyclopentadienyl ligand [Ti—Cg = 2.045 (2) Å; Cg is the centroid of the cyclopentadienyl ring] and two Br atoms [Ti—Br = 2.5115 (7) Å]. The presence of the short 2,2-propylidene bridge between the two cyclopentadienyl rings constrains the Cg—Ti—Cg angle to a value of 121.32 (9)°. The Ti and central C atoms are located on a crystallographic C 2 axis. | ||
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