| Reference Type | Journal (article/letter/editorial) |
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| Title | Tetraethylammonium [12,12-diethyl-2,2,9,9-tetramethyl-1,4,7,10-tetraza-5,6-benzotridecane-3,8,11,13-tetraone(4−)]oxidomanganate(V) |
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| Journal | Acta Crystallographica Section E Structure Reports Online |
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| Authors | Berggren, Gustav | Author |
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| Kaynak, Filiz Betul | Author |
| Anderlund, Magnus F. | Author |
| Eriksson, Lars | Author |
| Åkermark, Björn | Author |
| Year | 2007 (November 1) | Volume | 63 |
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| Issue | 11 |
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| Publisher | International Union of Crystallography (IUCr) |
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| DOI | doi:10.1107/s1600536807047691Search in ResearchGate |
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| Generate Citation Formats |
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| Mindat Ref. ID | 466745 | Long-form Identifier | mindat:1:5:466745:6 |
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| GUID | 0 |
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| Full Reference | Berggren, Gustav, Kaynak, Filiz Betul, Anderlund, Magnus F., Eriksson, Lars, Åkermark, Björn (2007) Tetraethylammonium [12,12-diethyl-2,2,9,9-tetramethyl-1,4,7,10-tetraza-5,6-benzotridecane-3,8,11,13-tetraone(4−)]oxidomanganate(V) Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807047691 |
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| Plain Text | Berggren, Gustav, Kaynak, Filiz Betul, Anderlund, Magnus F., Eriksson, Lars, Åkermark, Björn (2007) Tetraethylammonium [12,12-diethyl-2,2,9,9-tetramethyl-1,4,7,10-tetraza-5,6-benzotridecane-3,8,11,13-tetraone(4−)]oxidomanganate(V) Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807047691 |
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| In | (2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr) |
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| Abstract/Notes | The MnV complex in the title compound, (C8H20N)[Mn(C21H26N4O4)O], is interesting as it has been suggested that MnV oxospecies are intermediates both in epoxidation of alkenes and in water oxidation in PSII, i.e. photosystem II, the protein found in oxygenic photosynthetic organisms, which uses light to split water into O2, protons and electrons. The Mn atom has a square-pyramidal coordination of four N atoms with an apical O atom. The four N atoms coordinating to Mn [Mn—N = 1.872 (2)–1.882 (2) Å] form a plane within 0.03 (3) Å from which the Mn ion is displaced by 0.582 (2) Å. |
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