Li, Xiu-Ling, Lu, Zai-Sheng, Niu, De-Zhong (2007) Bis(4-carboxypyridinium) aquapentakis(isothiocyanato-κN)iron(III) bis(pyridinium-4-carboxylate) Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807047460
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Bis(4-carboxypyridinium) aquapentakis(isothiocyanato-κN)iron(III) bis(pyridinium-4-carboxylate) | ||
| Journal | Acta Crystallographica Section E Structure Reports Online | ||
| Authors | Li, Xiu-Ling | Author | |
| Lu, Zai-Sheng | Author | ||
| Niu, De-Zhong | Author | ||
| Year | 2007 (November 1) | Volume | 63 |
| Issue | 11 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s1600536807047460Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 466695 | Long-form Identifier | mindat:1:5:466695:4 |
| GUID | 0 | ||
| Full Reference | Li, Xiu-Ling, Lu, Zai-Sheng, Niu, De-Zhong (2007) Bis(4-carboxypyridinium) aquapentakis(isothiocyanato-κN)iron(III) bis(pyridinium-4-carboxylate) Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807047460 | ||
| Plain Text | Li, Xiu-Ling, Lu, Zai-Sheng, Niu, De-Zhong (2007) Bis(4-carboxypyridinium) aquapentakis(isothiocyanato-κN)iron(III) bis(pyridinium-4-carboxylate) Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807047460 | ||
| In | (2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | In the crystal structure of the title compound, (C6H6NO2)2[Fe(NCS)5(H2O)]·2C6H5NO2, the iron complex lies on a mirror plane; the six-coordinate FeIII ion, the coordinated water molecule and three of the five isothiocyanate ligands are located on this plane. The crystal structure is triple-layered. The pyridinium-4-carboxylate (ina) molecules and the protonated 4-carboxypyridinium (inaH+) cations interact with each other through N—H...O and O—H...O hydrogen bonds, leading to the formation of a layer perpendicular to the b axis. Pairs of these layers sandwich another layer of {[Fe(NCS)5(H2O)]2−} n anions with which they interact via electrostatic attraction and O—H...O hydrogen bonds, resulting in sheets of triple layers also perpendicular to the b axis. | ||
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