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Jin, Li-Xia, Zhang, Shu-Hua, Liu, Zheng, Li, Guang-Zhao (2007) Aqua[3-carboxy-2-(3,5-dibromo-2-oxidobenzylamino-κ2 N,O)propanoato-κO 1](dimethylformamide-κO)copper(II) dimethylformamide solvate monohydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807041517

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Reference TypeJournal (article/letter/editorial)
TitleAqua[3-carboxy-2-(3,5-dibromo-2-oxidobenzylamino-κ2 N,O)propanoato-κO 1](dimethylformamide-κO)copper(II) dimethylformamide solvate monohydrate
JournalActa Crystallographica Section E Structure Reports Online
AuthorsJin, Li-XiaAuthor
Zhang, Shu-HuaAuthor
Liu, ZhengAuthor
Li, Guang-ZhaoAuthor
Year2007 (November 1)Volume63
Issue11
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s1600536807041517Search in ResearchGate
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Mindat Ref. ID466510Long-form Identifiermindat:1:5:466510:0
GUID0
Full ReferenceJin, Li-Xia, Zhang, Shu-Hua, Liu, Zheng, Li, Guang-Zhao (2007) Aqua[3-carboxy-2-(3,5-dibromo-2-oxidobenzylamino-κ2 N,O)propanoato-κO 1](dimethylformamide-κO)copper(II) dimethylformamide solvate monohydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807041517
Plain TextJin, Li-Xia, Zhang, Shu-Hua, Liu, Zheng, Li, Guang-Zhao (2007) Aqua[3-carboxy-2-(3,5-dibromo-2-oxidobenzylamino-κ2 N,O)propanoato-κO 1](dimethylformamide-κO)copper(II) dimethylformamide solvate monohydrate. Acta Crystallographica Section E Structure Reports Online, 63 (11) doi:10.1107/s1600536807041517
In(2007, November) Acta Crystallographica Section E Structure Reports Online Vol. 63 (11) International Union of Crystallography (IUCr)
Abstract/NotesIn the title compound, [Cu(C11H7Br2NO5)(C3H7NO)(H2O)]·C3H7NO·H2O, the CuII atom is coordinated in a slightly distorted square-pyramidal geometry defined by two O atoms and one N atom from a 3-carboxy-2-(3,5-dibromo-2-oxidobenzylamino)propanoate ligand, one O atom from a dimethylformamide (DMF) molecule in the basal plane, and by one O atom from an aqua ligand in the apical position. In the crystal structure, the water molecules are linked by O—H...O hydrogen bonds into chains which resemble a pearl necklace. The molecules form a three-dimensional supramolecular network through O—H...O hydrogen bonds and C—H...Br hydrogen bonds.


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