| Reference Type | Journal (article/letter/editorial) |
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| Title | A monomeric N,N′-dilithiobis(amido)organophosphane |
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| Journal | Acta Crystallographica Section E Structure Reports Online |
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| Authors | Copsey, May C. | Author |
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| Chivers, Tristram | Author |
| Year | 2006 (July 1) | Volume | 62 |
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| Issue | 7 |
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| Publisher | International Union of Crystallography (IUCr) |
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| DOI | doi:10.1107/s1600536806021945Search in ResearchGate |
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| Generate Citation Formats |
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| Mindat Ref. ID | 461683 | Long-form Identifier | mindat:1:5:461683:6 |
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| GUID | 0 |
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| Full Reference | Copsey, May C., Chivers, Tristram (2006) A monomeric N,N′-dilithiobis(amido)organophosphane. Acta Crystallographica Section E Structure Reports Online, 62 (7) doi:10.1107/s1600536806021945 |
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| Plain Text | Copsey, May C., Chivers, Tristram (2006) A monomeric N,N′-dilithiobis(amido)organophosphane. Acta Crystallographica Section E Structure Reports Online, 62 (7) doi:10.1107/s1600536806021945 |
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| In | (2006, July) Acta Crystallographica Section E Structure Reports Online Vol. 62 (7) International Union of Crystallography (IUCr) |
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| Abstract/Notes | The title compound [μ2-bis(2,6-diisopropylphenylamido)phenylphospaine]bis(diethyl ether)dilithium(I), [Li2(C30H39N2P)(C4H10O)2] or Li2(Et2O)2[PhP(NDipp)2] (Dipp = 2,6-diisopropylphenyl), has been structurally characterized. This is the first example of a monomeric N,N′-dilithiobis(amido)organophosphane. The steric constraints of the bulky diisopropylphenyl substituents bonded to the N atom and the solvation of the lithium ions by a donor solvent prevent the formation of a higher oligomer. |
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