Kooijman, Huub, Leijen, Monique M. van, Akkerman, Otto S., Bickelhaupt, Friedrich, Spek, Anthony L. (2006) [η2-8-(tert-Butylimino)-1-naphthyl]bis(η5-cyclopentadienyl)titanium(IV) Acta Crystallographica Section E Structure Reports Online, 62 (7) doi:10.1107/s1600536806021726
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | [η2-8-(tert-Butylimino)-1-naphthyl]bis(η5-cyclopentadienyl)titanium(IV) | ||
| Journal | Acta Crystallographica Section E Structure Reports Online | ||
| Authors | Kooijman, Huub | Author | |
| Leijen, Monique M. van | Author | ||
| Akkerman, Otto S. | Author | ||
| Bickelhaupt, Friedrich | Author | ||
| Spek, Anthony L. | Author | ||
| Year | 2006 (July 1) | Volume | 62 |
| Issue | 7 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s1600536806021726Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 461667 | Long-form Identifier | mindat:1:5:461667:6 |
| GUID | 0 | ||
| Full Reference | Kooijman, Huub, Leijen, Monique M. van, Akkerman, Otto S., Bickelhaupt, Friedrich, Spek, Anthony L. (2006) [η2-8-(tert-Butylimino)-1-naphthyl]bis(η5-cyclopentadienyl)titanium(IV) Acta Crystallographica Section E Structure Reports Online, 62 (7) doi:10.1107/s1600536806021726 | ||
| Plain Text | Kooijman, Huub, Leijen, Monique M. van, Akkerman, Otto S., Bickelhaupt, Friedrich, Spek, Anthony L. (2006) [η2-8-(tert-Butylimino)-1-naphthyl]bis(η5-cyclopentadienyl)titanium(IV) Acta Crystallographica Section E Structure Reports Online, 62 (7) doi:10.1107/s1600536806021726 | ||
| In | (2006, July) Acta Crystallographica Section E Structure Reports Online Vol. 62 (7) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | The title compound, [Ti(C5H5)2(C15H15N)], displays an iminoacyl fragment in an N-outside conformation, indicating that the C=N vector points away from the σ-bonded C atom. Considering only the geometrical centres of all η-coordinated groups, the TiIV ion adopts a severely distorted tetrahedral configuration. The crystal packing displays a short C—H...π contact linking the molecules into an infinite chain running along the b-axis direction. | ||
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