Chippindale, Ann M., Hibble, Simon J., Pohl, Alexander H., Bilbé, Edward J. (2006) Dicaesium pentacyanotricuprate(I), Cs2Cu3(CN)5. Acta Crystallographica Section E Structure Reports Online, 62 (7) doi:10.1107/s1600536806020484
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Dicaesium pentacyanotricuprate(I), Cs2Cu3(CN)5 | ||
| Journal | Acta Crystallographica Section E Structure Reports Online | ||
| Authors | Chippindale, Ann M. | Author | |
| Hibble, Simon J. | Author | ||
| Pohl, Alexander H. | Author | ||
| Bilbé, Edward J. | Author | ||
| Year | 2006 (July 1) | Volume | 62 |
| Issue | 7 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s1600536806020484Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 461580 | Long-form Identifier | mindat:1:5:461580:8 |
| GUID | 0 | ||
| Full Reference | Chippindale, Ann M., Hibble, Simon J., Pohl, Alexander H., Bilbé, Edward J. (2006) Dicaesium pentacyanotricuprate(I), Cs2Cu3(CN)5. Acta Crystallographica Section E Structure Reports Online, 62 (7) doi:10.1107/s1600536806020484 | ||
| Plain Text | Chippindale, Ann M., Hibble, Simon J., Pohl, Alexander H., Bilbé, Edward J. (2006) Dicaesium pentacyanotricuprate(I), Cs2Cu3(CN)5. Acta Crystallographica Section E Structure Reports Online, 62 (7) doi:10.1107/s1600536806020484 | ||
| In | (2006, July) Acta Crystallographica Section E Structure Reports Online Vol. 62 (7) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | Cs2Cu3(CN)5 has a layered structure consisting of [Cu3(CN)5]2− sheets stacked in an ABAB fashion along the c axis, with Cs+ cations lying between the sheets. The sheets are generated by linking –(CuCN)– chains, in which the C[triple-bond]N groups are ordered, via [Cu(CN)3]2− units. The two bridging cyanide groups of each [Cu(CN)3]2− unit show partial `head-to-tail' disorder of C and N, whilst the third C[triple-bond]N group is terminal and ordered with C bonded to Cu. | ||
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