| Reference Type | Journal (article/letter/editorial) |
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| Title | Chloro(triphenylphosphine)(tropolonato)palladium(II) |
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| Journal | Acta Crystallographica Section E Structure Reports Online |
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| Authors | Steyl, Gideon | Author |
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| Year | 2006 (May 1) | Volume | 62 |
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| Issue | 5 |
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| Publisher | International Union of Crystallography (IUCr) |
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| DOI | doi:10.1107/s1600536806011652Search in ResearchGate |
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| Generate Citation Formats |
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| Mindat Ref. ID | 460964 | Long-form Identifier | mindat:1:5:460964:7 |
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| GUID | 0 |
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| Full Reference | Steyl, Gideon (2006) Chloro(triphenylphosphine)(tropolonato)palladium(II) Acta Crystallographica Section E Structure Reports Online, 62 (5) doi:10.1107/s1600536806011652 |
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| Plain Text | Steyl, Gideon (2006) Chloro(triphenylphosphine)(tropolonato)palladium(II) Acta Crystallographica Section E Structure Reports Online, 62 (5) doi:10.1107/s1600536806011652 |
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| In | (2006, May) Acta Crystallographica Section E Structure Reports Online Vol. 62 (5) International Union of Crystallography (IUCr) |
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| Abstract/Notes | The title compound, [Pd(C7H5O2)Cl(C18H15P)], is a new type of α-diketone palladium(II) complex containing a tertiary arylphosphine. It crystallizes with a distorted square-planar geometry about the palladium(II) metal centre. The most important bond distances and angles include Pd—O (trans P) = 2.0481 (12) Å, Pd—O (trans Cl) = 2.0016 (12) Å, Pd—P = 2.2268 (4) Å, Pd—Cl = 2.2770 (5) Å, O—Pd—O = 80.22 (5)° and O—C—C—O = 3.7 (2)°. A π–π stacking interaction is observed between neighbouring tropolonate groups, with an interplanar distance of 3.377 (6) Å. |
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