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Billetter, Heinrich, Pantenburg, Ingo, Ruschewitz, Uwe (2006) Copper(II) chlorofumarate trihydrate. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010750

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Reference TypeJournal (article/letter/editorial)
TitleCopper(II) chlorofumarate trihydrate
JournalActa Crystallographica Section E Structure Reports Online
AuthorsBilletter, HeinrichAuthor
Pantenburg, IngoAuthor
Ruschewitz, UweAuthor
Year2006 (April 1)Volume62
Issue4
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s1600536806010750Search in ResearchGate
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Mindat Ref. ID460876Long-form Identifiermindat:1:5:460876:3
GUID0
Full ReferenceBilletter, Heinrich, Pantenburg, Ingo, Ruschewitz, Uwe (2006) Copper(II) chlorofumarate trihydrate. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010750
Plain TextBilletter, Heinrich, Pantenburg, Ingo, Ruschewitz, Uwe (2006) Copper(II) chlorofumarate trihydrate. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010750
In(2006, April) Acta Crystallographica Section E Structure Reports Online Vol. 62 (4) International Union of Crystallography (IUCr)
Abstract/NotesBlue crystals of the title compound, poly[[[diaquacopper(II)]-μ3-chlorofumarato] monohydrate], {[Cu(OOC–CH=CCl–COO)(H2O)2]·H2O}
n
, crystallized unexpectedly from an aqueous solution containing acetylenedicarboxylic acid and CuCl2. Each copper cation is coordinated by five O atoms – three from three fumarate anions and two from two water molecules – in the form of a distorted square pyramid. All atoms of the asymmetric unit, except a carboxylate oxygen and the coordinated water molecule, lie on a mirror plane. These units are connected by the bifunctional anions to form ribbons along [001]. These ribbons are held together by hydrogen bonds, which also involve the third water molecule.


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