Billetter, Heinrich, Pantenburg, Ingo, Ruschewitz, Uwe (2006) Copper(II) chlorofumarate trihydrate. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010750
| Reference Type | Journal (article/letter/editorial) | ||
|---|---|---|---|
| Title | Copper(II) chlorofumarate trihydrate | ||
| Journal | Acta Crystallographica Section E Structure Reports Online | ||
| Authors | Billetter, Heinrich | Author | |
| Pantenburg, Ingo | Author | ||
| Ruschewitz, Uwe | Author | ||
| Year | 2006 (April 1) | Volume | 62 |
| Issue | 4 | ||
| Publisher | International Union of Crystallography (IUCr) | ||
| DOI | doi:10.1107/s1600536806010750Search in ResearchGate | ||
| Generate Citation Formats | |||
| Mindat Ref. ID | 460876 | Long-form Identifier | mindat:1:5:460876:3 |
| GUID | 0 | ||
| Full Reference | Billetter, Heinrich, Pantenburg, Ingo, Ruschewitz, Uwe (2006) Copper(II) chlorofumarate trihydrate. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010750 | ||
| Plain Text | Billetter, Heinrich, Pantenburg, Ingo, Ruschewitz, Uwe (2006) Copper(II) chlorofumarate trihydrate. Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010750 | ||
| In | (2006, April) Acta Crystallographica Section E Structure Reports Online Vol. 62 (4) International Union of Crystallography (IUCr) | ||
| Abstract/Notes | Blue crystals of the title compound, poly[[[diaquacopper(II)]-μ3-chlorofumarato] monohydrate], {[Cu(OOC–CH=CCl–COO)(H2O)2]·H2O} n , crystallized unexpectedly from an aqueous solution containing acetylenedicarboxylic acid and CuCl2. Each copper cation is coordinated by five O atoms – three from three fumarate anions and two from two water molecules – in the form of a distorted square pyramid. All atoms of the asymmetric unit, except a carboxylate oxygen and the coordinated water molecule, lie on a mirror plane. These units are connected by the bifunctional anions to form ribbons along [001]. These ribbons are held together by hydrogen bonds, which also involve the third water molecule. | ||
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