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Macalindong, Jennifer S., Fronczek, Frank R., Schuerman, Judith A., Selbin, Joel, Watkins, Steven F. (2006) (2-Methyldithiobenzoato-κS)(triphenylphosphine-κO)gold(I) Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010725

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Reference TypeJournal (article/letter/editorial)
Title(2-Methyldithiobenzoato-κS)(triphenylphosphine-κO)gold(I)
JournalActa Crystallographica Section E Structure Reports Online
AuthorsMacalindong, Jennifer S.Author
Fronczek, Frank R.Author
Schuerman, Judith A.Author
Selbin, JoelAuthor
Watkins, Steven F.Author
Year2006 (April 1)Volume62
Issue4
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s1600536806010725Search in ResearchGate
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Mindat Ref. ID460873Long-form Identifiermindat:1:5:460873:2
GUID0
Full ReferenceMacalindong, Jennifer S., Fronczek, Frank R., Schuerman, Judith A., Selbin, Joel, Watkins, Steven F. (2006) (2-Methyldithiobenzoato-κS)(triphenylphosphine-κO)gold(I) Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010725
Plain TextMacalindong, Jennifer S., Fronczek, Frank R., Schuerman, Judith A., Selbin, Joel, Watkins, Steven F. (2006) (2-Methyldithiobenzoato-κS)(triphenylphosphine-κO)gold(I) Acta Crystallographica Section E Structure Reports Online, 62 (4) doi:10.1107/s1600536806010725
In(2006, April) Acta Crystallographica Section E Structure Reports Online Vol. 62 (4) International Union of Crystallography (IUCr)
Abstract/NotesThe asymmetric unit of the title compound, o-CH3(C6H4)C(S)S–Au–P(C6H5)3 or [Au(C8H7S2)(C18H15P)], consists of two quasi-linear gold complexes. The S—Au—P bond angles [173.83 (2), 175.03 (2)°], S—Au bond lengths [2.3240 (6), 2.3329 (6) Å] and Au—P bond lengths [2.2568 (6), 2.2632 (6) Å] are consistent with previously reported values. The major difference in the two molecules is that the o-methylphenyl rings are twisted with respect to the dithiocarboxyl planes by 73.0 (3)° and 46.6 (3)°, as measured by S—C—C—C torsion angles.


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