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Bryan, Jeffrey C., Burrell, Anthony K., Kubas, Gregory J. (2001) [TcCl(CS)(dppe)2]·C6H6. Acta Crystallographica Section E Structure Reports Online, 57 (1) doi:10.1107/s1600536800019486

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Reference TypeJournal (article/letter/editorial)
Title[TcCl(CS)(dppe)2]·C6H6
JournalActa Crystallographica Section E Structure Reports Online
AuthorsBryan, Jeffrey C.Author
Burrell, Anthony K.Author
Kubas, Gregory J.Author
Year2001 (January 1)Volume57
Issue1
PublisherInternational Union of Crystallography (IUCr)
DOIdoi:10.1107/s1600536800019486Search in ResearchGate
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Mindat Ref. ID445393Long-form Identifiermindat:1:5:445393:6
GUID0
Full ReferenceBryan, Jeffrey C., Burrell, Anthony K., Kubas, Gregory J. (2001) [TcCl(CS)(dppe)2]·C6H6. Acta Crystallographica Section E Structure Reports Online, 57 (1) doi:10.1107/s1600536800019486
Plain TextBryan, Jeffrey C., Burrell, Anthony K., Kubas, Gregory J. (2001) [TcCl(CS)(dppe)2]·C6H6. Acta Crystallographica Section E Structure Reports Online, 57 (1) doi:10.1107/s1600536800019486
In(2001, January) Acta Crystallographica Section E Structure Reports Online Vol. 57 (1) International Union of Crystallography (IUCr)
Abstract/NotesThe title compound, chlorobis[1,2-ethanediylbis(diphenylphosphine)-P,P′](thiocarbonyl-C)technetium benzene solvate, [TcCl(C46H42P4)(CS)]·C6H6, was obtained as one of two Tc-containing products isolated from the reaction between CS2and the electron-deficient complex [TcCl(dppe)2], where dppe is 1,2-ethanediylbis(diphenylphosphine). The structure exhibits an unusually short Tc—C distance [1.819 (6) Å], suggesting some multiple-bond character.


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