| Reference Type | Journal (article/letter/editorial) |
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| Title | Crystal structure and cation distribution in freibergite and tetrahedrite |
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| Journal | Mineralogical Magazine | ISSN | 0026-461X |
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| Authors | Peterson, R. C. | Author |
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| Miller, I. | Author |
| Year | 1986 (December) | Volume | 50 |
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| Issue | 358 |
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| Publisher | Mineralogical Society |
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| Download URL | https://rruff.info/doclib/MinMag/Volume_50/50-358-717.pdf+ |
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| DOI | doi:10.1180/minmag.1986.050.358.19Search in ResearchGate |
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| Generate Citation Formats |
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| Classification | Not set | LoC | Not set |
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| Mindat Ref. ID | 3918 | Long-form Identifier | mindat:1:5:3918:9 |
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| GUID | 0 |
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| Full Reference | Peterson, R. C., Miller, I. (1986) Crystal structure and cation distribution in freibergite and tetrahedrite. Mineralogical Magazine, 50 (358) 717-721 doi:10.1180/minmag.1986.050.358.19 |
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| Plain Text | Peterson, R. C., Miller, I. (1986) Crystal structure and cation distribution in freibergite and tetrahedrite. Mineralogical Magazine, 50 (358) 717-721 doi:10.1180/minmag.1986.050.358.19 |
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| In | (1986, December) Mineralogical Magazine Vol. 50 (358) Mineralogical Society |
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| Abstract/Notes | AbstractThe crystal structure of a freibergite (Ag-tetrahedrite) from Keno Hill, Yukon, Canada, and a tetrahedrite from Turquetil Lake, NWT, Canada, have been refined. The freibergite, Cu5.84Ag4.22Fe1.59Zn0.43 Sb4.10AS0.13S13, a = 10.610(2) Å, and the tetrahedrite, Cu10.24Fe1.03Zn0.97Ag0.05Sb3.66As0.28S13, a = 10.364(2) Å, were both refined in space group I4̄3m. The refinements confirm that Ag does occupy the threefold coordinated metal site as first described by Kalbskopf (1972) and that Fe also occupies this site. The structural changes accompanying Ag substitution are described and a model to explain the upper limit of substitution at four atoms of silver for thirteen atoms of sulphur is proposed. |
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