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Oberti, Roberta, Boiocchi, Massimo, Hawthorne, Frank C., Ball, Neil A., Martin, Robert F. (2019) Ferri-fluoro-katophorite from Bear Lake diggings, Bancroft area, Ontario, Canada: a new species of amphibole, ideally Na(NaCa)(Mg4Fe3+)(Si7Al)O22F2. Mineralogical Magazine, 83 (3) 413-417 doi:10.1180/mgm.2018.130

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Reference TypeJournal (article/letter/editorial)
TitleFerri-fluoro-katophorite from Bear Lake diggings, Bancroft area, Ontario, Canada: a new species of amphibole, ideally Na(NaCa)(Mg4Fe3+)(Si7Al)O22F2
JournalMineralogical Magazine
AuthorsOberti, RobertaAuthor
Boiocchi, MassimoAuthor
Hawthorne, Frank C.Author
Ball, Neil A.Author
Martin, Robert F.Author
Year2019 (June)Volume83
Issue3
PublisherMineralogical Society
DOIdoi:10.1180/mgm.2018.130Search in ResearchGate
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Mindat Ref. ID245142Long-form Identifiermindat:1:5:245142:2
GUID0
Full ReferenceOberti, Roberta, Boiocchi, Massimo, Hawthorne, Frank C., Ball, Neil A., Martin, Robert F. (2019) Ferri-fluoro-katophorite from Bear Lake diggings, Bancroft area, Ontario, Canada: a new species of amphibole, ideally Na(NaCa)(Mg4Fe3+)(Si7Al)O22F2. Mineralogical Magazine, 83 (3) 413-417 doi:10.1180/mgm.2018.130
Plain TextOberti, Roberta, Boiocchi, Massimo, Hawthorne, Frank C., Ball, Neil A., Martin, Robert F. (2019) Ferri-fluoro-katophorite from Bear Lake diggings, Bancroft area, Ontario, Canada: a new species of amphibole, ideally Na(NaCa)(Mg4Fe3+)(Si7Al)O22F2. Mineralogical Magazine, 83 (3) 413-417 doi:10.1180/mgm.2018.130
Abstract/NotesAbstractFerri-fluoro-katophorite is the second species characterised involving the rootname katophorite in the sodium–calcium subgroup of the amphibole supergroup. The mineral and its name were approved by the International Mineralogical Association Commission on New Minerals, Nomenclature and Classification, IMA2015-096. It was found in the Bear Lake diggings, Bancroft area, Ontario, Canada, where coarse euhedral crystals of amphibole, phlogopite, sanidine solid-solution (now coarsely exsolved to microcline perthite), titanite, augite, zircon and fluorapatite crystallised from a low-viscosity silicocarbonatitic magma of crustal origin. Greenish grey prismatic crystals of ferri-fluoro-katophorite generally protrude from the walls into a body of coarsely crystalline calcite, but they also occur away from the walls, completely enclosed by calcite. The empirical formula derived from electron microprobe analysis and single-crystal structure refinement is: A(Na0.55K0.32)Σ0.87B(Na0.79Ca1.18Mn2+0.03)Σ2.00C(Mg3.29Mn2+0.02Fe2+1.19Fe3+0.31Al0.09Ti4+0.08Li0.02)Σ5.00T(Si7.39Al0.61)Σ8.00O22W[F1.23 (OH)0.77]Σ2.00. Ferri-fluoro-katophorite is biaxial (–), with α = 1.640(2), β = 1.652(2), γ = 1.658(2), 2Vmeas. = 68.9(2)° and 2Vcalc.. = 70.1°. The unit-cell parameters are a = 9.887(3), b = 18.023(9), c = 5.292(2) Å, β = 104.66(3)°, V = 912.3(6) Å3, Z = 2 and space group C2/m. The strongest ten lines in the powder X-ray pattern [d values (in Å) I (hkl)] are: 2.708, 100, (151); 2.388, 74, (131); 3.139, 72, (310); 8.449, 69, (110); 2.540, 65, ($\bar{2}$02); 2.591, 53, (061); 2.739, 47, ($\bar{3}$31); 2.165, 45, (261); 3.279, 44, ($\bar{2}$40); 2.341, 43, ($\bar{3}$51).


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