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Bamforth, Tobias G.; Lampinen, Heta M.; Lynham, Leah; Reid, Nathan; Thorne, Robert; Iglesias-Martínez, Mario; Brugger, Joël; Cribb, Brad; Hazelden, Brett; Xia, Fang (2025) Unsupervised geochemical characterisation of deeply weathered terrains and regolith-hosted REE deposits: Rationale and benefits for exploration. Ore Geology Reviews, 181. 106634 doi:10.1016/j.oregeorev.2025.106634

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Reference TypeJournal (article/letter/editorial)
TitleUnsupervised geochemical characterisation of deeply weathered terrains and regolith-hosted REE deposits: Rationale and benefits for exploration
JournalOre Geology Reviews
AuthorsBamforth, Tobias G.Author
Lampinen, Heta M.Author
Lynham, LeahAuthor
Reid, NathanAuthor
Thorne, RobertAuthor
Iglesias-Martínez, MarioAuthor
Brugger, JoëlAuthor
Cribb, BradAuthor
Hazelden, BrettAuthor
Xia, FangAuthor
Year2025Volume<   181   >
Page(s)106634
URL
DOIdoi:10.1016/j.oregeorev.2025.106634Search in ResearchGate
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Mindat Ref. ID18364178Long-form Identifiermindat:1:5:18364178:0
GUID0
Full ReferenceBamforth, Tobias G.; Lampinen, Heta M.; Lynham, Leah; Reid, Nathan; Thorne, Robert; Iglesias-Martínez, Mario; Brugger, Joël; Cribb, Brad; Hazelden, Brett; Xia, Fang (2025) Unsupervised geochemical characterisation of deeply weathered terrains and regolith-hosted REE deposits: Rationale and benefits for exploration. Ore Geology Reviews, 181. 106634 doi:10.1016/j.oregeorev.2025.106634
Plain TextBamforth, Tobias G.; Lampinen, Heta M.; Lynham, Leah; Reid, Nathan; Thorne, Robert; Iglesias-Martínez, Mario; Brugger, Joël; Cribb, Brad; Hazelden, Brett; Xia, Fang (2025) Unsupervised geochemical characterisation of deeply weathered terrains and regolith-hosted REE deposits: Rationale and benefits for exploration. Ore Geology Reviews, 181. 106634 doi:10.1016/j.oregeorev.2025.106634
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Abstract/NotesThe accurate characterisation of regolith materials is crucial for mineral exploration, yet distinguishing visually indistinct clay-rich samples can be challenging and labour-intensive. This study conducts unsupervised k-means clustering and principal component analysis (PCA) on a geochemical dataset of over 3000 regolith samples from the Splinter Rock rare earth element (REE) prospect, Western Australia, to determine how unsupervised statistical methods may expedite the characterisation of regolith samples across large, buried and/or regolith-hosted ore deposits. K-means clustering identified five laterally consistent regolith horizons at Splinter Rock, which were manually interpreted into three REE-barren transported horizons and two mineralized saprolite-saprock horizons. The mineralogical and metallurgical features of all 3000 samples were then extrapolated from hyperspectral and metallurgical data of a select few reference samples within their clusters, to provide a preliminary understanding of the deposit’s overall structure and properties. Despite being a first-order approach, this method highlighted several consistent, statistically robust and previously unidentified patterns across the entire prospect: 1) the highest REE grades exist predominantly in the granitic saprolite and saprock; 2) relative to the light REEs (La–Sm), the heavy REEs (Eu–Lu) experience enrichment at the saprolite-saprock boundary and depletion with increasing depth in the saprock; 3) optimal metallurgical conditions occur near this saprolite-saprock interface; 4) relative accumulation of the economically- and environmentally-important ‘magnet’ REEs (MagREE, Pr, Nd, Tb, Dy) occurs mostly in the saprock; and 5) relative MagREE enrichment can be linked to the formation of negative Ce anomalies at lower stratigraphic positions. Lastly, PCA facilitated the development of tailored geochemical ratios to classify future samples into their appropriate horizons. This study highlights unsupervised statistical analysis of existing geochemical data as a robust, rapid and effective first-pass method for classifying and characterising extensive sets of regolith samples, as well as an efficient method of outlining deposit-scale trends and zones of consistent economic REE enrichment in large regolith-hosted deposits/prospects.

References Listed

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Not Yet Imported: - journal-article : 10.1111/j.2517-6161.1982.tb01195.x

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Bamforth, T.G., Hu, S., González-Álvarez, I., 2022. Developing geochemical exploration vectors through principal component analysis: a users guide by case study of the Woodlawn volcanogenic massive sulfide deposit, NSW. https://doi.org/10.25919/0xjn-wq15.
Not Yet Imported: - journal-article : 10.1071/SB9951107

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Not Yet Imported: - journal-article : 10.1111/j.1600-0587.2012.07348.x

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Eggleton, R.A., 2001. The regolith glossary, in: Surficial Geology, Soils, and Landscapes. Cooperative Research Centre for Landscape Evolution and Mineral Exploration.
Not Yet Imported: - book-chapter : 10.1029/GD002p0077

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Not Yet Imported: - journal-article : 10.1002/env.966

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Not Yet Imported: Solid Earth - journal-article : 10.5194/se-13-827-2022

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Not Yet Imported: - journal-article : 10.2307/2531893

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Mingyuan (1992) J. Nat. Resour. Distribution characteristics of the weathering crust-type rare earth resources in Nanling, China 7, 64
Pillans (2005) Geochronology of the Australian regolith , 41
Richardson (2018) Front Earth Sci (lausanne) Regolith Weathering and Sorption Influences Molybdenum, Vanadium, and Chromium Export via Stream Water at Four Granitoid Critical Zone Observatories 6
Not Yet Imported: - journal-article : 10.1016/j.heliyon.2021.e08581

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Not Yet Imported: - book-chapter : 10.5382/Rev.18.03

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Schodlok (2016) Aust. J. Earth Sci. HyLogger-3, a visible to shortwave and thermal infrared reflectance spectrometer system for drill core logging: functional description 63
Smithies (2015) Geol. Survey Western Australia Report Building the crust of the Albany-Fraser Orogen; constraints from granite geochemistry 150, 49
Trench (2024) Geosyst. Geoenviron. Australian critical metal exploration for analogues of Chinese ionic-clay REE deposits
Not Yet Imported: - journal-article : 10.1127/zfg/21/1977/379

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Map of Localities

Locality Pages

LocalityCitation Details
Splinter Rock deposit, Esperance Shire, Western Australia, Australia

Mineral Occurrences

LocalityMineral(s)
Splinter Rock deposit, Esperance Shire, Western Australia, Australia Florencite, Halloysite, Kaolinite, Monazite Group, Quartz, Rhabdophane, Saprolite, Smectite Group


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