| Reference Type | Journal (article/letter/editorial) |
|---|
| Title | Unsupervised geochemical characterisation of deeply weathered terrains and regolith-hosted REE deposits: Rationale and benefits for exploration |
|---|
| Journal | Ore Geology Reviews |
|---|
| Authors | Bamforth, Tobias G. | Author |
|---|
| Lampinen, Heta M. | Author |
| Lynham, Leah | Author |
| Reid, Nathan | Author |
| Thorne, Robert | Author |
| Iglesias-Martínez, Mario | Author |
| Brugger, Joël | Author |
| Cribb, Brad | Author |
| Hazelden, Brett | Author |
| Xia, Fang | Author |
| Year | 2025 | Volume | < 181 > |
|---|
| Page(s) | 106634 |
|---|
| URL | |
|---|
| DOI | doi:10.1016/j.oregeorev.2025.106634Search in ResearchGate |
|---|
| Generate Citation Formats |
| Classification | Not set | LoC | Not set |
|---|
| Mindat Ref. ID | 18364178 | Long-form Identifier | mindat:1:5:18364178:0 |
|---|
|
| GUID | 0 |
|---|
| Full Reference | Bamforth, Tobias G.; Lampinen, Heta M.; Lynham, Leah; Reid, Nathan; Thorne, Robert; Iglesias-Martínez, Mario; Brugger, Joël; Cribb, Brad; Hazelden, Brett; Xia, Fang (2025) Unsupervised geochemical characterisation of deeply weathered terrains and regolith-hosted REE deposits: Rationale and benefits for exploration. Ore Geology Reviews, 181. 106634 doi:10.1016/j.oregeorev.2025.106634 |
|---|
| Plain Text | Bamforth, Tobias G.; Lampinen, Heta M.; Lynham, Leah; Reid, Nathan; Thorne, Robert; Iglesias-Martínez, Mario; Brugger, Joël; Cribb, Brad; Hazelden, Brett; Xia, Fang (2025) Unsupervised geochemical characterisation of deeply weathered terrains and regolith-hosted REE deposits: Rationale and benefits for exploration. Ore Geology Reviews, 181. 106634 doi:10.1016/j.oregeorev.2025.106634 |
|---|
| In | Link this record to the correct parent record (if possible) |
|---|
| Abstract/Notes | The accurate characterisation of regolith materials is crucial for mineral exploration, yet distinguishing visually indistinct clay-rich samples can be challenging and labour-intensive. This study conducts unsupervised k-means clustering and principal component analysis (PCA) on a geochemical dataset of over 3000 regolith samples from the Splinter Rock rare earth element (REE) prospect, Western Australia, to determine how unsupervised statistical methods may expedite the characterisation of regolith samples across large, buried and/or regolith-hosted ore deposits. K-means clustering identified five laterally consistent regolith horizons at Splinter Rock, which were manually interpreted into three REE-barren transported horizons and two mineralized saprolite-saprock horizons. The mineralogical and metallurgical features of all 3000 samples were then extrapolated from hyperspectral and metallurgical data of a select few reference samples within their clusters, to provide a preliminary understanding of the deposit’s overall structure and properties. Despite being a first-order approach, this method highlighted several consistent, statistically robust and previously unidentified patterns across the entire prospect: 1) the highest REE grades exist predominantly in the granitic saprolite and saprock; 2) relative to the light REEs (La–Sm), the heavy REEs (Eu–Lu) experience enrichment at the saprolite-saprock boundary and depletion with increasing depth in the saprock; 3) optimal metallurgical conditions occur near this saprolite-saprock interface; 4) relative accumulation of the economically- and environmentally-important ‘magnet’ REEs (MagREE, Pr, Nd, Tb, Dy) occurs mostly in the saprock; and 5) relative MagREE enrichment can be linked to the formation of negative Ce anomalies at lower stratigraphic positions. Lastly, PCA facilitated the development of tailored geochemical ratios to classify future samples into their appropriate horizons. This study highlights unsupervised statistical analysis of existing geochemical data as a robust, rapid and effective first-pass method for classifying and characterising extensive sets of regolith samples, as well as an efficient method of outlining deposit-scale trends and zones of consistent economic REE enrichment in large regolith-hosted deposits/prospects. |
|---|
These are the references the publisher has listed as being connected to the article. Please check the article itself for the full list of references which may differ. Not all references are currently linkable within the Digital Library.
| Not Yet Imported: - journal-article : 10.1111/j.2517-6161.1982.tb01195.x
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
 | |
 | |
 | |
 | |
 | |
 | |
 | |
| Bamforth, T.G., Hu, S., González-Álvarez, I., 2022. Developing geochemical exploration vectors through principal component analysis: a users guide by case study of the Woodlawn volcanogenic massive sulfide deposit, NSW. https://doi.org/10.25919/0xjn-wq15. |
 | Bamforth, Tobias G., Xia, Fang, Putnis, Andrew, Brugger, Joël, Hu, Si-Yu, Roberts, Malcolm P., Suvorova, Alexandra, Pring, Allan (2024) Hydrothermal mineral replacement in the apatite-rhabdophane-monazite system: Experiments, reaction mechanisms and geological implications. Chemical Geology, 666. doi:10.1016/j.chemgeo.2024.122307 |
 | Bamforth, Tobias G., Xia, Fang, Tiddy, Caroline J., González-Álvarez, Ignacio, Brugger, Joël, Hu, Si-Yu, Schoneveld, Louise E., Pearce, Mark A., Putnis, Andrew (2024) High-Grade REE accumulation in regolith: Insights from supergene alteration of an apatite-rich vein at the Kapunda Cu mine, South Australia. Mineralium Deposita, 59 (7). doi:10.1007/s00126-024-01283-2 |
 | |
 | |
 | |
 | Berger, Alfons, Janots, Emilie, Gnos, Edwin, Frei, Robert, Bernier, Felix (2014) Rare earth element mineralogy and geochemistry in a laterite profile from Madagascar. Applied Geochemistry, 41. 218-228 doi:10.1016/j.apgeochem.2013.12.013 |
 | Berman, Mark, Bischof, Leanne, Lagerstrom, Ryan, Guo, Yi, Huntington, Jon, Mason, Peter, Green, Andrew A. (2017) A Comparison Between Three Sparse Unmixing Algorithms Using a Large Library of Shortwave Infrared Mineral Spectra. IEEE Transactions on Geoscience and Remote Sensing, 55 (6) 3588-3610 doi:10.1109/tgrs.2017.2676816 |
 | |
 | |
 | |
 | Braun, Jean-Jacques, Pagel, Maurice, Muller, Jean-Pierre, Bilong, Paul, Michard, Annie, Guillet, Bernard (1990) Cerium anomalies in lateritic profiles. Geochimica et Cosmochimica Acta, 54 (3) 781-795 doi:10.1016/0016-7037(90)90373-s |
 | |
 | |
| Not Yet Imported: - journal-article : 10.1071/SB9951107
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
 | |
 | Caruso, Alicia S., Clarke, Kenneth D., Tiddy, Caroline J., Delean, Steven, Lewis, Megan M. (2018) Objective Regolith-Landform Mapping in a Regolith Dominated Terrain to Inform Mineral Exploration. Geosciences, 8 (9) 318 doi:10.3390/geosciences8090318 |
 | |
 | |
 | |
 | |
 | |
 | |
| Not Yet Imported: - journal-article : 10.1111/j.1600-0587.2012.07348.x
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
 | |
| Eggleton, R.A., 2001. The regolith glossary, in: Surficial Geology, Soils, and Landscapes. Cooperative Research Centre for Landscape Evolution and Mineral Exploration. |
| Not Yet Imported: - book-chapter : 10.1029/GD002p0077
If you would like this item imported into the Digital Library, please contact us quoting Book ID 0875905110 |
 | |
 | Fandeur, Dik, Juillot, Farid, Morin, Guillaume, Olivi, Luca, Cognigni, Andrea, Webb, Samuel M., Ambrosi, Jean-Paul, Fritsch, Emmanuel, Guyot, François, Brown, Jr., Gordon E. (2009) XANES Evidence for Oxidation of Cr(III) to Cr(VI) by Mn-Oxides in a Lateritic Regolith Developed on Serpentinized Ultramafic Rocks of New Caledonia. Environmental Science & Technology, 43 (19). 7384-7390 doi:10.1021/es900498r |
| Not Yet Imported: - journal-article : 10.1002/env.966
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
 | Fu, Wei, Li, Xiaoting, Feng, Yangyang, Feng, Meng, Peng, Zhao, Yu, Hongxia, Lin, Henry (2019) Chemical weathering of S-type granite and formation of Rare Earth Element (REE)-rich regolith in South China: Critical control of lithology. Chemical Geology, 520. 33-51 doi:10.1016/j.chemgeo.2019.05.006 |
 | |
 | |
 | |
 | Gong, Qingjie, Deng, Jun, Wang, Changming, Wang, Zhongliang, Zhou, Liangzhuang (2013) Element behaviors due to rock weathering and its implication to geochemical anomaly recognition: A case study on Linglong biotite granite in Jiaodong peninsula, China. Journal of Geochemical Exploration, 128. 14-24 doi:10.1016/j.gexplo.2013.01.004 |
 | |
 | |
 | |
 | |
 | |
 | |
 | |
 | Ichimura, Koji, Sanematsu, Kenzo, Kon, Yoshiaki, Takagi, Tetsuichi, Murakami, Takashi (2020) REE redistributions during granite weathering: Implications for Ce anomaly as a proxy for paleoredox states. American Mineralogist, 105 (6). 848-859 doi:10.2138/am-2020-7148 |
 | |
 | |
 | |
 | |
 | |
 | |
| Not Yet Imported: Solid Earth - journal-article : 10.5194/se-13-827-2022
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
 | |
 | Kirkland, C.L., Spaggiari, C.V., Pawley, M.J., Wingate, M.T.D., Smithies, R.H., Howard, H.M., Tyler, I.M., Belousova, E.A., Poujol, M. (2011) On the edge: U–Pb, Lu–Hf, and Sm–Nd data suggests reworking of the Yilgarn craton margin during formation of the Albany-Fraser Orogen. Precambrian Research, 187 (3) 223-247 doi:10.1016/j.precamres.2011.03.002 |
| Not Yet Imported: - journal-article : 10.2307/2531893
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
 | Laukamp, Carsten, Rodger, Andrew, LeGras, Monica, Lampinen, Heta, Lau, Ian C., Pejcic, Bobby, Stromberg, Jessica, Francis, Neil, Ramanaidou, Erick (2021) Mineral Physicochemistry Underlying Feature-Based Extraction of Mineral Abundance and Composition from Shortwave, Mid and Thermal Infrared Reflectance Spectra. Minerals, 11 (4) 347 doi:10.3390/min11040347 |
 | |
 | |
 | |
 | Liu, Wenjing, Li, Yuanchuan, Wang, Xuan, Cui, Lifeng, Zhao, Zhiqi, Liu, Congqiang, Xu, Zhifang (2022) Weathering stage and topographic control on rare earth element (REE) behavior: New constraints from a deeply weathered granite hill. Chemical Geology, 610. 121066 doi:10.1016/j.chemgeo.2022.121066 |
 | Liu, Wenjing, Liu, Congqiang, Brantley, Susan L., Xu, Zhifang, Zhao, Tong, Liu, Taoze, Yu, Chong, Xue, Dingshuai, Zhao, Zhiqi, Cui, Lifeng, Zhang, Zhuojun, Fan, Bailin, Gu, Xin (2016) Deep weathering along a granite ridgeline in a subtropical climate. Chemical Geology, 427. 17-34 doi:10.1016/j.chemgeo.2016.02.014 |
 | |
 | Metelka, Václav, Baratoux, Lenka, Jessell, Mark W., Barth, Andreas, Ježek, Josef, Naba, Séta (2018) Automated regolith landform mapping using airborne geophysics and remote sensing data, Burkina Faso, West Africa. Remote Sensing of Environment, 204. 964-978 doi:10.1016/j.rse.2017.08.004 |
 | |
| Mingyuan (1992) J. Nat. Resour. Distribution characteristics of the weathering crust-type rare earth resources in Nanling, China 7, 64 |
 | |
 | |
 | |
 | |
 | |
| Pillans (2005) Geochronology of the Australian regolith , 41 |
 | |
 | Ram, Rahul, Becker, Megan, Brugger, Joël, Etschmann, Barbara, Burcher-Jones, Cody, Howard, Daryl, Kooyman, Patricia J., Petersen, Jochen (2019) Characterisation of a rare earth element- and zirconium-bearing ion-adsorption clay deposit in Madagascar. Chemical Geology, 522. 93-107 doi:10.1016/j.chemgeo.2019.05.011 |
| Richardson (2018) Front Earth Sci (lausanne) Regolith Weathering and Sorption Influences Molybdenum, Vanadium, and Chromium Export via Stream Water at Four Granitoid Critical Zone Observatories 6 |
 | |
| Not Yet Imported: - journal-article : 10.1016/j.heliyon.2021.e08581
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
 | |
 | |
 | |
 | |
 | Sanematsu, Kenzo, Kon, Yoshiaki, Imai, Akira, Watanabe, Koichiro, Watanabe, Yasushi (2013) Geochemical and mineralogical characteristics of ion-adsorption type REE mineralization in Phuket, Thailand. Mineralium Deposita, 48 (4) 437-451 doi:10.1007/s00126-011-0380-5 |
| Not Yet Imported: - book-chapter : 10.5382/Rev.18.03
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
 | |
| Schodlok (2016) Aust. J. Earth Sci. HyLogger-3, a visible to shortwave and thermal infrared reflectance spectrometer system for drill core logging: functional description 63 |
 | |
 | |
 | |
| Smithies (2015) Geol. Survey Western Australia Report Building the crust of the Albany-Fraser Orogen; constraints from granite geochemistry 150, 49 |
 | |
 | |
| Trench (2024) Geosyst. Geoenviron. Australian critical metal exploration for analogues of Chinese ionic-clay REE deposits |
 | |
 | |
| Not Yet Imported: - journal-article : 10.1127/zfg/21/1977/379
If you would like this item imported into the Digital Library, please contact us quoting Journal ID |
 | Wilford, J.R., Searle, R., Thomas, M., Pagendam, D., Grundy, M.J. (2016) A regolith depth map of the Australian continent. Geoderma, 266. 1-13 doi:10.1016/j.geoderma.2015.11.033 |
 | |
 | |
 | Yang, Meijun, Liang, Xiaoliang, Ma, Lingya, Huang, Jian, He, Hongping, Zhu, Jianxi (2019) Adsorption of REEs on kaolinite and halloysite: A link to the REE distribution on clays in the weathering crust of granite. Chemical Geology, 525. 210-217 doi:10.1016/j.chemgeo.2019.07.024 |
 | |
 | |
 | |
These are possibly similar items as determined by title/reference text matching only.