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Guthrie, J. Peter, Cossar, John, Klym, Alex (1984) Halogenation of acetone. A method for determining pKas of ketones in aqueous solution, with an examination of the thermodynamics and kinetics of alkaline halogenation and a discussion of the best value for the rate constant for a diffusion-controlled reaction. Energetic requirements for a diffusion-controlled reaction involving heavy-atom bond formation. Journal Of The American Chemical Society, 106 (5) 1351-1360 doi:10.1021/ja00317a030

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Reference TypeJournal (article/letter/editorial)
TitleHalogenation of acetone. A method for determining pKas of ketones in aqueous solution, with an examination of the thermodynamics and kinetics of alkaline halogenation and a discussion of the best value for the rate constant for a diffusion-controlled reaction. Energetic requirements for a diffusion-controlled reaction involving heavy-atom bond formation
JournalJournal Of The American Chemical Society
AuthorsGuthrie, J. PeterAuthor
Cossar, JohnAuthor
Klym, AlexAuthor
Year1984 (March)Volume106
Issue5
PublisherAmerican Chemical Society (ACS)
DOIdoi:10.1021/ja00317a030Search in ResearchGate
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Mindat Ref. ID1398516Long-form Identifiermindat:1:5:1398516:7
GUID0
Full ReferenceGuthrie, J. Peter, Cossar, John, Klym, Alex (1984) Halogenation of acetone. A method for determining pKas of ketones in aqueous solution, with an examination of the thermodynamics and kinetics of alkaline halogenation and a discussion of the best value for the rate constant for a diffusion-controlled reaction. Energetic requirements for a diffusion-controlled reaction involving heavy-atom bond formation. Journal Of The American Chemical Society, 106 (5) 1351-1360 doi:10.1021/ja00317a030
Plain TextGuthrie, J. Peter, Cossar, John, Klym, Alex (1984) Halogenation of acetone. A method for determining pKas of ketones in aqueous solution, with an examination of the thermodynamics and kinetics of alkaline halogenation and a discussion of the best value for the rate constant for a diffusion-controlled reaction. Energetic requirements for a diffusion-controlled reaction involving heavy-atom bond formation. Journal Of The American Chemical Society, 106 (5) 1351-1360 doi:10.1021/ja00317a030
In(1984, March) Journal Of The American Chemical Society Vol. 106 (5) American Chemical Society (ACS)

See Also

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GUTHRIE, J. P., COSSAR, J., KLYM, A. (1984) ChemInform Abstract: HALOGENATION OF ACETONE. A METHOD FOR DETERMINING PKAS OF KETONES IN AQUEOUS SOLUTION, WITH AN EXAMINATION OF THE THERMODYNAMICS AND KINETICS OF ALKALINE HALOGENATION AND A DISCUSSION OF THE BEST VALUE FOR THE RATE CONSTANT FOR A DIFF. Chemischer Informationsdienst, 15 (24) doi:10.1002/chin.198424079
Guthrie, J. Peter, Cossar, John, Klym, Alex (1982) The pKa of acetone: a kinetic method for determining the pKas of ketones in aqueous solution. Journal Of The American Chemical Society, 104 (3) 895-896 doi:10.1021/ja00367a061
GUTHRIE, J. P., COSSAR, J., KLYM, A. (1982) ChemInform Abstract: THE PKA OF ACETONE: A KINETIC METHOD FOR DETERMINING THE PKAS OF KETONES IN AQUEOUS SOLUTION. Chemischer Informationsdienst, 13 (21) doi:10.1002/chin.198221135
Guthrie, J. Peter, Cossar, John, Klym, Alex (1987) pKa values for substituted acetophenones: values determined by study of rates of halogenation. Canadian Journal of Chemistry, 65 (9). 2154-2159 doi:10.1139/v87-360
Richard, John P., Tsuji, Yutaka (2000) Dynamics for Reaction of an Ion Pair in Aqueous Solution:  The Rate Constant for Ion Pair Reorganization. Journal Of The American Chemical Society, 122 (16) 3963-3964 doi:10.1021/ja994453j
Guthrie, J. Peter (1980) Free energy of formation of sulfur trioxide in aqueous solution. Methods for determining the energy level of an unobservable intermediate. Journal Of The American Chemical Society, 102 (16) 5177-5180 doi:10.1021/ja00536a008
Guthrie, J. Peter (1991) Concerted mechanism for alcoholysis of esters: an examination of the requirements. Journal Of The American Chemical Society, 113 (10) 3941-3949 doi:10.1021/ja00010a040
Olea, Andres F., Thomas, J. K. (1988) Rate constants for reactions in viscous media: correlation between the viscosity of the solvent and the rate constant of the diffusion-controlled reactions. Journal Of The American Chemical Society, 110 (14) 4494-4502 doi:10.1021/ja00222a002
Deutch, J. M. (1980) A simple method for determining the mean passage time for diffusion controlled processes. The Journal of Chemical Physics, 73 (9) 4700-4701 doi:10.1063/1.440666
Guthrie, J. Peter (1974) The Aldol Condensation of Acetaldehyde: the Equilibrium Constant for the Reaction and the Rate Constant for the Hydroxide Catalyzed RetroAldol Reaction. Canadian Journal of Chemistry, 52 (11). 2037-2040 doi:10.1139/v74-294
Chiles, Richard A., Rossky, Peter J. (1984) Evaluation of reaction free energy surfaces in aqueous solution: an integral equation approach. Journal Of The American Chemical Society, 106 (22) 6867-6868 doi:10.1021/ja00334a080
 
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