Gurzhiy, Vladislav V., Tyumentseva, Olga S., Krivovichev, Sergey V., Tananaev, Ivan G. (2018) Cyclic polyamines as templates for novel complex topologies in uranyl sulfates and selenates. Zeitschrift für Kristallographie - Crystalline Materials, 233 (3) 233-245 doi:10.1515/zkri-2017-2129
Reference Type | Journal (article/letter/editorial) | ||
---|---|---|---|
Title | Cyclic polyamines as templates for novel complex topologies in uranyl sulfates and selenates | ||
Journal | Zeitschrift für Kristallographie - Crystalline Materials | ||
Authors | Gurzhiy, Vladislav V. | Author | |
Tyumentseva, Olga S. | Author | ||
Krivovichev, Sergey V. | Author | ||
Tananaev, Ivan G. | Author | ||
Year | 2018 (March 28) | Volume | 233 |
Page(s) | 233-245 | Issue | 3 |
Publisher | Walter de Gruyter GmbH | ||
DOI | doi:10.1515/zkri-2017-2129Search in ResearchGate | ||
Mindat Ref. ID | 118100 | Long-form Identifier | mindat:1:5:118100:9 |
GUID | d65d55a6-cf0f-4d39-a0d3-f4b03928d9f5 | ||
Full Reference | Gurzhiy, Vladislav V., Tyumentseva, Olga S., Krivovichev, Sergey V., Tananaev, Ivan G. (2018) Cyclic polyamines as templates for novel complex topologies in uranyl sulfates and selenates. Zeitschrift für Kristallographie - Crystalline Materials, 233 (3) 233-245 doi:10.1515/zkri-2017-2129 | ||
Plain Text | Gurzhiy, Vladislav V., Tyumentseva, Olga S., Krivovichev, Sergey V., Tananaev, Ivan G. (2018) Cyclic polyamines as templates for novel complex topologies in uranyl sulfates and selenates. Zeitschrift für Kristallographie - Crystalline Materials, 233 (3) 233-245 doi:10.1515/zkri-2017-2129 | ||
In | (2018, March) Zeitschrift für Kristallographie - Crystalline Materials Vol. 233 (3) Walter de Gruyter GmbH | ||
Abstract/Notes | AbstractSingle crystals of two novel uranyl sulfates and two novel uranyl selenates with protonated cyclen and 3-aminotropane molecules, ((C8H24N4)[(UO2)3(SO4)5](H2O)3(I), (C8H24N4)(H5O2)(H3O)[(UO2)4(SeO4)7(H2O)](H2O)6.6(II), (C8H18N2)(H5O2)(H3O)[(UO2)3(SO4)5(H2O)](H2O)0.5(III), and (C8H18N2)(H5O2)(H3O)[(UO2)3(SeO4)5(H2O)](H2O)2(IV) have been prepared by isothermal evaporation from aqueous solutions and structurally characterized. Uranyl-containing 2D units have been investigated using topological approach and information-based complexity measures demonstrating that complex topologies form more rare than their simplest counterparts, which is a response of the crystal structure to changes of chemical conditions within the system. |
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