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Identity HelpChalcocite versus digenite

15th Oct 2014 14:46 UTCBill Cordua 🌟 Expert OP

I'm going through a batch of specimens collected years ago from the Flambeau Copper Mine in Wisconsin. Chalcocite, digenite and djurleite were all reported from there by mine site geologists. Any thoughts on how to tell them apart in hand sample without chemical or XRD analysis? I gather digenite has a cleavage and the others do not. Anything else useful? Thanks!

15th Oct 2014 15:44 UTCWilliam C. van Laer Expert

Bill: These three copper sulfides were all prominent in the Butte ore deposits, but they are not easy to tell apart in hand sample.....digenite tends to be dark gray and has a fairly good, almost pitchy luster on a freshly broken surface, plus the fracture is similar to quartz. Chalcocite tends to be dull gray with a dull luster, earthy fracture and often exhibits a "sooty" coating upon exposure....rubbing the sample should yield a black powder. Djurleite often goes unrecognized for what it is; it is colored a more silvery hue and has a submetallic luster. Unless you have reasonable crystals of these minerals, they are tough to distinguish, but digenite is the most easily recognized.

15th Oct 2014 17:47 UTCPeter Haas

Chalcocite is often superficially altered into bornite, djurleite or digenite. In addition, all those minerals can occur as pseudomorphs after each other ...

15th Oct 2014 19:12 UTCPaul Brandes 🌟 Manager

Unless you have large enough specimens to conduct other diagnostic testing, the only way to tell them apart for sure is by XRD and even then it's not always easy.....

16th Oct 2014 13:01 UTCBill Cordua 🌟 Expert OP

Thanks for the good input. I can see it's a tough problem. Appreciate the help!
 
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