 | | Journal (article/letter/editorial) | | TYPES IN SAPONITE AND VERMICULITE: A REVIEW HELENE SUQUET AND HENRI PEZERAT Laboratoire de Reactivite de...Marie Curie 4 Place Jussieu, 75252 Paris Cedex 05 France Abstract-Saponites and vermiculites may assurne...were synthesized under hydrothermal conditions (Suquet et al. , 1977). The synthetic clays are called... Sr, and Ba) are listed in Tables 2, 3, 353 Suquet and Pezerat 354 Clays and Clay Minerals Table...Vermiculite, Malawi, Nyasaland 2 Vermiculite, Prayssac, France 3 Vermiculite, Benahavis, Spain Saponite, Kozakov |  | | Journal (article/letter/editorial) | | K-bentonite 83 K-diffusion during, in adularia, muscovite 498 muscovite, K-diffusion during 498 shales, Salton...Alterations in the Granitic Cupola of Montebras, Creuse, France 505 BEAUFORT, D. (with F. RASSINEAUX,A. BOUCHET...and Tosudite from Echassi6res, Massif Central, France 39 BOUCHET, A. (with F. RASSINEAUX,D. BEAUFORT...dolomite weathering residua 448 muscovite 498 muscovite vein in Mn wad 448 muscovite, K-diffusion in 498 saponite...Classification of Trioetahedral 2:1 Phyllosilieates, by H. Suquet and H. Przerat 184 Compaction pressure effect of |  | | Journal (article/letter/editorial) | | PROPERTIES OF SAPONITES WITH INCREASING LAYER CHARGE H. SUQUET, J. T. IIYAMA*, H. KODAMAt and H . PEZERAT Laboratoire...Curie, 4 Place Jussieu, 75230, Paris Cedex 05, France . (R eceived 14 October 1976; and in final form...S., rue de la Ferollerie, 45045 Orleans Cedex, France. Permanent address: Geological Institute, Ex perimental...synthesis were prepared according 231 232 H. SUQUET, 1. T. IIYAMA, H. to the usual method from...published in Suquet et al. (1975). (3) Saponite from Kozakov, Czechoslovakia; x = 0.45; Suquet et al. (1975) |  | | Journal (article/letter/editorial) | | resulting in a basal spacing of approximately 12.5 A (Suquet et aI., 1975). The objective of this investigation...focused on Na-saponites (Koizumi and Roy, 1959; Suquet et aI., 1977; Iwasaki et al., 1989) and on their...various other cations in the interlayer region (Suquet et aI., 1977; 1981a, 1981b, 1982, 1987). Recently...The data will be compared with those reported by Suquet et al. (1975, 1981a, 1981b), who exchanged Nasaponite...the values reported in various articles (e.g. , Suquet et aI., 1981a, 1981 b), and varies between 9. I |  | | Journal (article/letter/editorial) | | Cristalline lmparfaite, C.N .R.S. 45045 Orleans CEDEX, France (Received 6 September 1977) Abstract-Using a simple...Brindley, 1%6; Pedro, 1967). This pansion. However, Suquet et al. (1977) have syntheappears to be a very natural...makes it very difficult to expand them. Thirdly, muscovite and biotite have the same layer charge but the...charges may be similar or identical. More recently, Suquet et al. (1977) have observed such streaks in high-charge...respectively. These are much smaller than for muscovite (32.2 kcal/mole) and phlogopite (22.4 kcallmole |  | Raimbault, Louis, Cuney, Michel, Azencott, Claude, Duthou, Jean-Louis, Joron, Jean Louis (1995) Geochemical evidence for a multistage magmatic genesis of Ta-Sn-Li mineralization in the granite at Beauvoir, French Massif Central. Economic Geology, 90 (3) 548-576 doi:10.2113/gsecongeo.90.3.548 | Journal (article/letter/editorial) | | 35 rue SaintHonord, F-77305Fontainebleau Cedex, France,andLaboratoire PierreSiie,Groupe desSciences dela...surYvetteCedex, France MICHEL CUNEY, CREGUandGS CNRS-CREGU, B.P.23, F-54501Vandoeuvre lesNancyCedex,France CLAUDE...Nucldaires de Saclay, B.P.2, F-91191Gif surYvetteCedex, France JEANLOUISDUTHOU, Ddpartement de Gdologie et Mindralogie...ClermontII, 5 rueKessler, F-63038ClermontFerrandCedex,France ANDJEANLOUISJORON Laboratoire PierreSiie,GroupedesSciences...Nucldaires de Saclay,B.P.2, F-91191Gif surYvetteCedex,France Abstract The Beauvoir raremetalgranite,at the |  | | Journal (article/letter/editorial) | | Chimie des Mindraux, C.N.R.S., 45045 Orldans Cedex (France) =Groupe de Recherche GARNAC, Service du Cyclotron...Cyclotron, C.N.R.S., 45045 Orldans Cedex (France) (Received September 16, 1982; revised and accepted January...1979). In the case of dioctahedral micas, such as muscovite, Li ÷ may occur in these two positions; a fraction...Li ÷ must be hydrated, as it is in clays (Suquet, 1978; Suquet et al., 1982). Then, a lithian eastonite...expansion of the interlayer, as observed in smectites (Suquet, 1978); the contrary is observed in the present |  | | Journal (article/letter/editorial) | | Hydrothermal conversion of muscovite-zM, to a K-poor, Si-rich muscovite-2M, and formation of chlorite...chlorite from solution and by replacementof altered muscovite was proposed.The quartz chlorite schist examined...electronmrcroscope[100]imageof 2M,low K, high Si muscovite; (b) selected-areaelecfon diffractionpattem showingtwo...characterizedby high Si:Al ratios compared with ideal muscovite and l-5%o Mg and Fe. Careful examination of a...layers. Probably, Mg and Fe are incorporatedin the muscovite structure. Image simulations (Fig. 3) show that |  | Lantenois, Sébastien, Lanson, Bruno, Muller, Fabrice, Bauer, Andreas, Jullien, Michel, Plançon, Alain (2005) Experimental study of smectite interaction with metal Fe at low temperature: 1. Smectite destabilization. clays and clay minerals, 53 (6) 597-612 doi:10.1346/ccmn.2005.0530606 | Journal (article/letter/editorial) | | rue de la FeÂrollerie, 45071 OrleÂans Cedex 2, France 2 Environmental Geochemistry Group, LGIT, Maison...Fourier ÿ CNRS, BP 53, 38041 Grenoble Cedex 9, France 3 Institut fuÈr Nukleare Entsorgung, Forschungzentrum...l'Environnement, Bat 307, 13108 Saint Paul Lez Durance Cedex, France 1 ÐInteraction between metal Fe and a variety...for 1 month at an estimated pressure of 100 MPa (Suquet ., 1977). The SbS-1 beidellite was synthesized...2+-saturated smectites varies from 18.6 to+ 19.2 AÊ (Suquet, 1978). The 001 basal spacing of Na -saturated |  | | Journal (article/letter/editorial) | | 40, avenue du recteur Pineau, 86022 Poitiers, France Bnucn Vpr,on Laboratoire de g6ologie,URA l316...Sup6rieure,24, rue Lhomortd,75230 Paris c6dex05, France Ansrucr Chemographic analysis of suites of I/S...and this appearsto be a function (de la Calle and Suquet,1988). INrnoouctloN 0003404x/89/0910-1l 06$02...position. As an example, the coordinates of an ideal muscovite (Si.Al)O,oAlr(OH)rK are calculated as follows:...diageneticseries Taele 1. Coordinatesof ideal muscovite,high-chargeand low-chargebeidellites,and montmorillonites |  | | Journal (article/letter/editorial) | | 1B, Rue de la Ftrollede, 45045 Orltans, Cedex, France Abstract--Integrated intensities of the fundamental...Greene-Kelly (1953, 1955), e = Guedon (1963), f = Suquet (1978). 5 r is the excess positive charge of the...alternating sheets with different compositions. For SK, Suquet et al. (1977) observed two swelling distances for...Glaeser for the Rupsroth beideUite, and Dr. H. Suquet for the K o z a k o v saponite and the Santa Olalla...121-142. Gatineau, L. (1964) Structure r~elle de la muscovite. Rtpartition des substitutions isomorphes: Bull |  | | Journal (article/letter/editorial) | | vermiculite (Vali & Koster, 1986; de la Calle & Suquet, 1988). These discrepancies can be resolved with...T H O D S Jefferson vermiculite from Brinton's Quarry, Pennsylvania, a weathering product of biotite...alkylammonium treatment; (b) similar treatment of muscovite, phlogopite and biotite did not produce the fine-grained...Clays Clay Miner. 36, 47-60. C alle C. de la & Suquet H. (1988) Vermiculite. Pp. 4 5 5 ^ 9 6 in: Hydrous |  | | Journal (article/letter/editorial) | | the octahedral sheet. Leonard and Weed (1967), Suquet et al. (1975), and Eirish and Tret'yakova (1970)...contribution of K., radiation, it is often * Muscovite, East Morris, C,onnecticut. difficult to clearly...caption for reffrom the (331) reflection. For a 2M, muscovite structure, erences),measuredabsorption frequenciesfrom... K-O,""".: 3.530 - 0.00602' R'z:0.72. (3) muscovite Using the appropriate IR and XRD measurementsfor...of micas showsgood agreementin some cases(e.g.,muscovite) and considerabledifferencesin other cases(e.9 |  | | Journal (article/letter/editorial) | | Group, LG,LT., RP. 53, F-38041 Grenoble Cedex 9, France Ahstract-Three methods were developed that allow...1: 1000, or 1:2000 by volume. A small disc of muscovite was taped with double-sided tape to a similarlyshaped...immersed in the 575 suspension for -30 s. The muscovite was then rinsed with a stream of deionized water...dismembrator set at -150 Watts. The dried PEI-coated muscovite was immersed in the clay suspension for 1 min...coated muscovite sample, and [ Si is the intensity of the Si 2p XPS peak for an uncoated muscovite sample |  | | Journal (article/letter/editorial) | | Grauby et al. 1994a, 1994b; Vogels et al. 1997). Suquet et al. (1977) and Whitney (1983) synthesized saponites...broad band. * Na-exchanged Kozakov (Mg)-saponite (Suquet et al. 1975). † Nemecz (1981). 938 VOGELS ET...CHARACTERIZATION OF SAPONITE in the literature (Suquet et al. 1975; Decarreau 1983; Kloprogge et al. 1993)...by Al3+ in the octahedral sheet, as suggested by Suquet et al. (1981a, 1981b). The charge deficiency caused...layer charge seems to increase, which favors the (muscovite) substitution 3Mg2+ ↔ 2Al3+ + vacancy, creating |  | He, H., Li, T., Tao, Q., Chen, T., Zhang, D., Zhu, J., Yuan, P., Zhu, R. (2014) Aluminum ion occupancy in the structure of synthetic saponites: Effect on crystallinity. American Mineralogist, 99 (1) 109-116 doi:10.2138/am.2014.4543 | Journal (article/letter/editorial) | | cation exchange capacity (CEC). For example, a muscovite substitution in the octahedral sheet (Vogels et...Mg2+) substitution will create a positive charge (Suquet et al. 1981). The latter compensates a negative...temperature (Kloprogge et al. 1994a 1994b). A muscovite substitution (2Al3+ + vacancy → 3Mg2+) was proposed...different from the model (1 Al3+ → 1 Mg2+) suggested by Suquet et al. (1981). These findings are helpful for understanding...Mg2+ in the octahedral sheet, i.e., 1Al3+ → 1Mg2+ (Suquet et al. 1981) and 2Al3+ + vacancy → 3Mg2+ (Vogels |  | Alba, M. D., Castro, M. A., Chain, P., Naranjo, M., Perdigón, A. C. (2005) Structural study of synthetic mica–montmorillonite by means of 2D MAS NMR experiments. Physics and Chemistry of Minerals, 32 (4) 248-254 doi:10.1007/s00269-005-0457-8 | Journal (article/letter/editorial) | | parameters of the interstratification (de la Calle and Suquet 1988; Pons et al. 1989), not many studies are devoted...infrared spectrum is broadly similar to that of 1 muscovite and contains bands due to NH+ 4 (1342 cm 1 and...the different silicon environments of a typical muscovite and a beidellite are shown in the upper diagram...octahedral sheet of the mineral—in the beidellite and muscovite layers—, the position of the signal being compatible...society. Clay Minerals Group, London de la Calle C, Suquet H (1988) in Reviews in mineralogy, vol 19 Hydrous |  | | Journal (article/letter/editorial) | | amorphization, which occurs by overgrinding asbestos (Suquet 1989), acetone was used as dispersing liquid because...the Italian beamline BM8 GILDA at ESRF (Grenoble, France) with a Debye–Scherrer setup suitable for kinetic...postulated for the dehydroxylation reaction of muscovite (Mazzucato et al. 1999). In that case, the reaction...AF (1999) High-temperature dehydroxylation of muscovite-2M1: a kinetic study by in situ XRPD. Phys Chem...magnetic structures. J Appl Crystallogr 2: 65–71 Suquet H (1989) Effects of dry grinding and leaching on |  | | Journal (article/letter/editorial) | | calcium. The term "illite" is preferable to "muscovite" because © 1978, The Clay Minerals Society potassium...8 equivalents per 01O(OHh rather than a full muscovite charge of -1.0 equivalent (Hower and Mowatt, 1966)...structural formula for cookeite from the Jeffrey Quarry, Arkansas, calculated from the analysis of Miser...Pattern C is a natural Na-rectorite from the Jeffrey Quarry, Arkansas. Pattern Dis a 40% expandable Na-rectorite...lower spacings with increasing layc er charge (Suquet et al., 1977; Srodon, 1976). Additional evidencefor |  | | Journal (article/letter/editorial) | | Responses of FIR order of the layers (de la Calle and Suquet, 1988). The spectra to dehydration can only be...diagenetic for the liS is similar to that of muscovite (108 em-I), liS transform through a process of...collapse of preexisting smectitic layby an AI-rich , muscovite-like dioctahedral sheet. If it ers into low-charge...expandability ues more closely resemble the values of muscovite than of liS. They now attribute the trend to an...layer types . Octahedral sheet thicknesses for muscovite and phlogopite average about 2.09 A and 2.15 A |  | Valášková, Marta, Hundáková, Marianna, Kutláková, Kateřina Mamulová, Seidlerová, Jana, Čapková, Pavla, Pazdziora, Erich, Matějová, Kateřina, Heřmánek, Martin, Klemm, Volker, Rafaja, David (2010) Preparation and characterization of antibacterial silver/vermiculites and silver/montmorillonites. Geochimica et Cosmochimica Acta, 74 (22) 6287-6300 doi:10.1016/j.gca.2010.08.025 | Journal (article/letter/editorial) | | removal of potassium from biotite, phlogopite or muscovite (Foster, 1963; Norrish, 1973; de la Calle et al...1954; Shirozu and Bailey, 1966; de la Calle and Suquet, 1988; Reichenbach and Beyer, 1994; Weiss et al...bending vibrations, respectively (Farmer, 1974; Suquet et al., 1991; Madejová et al., 2000). The positions...Today 36, 107–114. de la Calle C., Dubernat J., Suquet H., Pezerat H., Gaultier J. and Mamy J. (1976)...Wilmette, Illinois, pp. 201–209. de la Calle C. and Suquet H. (1988) Vermiculites. In Hydrous Phyllosilicates |  | Szczerba, Marek, Kuligiewicz, Artur, Derkowski, Arkadiusz, Gionis, Vassilis, Chryssikos, GeorgiosD., Kalinichev, AndreyG. (2016) Structure and Dynamics of Water—Smectite Interfaces: Hydrogen Bonding and the Origin of the Sharp O–DW/O–HW Infrared Band From Molecular Simulations. Clays and Clay Minerals, 64 (4) 452-471 doi:10.1346/ccmn.2016.0640409 | Journal (article/letter/editorial) | | (UMR 6457), Ecole des Mines de Nantes, Nantes, France Abstract—Experimental studies have shown that...(Russell and Farmer, 1964; Farmer and Russell, 1971; Suquet et al., 1977; Sposito and Prost, 1982; Cariati...later confirmed by simulations of smectites and muscovite (e.g. Wang et al., 2005b, 2009; Marry et al.,...2009) and Loganathan and Kalinichev (2013) for muscovite. Furthermore, in all smectites studied, a dependence...Russell, 1971; Prost, Clays and Clay Minerals 1975; Suquet et al., 1977; Sposito and Prost, 1982; Sposito |  | | Journal (article/letter/editorial) | | the hydration states of beidellite as reported by Suquet et al. (1975). After the sample had been heated...reported for sericite by Udagawa (I 955), for muscovite by Eberhart (1963), for pyrophyllite by Wardie...Eberhart, L. P. (1963) Transformation du mica en muscovite par chauffage entre 700 ~ et 1200"C: Bull. Soc...and correlations: Chemical Reviews 65, 467-490. Suquet, H.. de la Calle, C., and Pezerat. H. (1975) Swelling |  | | Journal (article/letter/editorial) | | aspects is given in the review of de la Calle and Suquet (1988). Interlayer structures of the two-layer...simulation studies on the cation ordering in the muscovite mineral (Palin et al. 2001) and in illites and...with water. Mol Phys 89: 879–888 de la Calle C, Suquet H (1988) Vermiculites. In: Bailey SW (ed) Hydrous...Computational study of tetrahedral Al-Si ordering in muscovite. Phys Chem Miner 28: 534–544 Perdew JP, Zunger |  | Kuligiewicz, Artur, Derkowski, Arkadiusz, Szczerba, Marek, Gionis, Vassilis, Chryssikos, Georgios D. (2015) Revisiting the Infrared Spectrum of the Water–Smectite Interface. Clays and Clay Minerals, 63 (1) 15-29 doi:10.1346/ccmn.2015.0630102 | Journal (article/letter/editorial) | | (Russell and Farmer, 1964; Farmer and Russell, 1971; Suquet et al., 1977; Sposito and Prost, 1982; Cariati...earlier studies (e.g. Farmer and Russell, 1971; Suquet et al., 1977) reported the spectra of HDO instead...Russell and Farmer, 1964; Farmer and Russell, 1971; Suquet et al., 1977; Sposito and Prost, 1982; Sposito...National Academy of Science USA, 96, 3358 3364. Suquet, H., Prost, R., and Pezerat, H. (1977) Etude par...energetics, and dynamics of water adsorbed on the muscovite (001) surface: A molecular dynamics simulation |
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