Spurrite
A valid IMA mineral species - grandfathered
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About Spurrite
Formula:
Ca5(SiO4)2(CO3)
Colour:
Colourless, grey-white, lilac-grey
Lustre:
Vitreous, Resinous
Hardness:
5
Specific Gravity:
3.014
Crystal System:
Monoclinic
Name:
Named by Fred Eugene Wright in 1908 after Josiah Edward Spurr (1 October 1870, Gloucester, Massachusetts, USA - 12 January 1950, Orlando, Florida, USA), economic geologist who collected the first specimens. He led expiditions to mapping the interior of Alaska at the beginning of the gold rush. Later he became a renowned consulting economic geologist. In his later years he studied the craters of the moon. The volcano Mount Spurr, in Alaska, and Spurr Crater in the northwestern part of Palus Putredinis near Archimedes Crater, on the Moon, are also named for him.
The Negra mine (B,Na)-enriched spurrite is isotypic with synthetic NaCa5(SiO4)2(BO3) compound.
Unique Identifiers
Mindat ID:
3734
Long-form identifier:
mindat:1:1:3734:7
GUID
(UUID V4):
(UUID V4):
7ba306e6-2015-4d05-8509-c48cf003b625
IMA Classification of Spurrite
Approved, 'Grandfathered' (first described prior to 1959)
First published:
1908
Classification of Spurrite
9.AH.15
9 : SILICATES (Germanates)
A : Nesosilicates
H : Nesosilicates with CO3, SO4, PO4, etc.
9 : SILICATES (Germanates)
A : Nesosilicates
H : Nesosilicates with CO3, SO4, PO4, etc.
53.1.1.1
53 : NESOSILICATES Insular SiO4 Groups and Other Anions or Complex Cations
1 : Insular SiO4 Groups and Other Anions of Complex Cations with (CO3)
53 : NESOSILICATES Insular SiO4 Groups and Other Anions or Complex Cations
1 : Insular SiO4 Groups and Other Anions of Complex Cations with (CO3)
17.4.2
17 : Silicates Containing other Anions
4 : Silicates with carbonates
17 : Silicates Containing other Anions
4 : Silicates with carbonates
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Spu | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Spu | Whitney & Evans (2010) | Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371 |
Spu | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Spurrite
Vitreous, Resinous
Transparency:
Transparent
Colour:
Colourless, grey-white, lilac-grey
Streak:
white
Hardness:
5 on Mohs scale
Tenacity:
Brittle
Cleavage:
Distinct/Good
Perfect on {001}, poor on {100}, (001) ^ (100) = 79 degrees
Perfect on {001}, poor on {100}, (001) ^ (100) = 79 degrees
Density:
3.014 g/cm3 (Measured) 3.025 g/cm3 (Calculated)
Comment:
Measured with a pycnometer, both in xylene and in water
Optical Data of Spurrite
Type:
Biaxial (-)
RI values:
nα = 1.637 - 1.641 nβ = 1.672 - 1.676 nγ = 1.676 - 1.681
2V:
Measured: 35° to 41°
Max Birefringence:
δ = 0.039 - 0.040
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
relatively weak
Chemistry of Spurrite
Mindat Formula:
Ca5(SiO4)2(CO3)
Elements listed:
Common Impurities:
Ti,Al,Fe,Mn,Mg,Na,K
Chemical Analysis
Empirical formulas:
Sample ID | Empirical Formula |
---|---|
1 | H0.18Ca5.01Na0.05[(SiO4)1.91(SO4)0.08)][(CO3)0.71(BO3)0.28]O11 |
Sample references:
ID | Locality | Reference | Notes |
---|---|---|---|
1 | Negra Mine, Maconi, Cadereyta de Montes Municipality, Queretaro, Mexico | via EPMA, wet chemistry & gas chromatography of annealing products |
Crystallography of Spurrite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/a
Cell Parameters:
a = 10.49 Å, b = 6.705 Å, c = 14.16 Å
β = 101.32°
β = 101.32°
Ratio:
a:b:c = 1.565 : 1 : 2.112
Unit Cell V:
976.57 ų (Calculated from Unit Cell)
Z:
4
Twinning:
Polysynthetic twins on {001} and {101}. Also composition planes {001} or {205}.
Crystal Structure
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2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0006059 | Spurrite | Grice J D (2005) The structure of spurrite, tilleyite and scawtite, and relationships to other silicate-carbonate minerals The Canadian Mineralogist 43 1489-1500 | 2005 | Cornet Hill, Apuseni Mountains, Romania | 0 | 293 | |
0009239 | Spurrite | Smith J V, Karle I L, Hauptman H, Karle J (1960) The crystal structure of spurrite, Ca5(SiO4)2CO3. II. Description of structure Acta Crystallographica 13 454-458 | 1960 | contact zone at Scawt Hill, North Ireland | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
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Radiation - Copper Kα
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
2.701 Å | (100) |
2.635 Å | (70) |
3.019 Å | (65) |
2.663 Å | (50) |
2.170 Å | (40) |
3.81 Å | (30) |
2.609 Å | (30) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-𝑇 alteration and/or metamorphism | |
31 : Thermally altered carbonate, phosphate, and iron formations | |
Stage 5: Initiation of plate tectonics | <3.5-2.5 |
40 : Regional metamorphism (greenschist, amphibolite, granulite facies) | |
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere | <0.6 |
51 : Pyrometamorphic minerals (see also #54 and #56) | <0.36 |
Type Occurrence of Spurrite
Co-Type Localities:
General Appearance of Type Material:
Granular masses which resemble crystallized marble.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 86532.
The Natural History Museum, London, England, 1923,1032.
The Natural History Museum, London, England, 1923,1032.
Geological Setting of Type Material:
High-temperature thermal metamorphism along the contact between carbonate rock and mafic magma.
Associated Minerals at Type Locality:
Reference:
Wright, F.E. (1908) On three contact minerals from Valardeña, Durango, Mexico. (Gehlenite, spurrite and hillebrandite). American Journal of Science: 176: 545-554.
Synonyms of Spurrite
Other Language Names for Spurrite
Common Associates
Associated Minerals Based on Photo Data:
7 photos of Spurrite associated with Gehlenite | Ca2Al[AlSiO7] |
7 photos of Spurrite associated with Hillebrandite | Ca2(SiO3)(OH)2 |
5 photos of Spurrite associated with Vesuvianite | Ca19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9 |
5 photos of Spurrite associated with Rustumite | Ca10(Si2O7)2(SiO4)(OH)2Cl2 |
5 photos of Spurrite associated with Dellaite | Ca6Si3O11(OH)2 |
4 photos of Spurrite associated with Periclase | MgO |
4 photos of Spurrite associated with Ariegilatite | BaCa12(SiO4)4(PO4)2F2O |
4 photos of Spurrite associated with Portlandite | Ca(OH)2 |
3 photos of Spurrite associated with Oldhamite | (Ca,Mg)S |
3 photos of Spurrite associated with Fluorite | CaF2 |
Related Minerals - Strunz-mindat Grouping
9.AH. | Fluorbritholite-(Nd) | Ca2Nd3(SiO4)3F |
9.AH.05 | Iimoriite-(Y) | Y2[SiO4][CO3] |
9.AH.10 | Tundrite-(Ce) | Na2Ce2Ti(SiO4)(CO3)2O2 |
9.AH.10 | Tundrite-(Nd) | Na2(Nd,Ce)2Ti(SiO4)(CO3)2O2 |
9.AH.15 | Galuskinite | Ca7(SiO4)3(CO3) |
9.AH.20 | Ternesite | Ca5(SiO4)2(SO4) |
9.AH.20 | Silicocarnotite | Ca5[(SiO4)(PO4)](PO4) |
9.AH.25 | Britholite-(Ce) | (Ce,Ca)5(SiO4)3OH |
9.AH.25 | Britholite-(Y) | (Y,Ca)5(SiO4)3OH |
9.AH.25 | Chlorellestadite | Ca5(SiO4)1.5(SO4)1.5Cl |
9.AH.25 | Fluorbritholite-(Ce) | (Ce,Ca)5(SiO4)3F |
9.AH.25 | Fluorellestadite | Ca5(SiO4)1.5(SO4)1.5F |
9.AH.25 | Hydroxylellestadite | Ca5(SiO4)1.5(SO4)1.5(OH) |
9.AH.25 | Mattheddleite | Pb5(SiO4)1.5(SO4)1.5(Cl,OH) |
9.AH.25 | Tritomite-(Ce) | Ce5(SiO4,BO4)3(OH,O) |
9.AH.25 | Tritomite-(Y) | Y5(SiO4,BO4)3(O,OH,F) |
9.AH.25 | Fluorcalciobritholite | (Ca,REE)5(SiO4,PO4)3F |
9.AH.25 | Fluorbritholite-(Y) | (Y,Ca)5(SiO4)3F |
9.AH.25 | Britholite-(La) | Ca2(La,Ce,Ca)3(SiO4,PO4)3(OH,F) |
9.AH.25 | Calciobritholite | (Ca,Y)5(SiO4,PO4)3(OH) |
9.AH.35 | Nabimusaite | KCa12(SiO4)4(SO4)2O2F |
9.AH.35 | Dargaite | BaCa12(SiO4)4(SO4)2O3 |
9.AH.40 | Zadovite | BaCa6[(SiO4)(PO4)](PO4)2F |
9.AH.40 | Gazeevite | BaCa6(SiO4)2(SO4)2O |
9.AH.40 | Stracherite | BaCa6(SiO4)2[(PO4)(CO3)]2F |
9.AH.45 | Flamite | Ca8-x(Na,K)x(SiO4)4-x(PO4)x |
9.AH.50 | Byzantievite | Ba5(Ca,REE,Y)22(Ti,Nb)18(SiO4)4[(PO4),(SiO4)]4(BO3)9O22[(OH),F]43(H2O)1.5 |
9.AH.55 | Greenwoodite | (Ba,V3+O)2V3+9(Fe3+,Fe2+)2Si2O22 |
9.AH.60 | Kihlmanite-(Ce) | Ce2TiO2(SiO4)(HCO3)2(H2O) |
9.AH.65 | Tsangpoite | Ca5(PO4)2(SiO4) |
9.AH.70 | Enalite | (Th,REE,Al) [(PO4),(SiO4),(OH)] |
Other Information
Notes:
With a blowpipe srurrite shows a strong calcium flame reaction, loses its glassy luster, becomes white and porcelain-like but does not fuse even in thin splinters.
Effervesces readily with weak hydrochloric acid, dissolves completely and gelatinizes thoroughly.
Green cathodoluminescence.
Effervesces readily with weak hydrochloric acid, dissolves completely and gelatinizes thoroughly.
Green cathodoluminescence.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Spurrite in petrology
An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.
Internet Links for Spurrite
mindat.org URL:
https://www.mindat.org/min-3734.html
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References for Spurrite
Reference List:
Localities for Spurrite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
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Fuka mine, Fuka, Bitchū, Takahashi City, Okayama Prefecture, Japan